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Melting point / freezing point

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Reference
Endpoint:
melting point/freezing point
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2016-12-29 – 2016-12-29
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: Experimental result using standard method of analysis
Qualifier:
according to guideline
Guideline:
other: as mentioned below
Principles of method if other than guideline:
The Freezing point determination of octyl acetate (CAS No.112-14-1) was done using crushed ice and salt
GLP compliance:
not specified
Type of method:
other: standard laboratory method
Melting / freezing pt.:
< -14.74 °C
Atm. press.:
974.5 hPa
Remarks on result:
other: other details not available

Method Details

Observations

Method

Freezing Temperature Method

-

Principle of Freezing

Point test

The freezing point of a pure sample is the

temperature at which transition from liquid to solid state takes place at atmospheric pressure.

-

Quantity of test

item used

g

1 ml

Type of cooling bath used

·        

·        

·        

·        

·        

Crushed Ice- Salt

Type and model no. of temperature sensor used

·        

·        

·        

·        

Thermistor

Atmospheric pressure

hPa

974.5 hPa

Freezing point °C

°C

Less than - 14.74 °C

Conclusions:
The Freezing point determination of octyl acetate (CAS No.112-14-1) was done using crushed ice and salt. No freezing was observed up to -14.74°C. Hence, the freezing point was inferred to be less than -14.74°C at 974.5 hPa.
Executive summary:

The Freezing point determination of octyl acetate (CAS No.112-14-1) was done using crushed ice and salt. No freezing was observed up to -14.74°C. Hence, the freezing point was inferred to be less than -14.74°C at 974.5 hPa.

Description of key information

The Freezing point determination of octyl acetate (CAS No.112-14-1) was done using crushed ice and salt. No freezing was observed up to -14.74°C. Hence, the freezing point was inferred to be less than -14.74°C at 974.5 hPa.

Key value for chemical safety assessment

Melting / freezing point at 101 325 Pa:
-14.74 °C

Additional information

In an experiment conducted by SSS(Europe)AB,the Freezing point determination of octyl acetate (CAS No.112-14-1) was done using crushed ice and salt. No freezing was observed up to -14.74°C. Hence, the freezing point was inferred to be less than -14.74°C at 974.5 hPa.

Other supporting studies from various reliable sources such as authoritative database and handbook also suggests that the freezing point of chemical was reported to be in the range of -38.5 degree C to -37 degree C.

As the data from lab has K1 reliability and the test was performed using standard methos of analysis which has the value of freezing point temperature as <-14.74 degree degree C thus considered as key study for the chemical safety assessment.