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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Identification

Chemical structure
Display Name:
Low chlorinated copper, [29H,31Hphthalocyaninato(2-)-N29,N30,N31,N32]-, wherein the number of chlorines is more than or equal to 0 and less than or equal to 7
EC Number:
701-372-3
Molecular formula:
C32H16CuN8, C32H15ClCuN8, C32H14Cl2CuN8, C32H13Cl3CuN8, C32H12Cl4CuN8, C32H11Cl5CuN8, C32H10Cl6CuN8, C32H9Cl7CuN8
IUPAC Name:
Low chlorinated copper, [29H,31Hphthalocyaninato(2-)-N29,N30,N31,N32]-, wherein the number of chlorines is more than or equal to 0 and less than or equal to 7

Type of Substance

Composition:
UVCB
Origin:
organometallic

Substance Identifiers open all close all

  • [tetrachloro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]copper
  • 248-573-8
  • 27614-17-1
  • 29H,31H-Phthalocyanine, C,C,C,C-tetrachloro-, copper complex
  • 29H,31H-Phthalocyanine, copper deriv.
  • Copper tetrachlorophthalocyanine
  • Copper, [C,C,C,C-tetrachloro-29H,31H-phthalocyaninato(2-)- N29,N30,N31,N32]- (9CI)
  • Copper, [tetrachlorophthalocyaninato(2-)]- (7CI, 8CI)
  • Compositions

    Boundary Composition(s) open all close all

    State Form:
    solid: nanoform


    Characterisation of nanoforms

    Type of information reported:
    single nanoform
    Name of nanoform:
    Low chlorinated copper, [29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]-, wherein the number of chlorines is more than or equal to 0 and less than or equal to 7_Nanoform mulimodal

    Shape

    Shape descriptionopen allclose all
    Shape category:
    spheroidal
    Shape:
    cubic
    Pure shape:
    no
    Range:
    > 1 - < 100 %
    Shape category:
    spheroidal
    Shape:
    spherical
    Pure shape:
    no
    Range:
    > 1 - < 100 %
    Shape category:
    elongated
    Shape:
    rod
    Pure shape:
    no
    Range:
    > 1 - < 100 %

    Particle size distribution and range

    Particle size distribution and rangeopen allclose all
    Shape category:
    spheroidal
    Percentileopen allclose all
    Percentile:
    D10
    Range:
    > 1 - < 50 nm
    Percentile:
    D50
    Range:
    > 10 - < 100 nm
    Percentile:
    D90
    Range:
    > 20 - < 200 nm
    Fraction of constituent particles in the size range 1-100 nm:
    >= 80 - < 100 %
    Shape category:
    elongated
    Percentileopen allclose all
    Percentile:
    D10
    Range:
    > 1 - < 100 nm
    Percentile:
    D50
    Range:
    > 10 - < 300 nm
    Percentile:
    D90
    Range:
    > 20 - < 500 nm
    Range of length:
    > 10 - < 500 nm
    Range of aspect ratio (:1):
    >= 3 - <= 5
    Fraction of constituent particles in the size range 1-100 nm:
    >= 80 - < 100 %

    Crystallinity

    Structures
    Structure:
    crystalline
    Name:
    Pigment 15:1
    Pure structure:
    yes

    Specific surface area

    Range of specific surface area:
    > 15 - < 500 m²/g

    Surface functionalisation / treatment

    Surface treatment applied:
    no

    Legal Entity Composition(s) open all close all

    State Form:
    solid: nanoform


    Characterisation of nanoforms

    Type of information reported:
    single nanoform
    Name of nanoform:
    Low chlorinated copper, [29H,31Hphthalocyaninato(2-)-N29,N30,N31,N32]-, wherein the number of chlorines is more than or equal to 0 and less than or equal to 7_Nanoform spheroidal

    Shape

    Shape description
    Shape category:
    spheroidal
    Shape:
    spherical
    Pure shape:
    yes
    Range:
    > 80 - < 100 %

    Particle size distribution and range

    Particle size distribution and range
    Shape category:
    spheroidal
    Percentileopen allclose all
    Percentile:
    D10
    Typical value:
    ca. 22.3 nm
    Range:
    > 1 - < 50 nm
    Percentile:
    D50
    Typical value:
    ca. 46 nm
    Range:
    > 10 - < 55 nm
    Percentile:
    D90
    Typical value:
    ca. 105.6 nm
    Range:
    > 50 - < 150 nm
    Additional information:
    analysis conducted on 643 particles
    Fraction of constituent particles in the size range 1-100 nm:
    ca. 88 - <= 100 %

    Crystallinity

    Structures
    Structure:
    crystalline
    Name:
    Pigment Blue 15:1
    Pure structure:
    yes
    Typical composition:
    ca. 100 %
    Range:
    > 90 - < 100 %
    Description:
    Powder X-Ray diffraction measurements of very fine crystals cannot be used to properly define the crystal system and Bravais lattice due to signal broadening.
    (Herbst, Hunger, Industrial Organic Pigments VCH, 1993, p.44)

    Specific surface area

    Typical specific surface area:
    ca. 17.2 m²/g
    Range of specific surface area:
    >= 10 - <= 80 m²/g

    Surface functionalisation / treatment

    Surface treatment applied:
    no
    State Form:
    solid: nanoform


    Constituent 1
    Chemical structure
    Reference substance name:
    29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32 copper
    EC Number:
    205-685-1
    EC Name:
    29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32 copper
    CAS Number:
    147-14-8
    Molecular formula:
    C32H16CuN8
    IUPAC Name:
    [29H,31H-phthalocyaninato(2-)-kappa~2~N~29~,N~31~]copper
    Constituent 2
    Chemical structure
    Reference substance name:
    Copper chlorophthalocyanine
    EC Number:
    235-476-0
    EC Name:
    Copper chlorophthalocyanine
    CAS Number:
    12239-87-1
    Molecular formula:
    C32H15ClCuN8
    IUPAC Name:
    copper chlorophthalocyanine
    Constituent 3
    Chemical structure
    Reference substance name:
    [dichloro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]copper
    EC Number:
    252-468-2
    EC Name:
    [dichloro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]copper
    CAS Number:
    35254-77-4
    Molecular formula:
    C32H14Cl2CuN8
    IUPAC Name:
    [dichloro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]copper
    Constituent 4
    Chemical structure
    Reference substance name:
    [trichloro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]copper
    EC Number:
    249-807-1
    EC Name:
    [trichloro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]copper
    CAS Number:
    29719-96-8
    Molecular formula:
    C32H13Cl3CuN8
    IUPAC Name:
    [trichloro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]copper
    Constituent 5
    Chemical structure
    Reference substance name:
    [tetrachloro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]copper
    EC Number:
    248-573-8
    EC Name:
    [tetrachloro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]copper
    CAS Number:
    27614-71-7
    Molecular formula:
    C32H12Cl4CuN8
    IUPAC Name:
    [tetrachloro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]copper
    Constituent 6
    Chemical structure
    Reference substance name:
    [pentachloro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]copper
    EC Number:
    263-711-7
    EC Name:
    [pentachloro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]copper
    CAS Number:
    62726-15-2
    Molecular formula:
    C32H11Cl5CuN8
    IUPAC Name:
    [pentachloro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]copper

    Characterisation of nanoforms

    Type of information reported:
    single nanoform
    Name of nanoform:
    Low chlorinated copper, [29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]-, wherein the number of chlorines is more than or equal to 0 and less than or equal to 7_Nanoform mulimodal_SE-IN02

    Shape

    Shape descriptionopen allclose all
    Shape category:
    spheroidal
    Shape:
    cubic
    Pure shape:
    no
    Range:
    > 50 - < 100 %
    Shape category:
    spheroidal
    Shape:
    spherical
    Pure shape:
    no
    Range:
    > 1 - < 50 %
    Shape category:
    elongated
    Shape:
    rod
    Pure shape:
    yes
    Range:
    > 1 - < 20 %

    Particle size distribution and range

    Particle size distribution and rangeopen allclose all
    Shape category:
    spheroidal
    Percentileopen allclose all
    Percentile:
    D10
    Range:
    >= 0.005 - <= 0.04 μm
    Percentile:
    D50
    Range:
    >= 0.01 - <= 0.06 μm
    Percentile:
    D90
    Range:
    >= 0.02 - <= 0.08 μm
    Fraction of constituent particles in the size range 1-100 nm:
    > 80 - < 100 %
    Shape category:
    elongated
    Percentileopen allclose all
    Percentile:
    D10
    Range:
    >= 0.005 - <= 0.04 μm
    Percentile:
    D50
    Range:
    >= 0.01 - <= 0.06 μm
    Percentile:
    D90
    Range:
    >= 0.02 - <= 0.08 μm
    Range of length:
    > 0.01 - <= 0.2 μm
    Range of aspect ratio (:1):
    >= 3 - <= 5
    Fraction of constituent particles in the size range 1-100 nm:
    > 80 - < 100 %

    Crystallinity

    Structures
    Structure:
    crystalline
    Name:
    Pigment Blue 15:1
    Pure structure:
    yes

    Specific surface area

    Range of specific surface area:
    >= 50 - <= 130 m²/g

    Surface functionalisation / treatment

    Surface treatment applied:
    no
    State Form:
    solid: nanoform


    Constituent 1
    Chemical structure
    Reference substance name:
    29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32 copper
    EC Number:
    205-685-1
    EC Name:
    29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32 copper
    CAS Number:
    147-14-8
    Molecular formula:
    C32H16CuN8
    IUPAC Name:
    [29H,31H-phthalocyaninato(2-)-kappa~2~N~29~,N~31~]copper
    Constituent 2
    Chemical structure
    Reference substance name:
    Copper chlorophthalocyanine
    EC Number:
    235-476-0
    EC Name:
    Copper chlorophthalocyanine
    CAS Number:
    12239-87-1
    Molecular formula:
    C32H15ClCuN8
    IUPAC Name:
    copper chlorophthalocyanine
    Constituent 3
    Chemical structure
    Reference substance name:
    [dichloro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]copper
    EC Number:
    252-468-2
    EC Name:
    [dichloro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]copper
    CAS Number:
    35254-77-4
    Molecular formula:
    C32H14Cl2CuN8
    IUPAC Name:
    [dichloro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]copper
    Constituent 4
    Chemical structure
    Reference substance name:
    [trichloro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]copper
    EC Number:
    249-807-1
    EC Name:
    [trichloro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]copper
    CAS Number:
    29719-96-8
    Molecular formula:
    C32H13Cl3CuN8
    IUPAC Name:
    [trichloro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]copper
    Constituent 5
    Chemical structure
    Reference substance name:
    [tetrachloro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]copper
    EC Number:
    248-573-8
    EC Name:
    [tetrachloro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]copper
    CAS Number:
    27614-71-7
    Molecular formula:
    C32H12Cl4CuN8
    IUPAC Name:
    [tetrachloro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]copper
    Constituent 6
    Chemical structure
    Reference substance name:
    [pentachloro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]copper
    EC Number:
    263-711-7
    EC Name:
    [pentachloro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]copper
    CAS Number:
    62726-15-2
    Molecular formula:
    C32H11Cl5CuN8
    IUPAC Name:
    [pentachloro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]copper

    Characterisation of nanoforms

    Type of information reported:
    single nanoform
    Name of nanoform:
    Low chlorinated copper, [29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]-, wherein the number of chlorines is more than or equal to 0 and less than or equal to 7_Nanoform mulimodal_DE90

    Shape

    Shape descriptionopen allclose all
    Shape category:
    spheroidal
    Shape:
    cubic
    Pure shape:
    no
    Range:
    > 50 - < 100 %
    Shape category:
    spheroidal
    Shape:
    spherical
    Pure shape:
    no
    Range:
    > 1 - < 50 %
    Shape category:
    elongated
    Shape:
    rod
    Pure shape:
    yes
    Range:
    > 1 - < 20 %

    Particle size distribution and range

    Particle size distribution and rangeopen allclose all
    Shape category:
    spheroidal
    Percentileopen allclose all
    Percentile:
    D10
    Range:
    >= 0.005 - <= 0.04 μm
    Percentile:
    D50
    Range:
    >= 0.01 - <= 0.06 μm
    Percentile:
    D90
    Range:
    >= 0.02 - <= 0.08 μm
    Fraction of constituent particles in the size range 1-100 nm:
    > 80 - < 100 %
    Shape category:
    elongated
    Percentileopen allclose all
    Percentile:
    D10
    Range:
    >= 0.005 - <= 0.04 μm
    Percentile:
    D50
    Range:
    >= 0.01 - <= 0.06 μm
    Percentile:
    D90
    Range:
    >= 0.02 - <= 0.08 μm
    Range of length:
    > 0.01 - <= 0.2 μm
    Range of aspect ratio (:1):
    >= 3 - <= 5
    Fraction of constituent particles in the size range 1-100 nm:
    > 80 - < 100 %

    Crystallinity

    Structures
    Structure:
    crystalline
    Name:
    Pigment Blue 15:1
    Pure structure:
    yes

    Specific surface area

    Range of specific surface area:
    >= 50 - <= 130 m²/g

    Surface functionalisation / treatment

    Surface treatment applied:
    no

    Composition(s) generated upon use

    Other types of composition(s)