Registration Dossier

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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

First-aid measures

Description of first aid measures

Remove contaminated or saturated clothing.

Inhalation

In case product dust is released:

Move victims into fresh air.

In case of discomfort: Supply with medical care.

Skin contact

IF ON SKIN: Wash with plenty of water/ soap.

In case of discomfort: Supply with medical care.

Eye contact

Rinse eyes thoroughly with plenty of water keeping eyelid open.Obtain medical attention.

Ingestion

If feeling unwell seek medical advice.

Have the mouth rinsed with water.

Most important symptoms and effects, both acute and delayed

Symptoms

sensitising effects

Hazards

Health injuries may be delayed.

Indication of any immediate medical attention and special treatment needed

After absorbing large amounts of substance:

administration of activated charcoal.

Acceleration of gastrointestinal passage

Fire-fighting measures

Extinguishing media

Suitable extinguishing media:       Adapt fire-extinguishing measures to surroundings

Carbon dioxide (CO2)

Foam

powder

Unsuitable extinguishing media:       Do not use full-force water jet in order to avoid dispersal and spread of the fire.

Special hazards arising from the substance or mixture

May be released in case of fire: phosphorous oxides.

organic products of decomposition

Advice for firefighters

Water for fire fighting must not be introduced in the sewer system, subsoil, or surface waters. Assure that there are sufficient fire water retaining facilities Contaminated fire fighting water must be disposed of in conformity with the regulations of the local authorities.

In the event of fire, wear self-contained breathing apparatus.

Employ protective equipment commonly used in the event of fire.

Accidental release measures

Personal precautions, protective equipment and emergency procedures

Wear personal protective equipment

Environmental precautions

Do not allow entrance in sewage water, groundwater or drainage systems.

Methods and material for containment and cleaning up

Sweep up or vacuum up spillage and collect in suitable container for disposal.

Handling and storage

Precautions for safe handling

Ensure suitable suction/aeration at the work place and with operational machinery.

Conditions for safe storage, including any incompatibilities

Advice on protection against fire and explosion

Normal measures for preventive fire protection.

Take precautionary measures against static charges, keep away from sources of ignition.

When repairs of the production system are to be made (e.g. welding work), the section to be repaired must be essentially free of product.

Storage

Keep in inert gas.

Keep in a dry, cool and well-ventilated place.

Keep container tightly closed.

Further information

Protect from sunlight, warmth and heat.

Advice on common storage

Avoid contact with strong oxidants.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
UN 3088
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Inland waterway transport (UN RTDG/ADN(R))

UN number:
UN 3088
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Marine transport (UN RTDG/IMDG)

UN number:
UN 3088
Shipping information
Proper shipping name and description:
SELF-HEATING SOLID, ORGANIC, N.O.S.(Tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dimethylimidazol-2-yliden](2-thienylmethyliden)ruthenium(II)dichloride)
Chemical name:
Tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dimethylimidazol-2-yliden](2-thienylmethyliden)ruthenium(II)dichloride
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Air transport (UN RTDG/ICAO/IATA)

UN number:
UN 3088
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Exposure controls / personal protection

Exposure controls

Engineering measures

Ensure suitable suction/aeration at the work place and with operational machinery.

Do not introduce suctioned air to the work rooms.

If possible, transfer and handle product in closed systems only. Avoid production of dust.

Personal protective equipment

Respiratory protection

In case product dust is released or if workplace exposure limit is exeeded:

Hand protection

Wear protective gloves made of the following materials:.

Glove material       Natural rubber (NR)

Material thickness       0,5 mm

Break through time       > 480 min

Glove material       Polychloroprene (PCP)

Material thickness       0,5 mm

Break through time       > 480 min

Glove material       PVC

Material thickness       0,5 mm

Break through time       > 480 min

The material thickness and rupture time data do not apply to non-solute solids / dusts.

Selection of protective gloves to meet the requirements of specific workplaces.

Suitability for specific workplaces should be clarified with protective glove manufacturers.

Please observe that the daily duration of usage of a chemical protective glove is in practice far shorter due to the many influencing factors (e.g. temperature, mechanical strain on the glove material) than the permeation time determined acc. EN 374.

Eye protection

close-fitting protective goggles (e.g. closed goggles)

Skin and body protection

Wear suitable protective clothing.

Remove contaminated clothing immediately and rinse clothing with water in a container to completely remove catalyst.

Keep working clothes separately.

Hygiene measures

Smoking, eating and drinking should be prohibited in the application area.

Wash face and/or hands before break and end of work.

Apply adequate skin protection agents before handling the product. Assure skin cleaning and skin care after work. Preventive skin protection is recommended.

Protective measures

The personal protective equipment used must meet the requirements of directive 89/686/EEC and amendments (CE certification).

It should be defined in the work place in the form of a risk analysis according to directive 89/686/EEC and amendments.

All precautionary measures indicated have to be observed.

Stability and reactivity

Reactivity

No dangerous reaction known under conditions of normal use.

Chemical stability

Stable under recommended storage conditions.

Possibility of hazardous reactions       Combustion may occur on contact with flammable solvents or solvent vapours or with flammable gases in the presence of air (oxygen) .

Conditions to avoid

Keep away from heat.

No dangerous reaction known under conditions of normal use.

Incompatible materials

Strong oxidizing agents, organic solvents

Hazardous decomposition products

No decomposition if stored and applied as directed.

Disposal considerations

Waste treatment methods

Product

Used catalysts may have different hazards or properties than the original products. For this reason, this safety data sheet must not be used for waste catalysts or catalysts currently in use.

Other countries: observe the national regulations.

Uncleaned packaging

Do not reuse empty containers and dispose of in accordance with the regulations issued by the appropriate local authorities.

If there is product residue in the emptied container, follow directions for handling on the container's label.

Waste Key Number

No waste key number as per the European Waste Types List can be assigned to this product, since such classification is based on the (as yet undetermined) use to which the product is put by the consumer.

The waste key number must be determined as per the European Waste Types List (decision on EU Waste Types List 2000/532/EC) in cooperation with the disposal firm / producing firm / official authority.