Registration Dossier

Administrative data

First-aid measures

General advice:
Show this safety data sheet to the doctor in attendance.
Call a physician immediately.
Keep at rest.
Move out of dangerous area.
Symptoms of poisoning may appear several hours later.
No artificial respiration, mouth-to-mouth or mouth to nose. Use suitable instruments/apparatus.
Never give anything by mouth to an unconscious person.

Inhalation:
Consult a physician.
Move to fresh air.

Skin contact:
If symptoms persist, call a physician.
Wash off immediately with soap and plenty of water.

Eye contact:
Immediately flush eye(s) with plenty of water.

Ingestion:
Clean mouth with water and drink afterwards plenty of water.
Prevent vomiting if possible.
If a person vomits when lying on his back, place him in the recovery position.
Never give anything by mouth to an unconscious person.
If accidentally swallowed obtain immediate medical attention.

Fire-fighting measures

Suitable extinguishing media:
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Extinguishing media which shall not be used for safety reasons:
High volume water jet

Specific hazards during firefighting:
Flash back possible over considerable distance.
Do not use a solid water stream as it may scatter and spread fire.
Do not allow run-off from fire fighting to enter drains or water courses.

Special protective equipment for firefighters:
In the event of fire, wear self-contained breathing apparatus.

Further information:
In the event of fire and/or explosion do not breathe fumes.
Use water spray to cool unopened containers.
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.
Collect contaminated fire extinguishing water separately. This must not be discharged into drains.

Accidental release measures

Personal precautions:
Ensure adequate ventilation.
Use personal protective equipment.
Keep people away from and upwind of spill/leak.
Remove all sources of ignition.
Wear respiratory protection.

Environmental precautions:
Should not be released into the environment.
Prevent product from entering drains.
No special environmental precautions required.
Prevent further leakage or spillage if safe to do so.

Methods for cleaning up:
Clean contaminated surface thoroughly.
Dam up.
Neutralise with sodium hydroxide and allow to stand for 4 hours.
Wipe up with absorbent material (e.g. cloth, fleece).

Additional advice:
Local authorities should be advised if significant spillages cannot be contained.
Suppress (knock down) gases/vapours/mists with a water spray jet.

Handling and storage

Advice on safe handling:
Plan first aid action before beginning work with this product.
Provide sufficient air exchange and/or exhaust in work rooms.
Wear personal protective equipment.
In case of insufficient ventilation, wear suitable respiratory equipment.
Do not smoke.
Take precautionary measures against static discharges.
Avoid contact with skin and eyes.
Avoid exceeding the given occupational exposure limits (see section 8).
Smoking, eating and drinking should be prohibited in the application area.
Use personal protective equipment.

Advice on protection against fire and explosion:
Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapours).
Use explosion-proof equipment.
Avoid formation of aerosol.
Do not spray on a naked flame or any incandescent material.
When using do not smoke.
Do not empty into drains.
Keep away from open flames, hot surfaces and sources of ignition.

Requirements for storage areas and containers:
Store in a place accessible by authorized persons only.
Store in original container.
Keep locked up.
Store in cool place.
Keep container tightly closed.
To maintain product quality, do not store in heat or direct sunlight.
No smoking.
Containers which are opened must be carefully resealed and kept upright to prevent leakage.
Electrical installations / working materials must comply with the technological safety standards.

Further information on storage conditions:
Storage must be in accordance with the BetrSichV (Germany).

Advice on common storage:
Keep away from tobacco products.
Keep away from food, drink and animal feeding stuffs.

Other data:
No decomposition if stored and applied as directed.

This substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 17(3) for on-site isolated intermediates and, in case the substance is transported to other sites for further processing, the substance should be handled at these sites under the Strictly Controlled Conditions as specified in REACH regulation Article 18(4). Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management system is available at each manufacturing site.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
1993
Shippingopen allclose all
Labels:
3
SpecialProvisionsopen allclose all

Inland waterway transport (UN RTDG/ADN(R))

UN number:
1993
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Labels:
3
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Marine transport (UN RTDG/IMDG)

UN number:
1993
Shipping information
Proper shipping name and description:
Flammable liquid, n.o.s.
Chemical name:
Methanol, 2-Methyl-4-(2,2,3-trimethyl-3-cyclopenten-1-yl)-2-butenal
Labels:
3
Remarksopen allclose all

Air transport (UN RTDG/ICAO/IATA)

UN number:
1993
Shipping information
Proper shipping name and description:
Flammable liquid, n.o.s.
Chemical name:
Methanol, 2-Methyl-4-(2,2,3-trimethyl-3-cyclopenten-1-yl)-2-butenal
Labels:
3
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Respiratory protection:
In the case of vapour formation use a respirator with filter model ABEK.

Hand protection:
Wear chemicals-resistant gloves, e.g. safety gloves of chloroprene Level 2 or of butyl rubber Level 6.

Eye protection:
Safety glasses

Skin and body protection:
Lightweight protective clothing
Remove and wash contaminated clothing before re-use.
complete suit protecting against chemicals

Hygiene measures:
Avoid contact with skin, eyes and clothing.
Keep away from food, drink and animal feedingstuffs.
Wash hands before breaks and immediately after handling the product.
When using do not eat or drink.
When using do not smoke.

Protective measures:
When using do not eat, drink or smoke.

This substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 17(3) for on-site isolated intermediates and, in case the substance is transported to other sites for further processing, the substance should be handled at these sites under the Strictly Controlled Conditions as specified in REACH regulation Article 18(4). Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management system is available at each manufacturing site.

Stability and reactivity

Vapours may form explosive mixture with air.

Disposal considerations

Product:
Where possible recycling is preferred to disposal or incineration.
If recycling is not practicable, dispose of in compliance with local regulations.

Contaminated packaging:
Empty remaining contents.
Dispose of as unused product.