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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Flammability

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Endpoint:
substances / mixtures which in contact with water emit flammable gases
Type of information:
experimental study
Adequacy of study:
key study
Study period:
From 2017-09-15 to 2017-09-18
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.12 (Flammability (Contact with Water))
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Specific details on test material used for the study:
- Batch n°: DR74271215
- Production release date: 30 November 2015
- Description: clear liquid
- Molecular formula: C13H31N3O2
- Molecular weight: 261.4 g/mol
- Expiry date: 30 December 2018
- Purity (on dry basis): 98.2%, water content: 0.05%
Test procedure:
step 1
Remarks on result:
no reaction with water observed
Test procedure:
step 2
Remarks on result:
no reaction with water observed
Test procedure:
step 3
Remarks on result:
no reaction with water observed
Test procedure:
step 4
Remarks on result:
no reaction with water observed

No gas generation or spontaneous ignitions were observed during any of the initial tests (test 1 - test 3) and in the final test (test 4).

It is concluded that the sample does not generate flammable gases in contact with water and is therefore non-hazardous.

Interpretation of results:
not classified based on GHS criteria
Conclusions:
The test substance does not generate flammable gases in contact with water.
Endpoint:
pyrophoric liquids
Type of information:
experimental study
Adequacy of study:
key study
Study period:
From 2017-09-22 to 2017-09-25
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.13 (Pyrophoric Properties of Solids and Liquids)
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Specific details on test material used for the study:
- Batch n°: DR74271215
- Production release date: 30 November 2015
- Description: clear liquid
- Molecular formula: C13H31N3O2
- Molecular weight: 261.4 g/mol
- Expiry date: 30 December 2018
- Purity (on dry basis): 98.2%, water content: 0.05%
Key result
Test procedure:
ignition time on contact with air
Remarks on result:
no ignition on contact with air (not further specified)
Key result
Test procedure:
effect on filter paper
Remarks on result:
no charring

Porcelain cup test (test 1): no ignition and no reaction was observed in any of the 6 repetitions.

Filter paper test (test 2): no ignition, no charring and no reaction was observed in any of the 3 repetitions.

Since no ignitions or charring was observed during any test, the sample is considered not pyrophoric.

Interpretation of results:
not classified based on GHS criteria
Conclusions:
The test item was determined to be not pyrophoric.
Endpoint:
flammable solids
Data waiving:
study technically not feasible
Justification for data waiving:
the study does not need to be conducted because the substance is a liquid
Endpoint:
self-heating substances / mixtures
Data waiving:
study technically not feasible
Justification for data waiving:
the study does not need to be conducted because the substance is a liquid

Description of key information

The substance is not considered a pyrophoric substance according to a GLP study (K1; Younis, 2017). In addition, the test substance does not generate flammable gases in contact with water (K1; Younis, 2017). Finally, the test substance is not considered as a flammable and a self-heating substance (no test performed, waiving because the substance is a liquid).

Key value for chemical safety assessment

Flammability:
not classified

Additional information

Justification for classification or non-classification

The substance does not need to be classified as flammable, self-heating or pyrophoric. In addition, the substance does not need to be classified as a substance that generate flammable gases in contact with water.