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Diss Factsheets

Administrative data

Endpoint:
auto-ignition temperature (liquids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
16 June 2010
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: Study was performed according to guideline

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2010
Report date:
2010

Materials and methods

Test guideline
Qualifier:
equivalent or similar to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Remarks:
Issued by: The Department of Health of the Government of the United Kingdom Inspection date: 15 September 2009

Test material

Constituent 1
Chemical structure
Reference substance name:
Phosphorodithioic acid, mixed O,O-bis(2-ethylhexyl and iso-Pr) esters, zinc salts
EC Number:
272-723-1
EC Name:
Phosphorodithioic acid, mixed O,O-bis(2-ethylhexyl and iso-Pr) esters, zinc salts
Cas Number:
68909-93-3
Molecular formula:
Too complex
IUPAC Name:
Phosphorodithioic acid, mixed O,O-bis(2-ethylhexyl and iso-Pr) esters, zinc salts
Details on test material:
- Substance type: a mixture of coordination compounds in oil consisting of a zinc metal complex bonded to alkydithiophosphate ligands

Results and discussion

Auto-ignition temperature (liquids / gases)
Auto-ignition temperature:
244 °C
Atm. press.:
>= 100.36 - <= 102.63 kPa
Remarks on result:
other:

Any other information on results incl. tables

Table 1. Results of Auto-Flammability Test

Test Temperature

(0C)

Test Volume (µL)

Ignition Delay

(sec)

Observations

50 (clean flask)

70

> 300

No ignition

100 (clean flask)

70

> 300

No ignition

150

70

> 300

No ignition

200

70

> 300

No ignition, grey fumes emitted

250

70

> 300

No ignition, grey fumes emitted

300

70

     9

Orange flame, grey flumes emitted

270 (clean flask)

70

> 300

No ignition

280 (clean flask)

70

   15

Orange flame, grey flumes emitted

276

70

17

Orange flame, grey flumes emitted

274

70

20

Orange flame, grey flumes emitted

272

70

> 300

No ignition

272 (clean flask)

200

25

Orange flame, grey flumes emitted

270 (clean flask)

200

34

Orange flame, grey flumes emitted

268 (clean flask)

200

32

Orange flame, grey flumes emitted

266 (clean flask)

200

40

Orange flame, grey flumes emitted

264 (clean flask)

200

 46

Orange flame, grey flumes emitted

262

200

42

Orange flame, grey flumes emitted

258

200

47

Orange flame, grey flumes emitted

250

200

> 300

No ignition, grey fumes emitted

256

200

56

Orange flame, grey flumes emitted

254

200

> 300

No ignition, grey fumes emitted

254 (clean flask)

400

79

Orange flame, grey flumes emitted

252 (clean flask)

400

83

Orange flame, grey flumes emitted

250 (clean flask)

400

83

Orange flame, grey flumes emitted

248 (clean flask)

400

> 300

No ignition, grey fumes emitted

248

400

103

Orange flame, grey flumes emitted

246 (clean flask)

400

117

Orange flame, grey flumes emitted

244 (clean flask)

400

> 300

No ignition, grey fumes emitted

244 (clean flask)

600

171

Orange flame, grey flumes emitted

242 (clean flask)

600

> 300

No ignition, grey fumes emitted

242 (clean flask)

800

> 300

No ignition, grey fumes emitted

242 (clean flask)

1000

> 300

No ignition, grey fumes emitted

242 (clean flask)

1200

> 300

No ignition, grey fumes emitted

242 (clean flask)

1400

> 300

No ignition, grey fumes emitted

Applicant's summary and conclusion

Conclusions:
The auto-ignition temperature of the substance is 244 degrees C
Executive summary:

The auto-ignition temperature of the substance was determined using a method designed to be compatible with EU Method A.15. Varying amounts of the substance were heated in a flask and observed for signs of ignition over a 300 second period until the lowest temperature at which ignition occured was determined.

The auto-ignition temperature of the test substance was determined to be 262 degrees C at atmospheric pressures between 100.36 - 102.63 kPa.