Registration Dossier

Data platform availability banner - registered substances factsheets

Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
auto-ignition temperature (liquids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
from 09 June 2017 to 25 July 2017
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2017
Report date:
2017

Materials and methods

Test guidelineopen allclose all
Qualifier:
according to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
Version / remarks:
2008
Deviations:
no
Qualifier:
according to guideline
Guideline:
DIN 51794 (Testing of mineral oil hydrocarbons - Determination of ignition temperature)
Version / remarks:
2003
Deviations:
no
Qualifier:
according to guideline
Guideline:
IEC 60079-4 (Electrical apparatus for explosive gas atmospheres. Part 4: Method of test for ignition temperature)
Version / remarks:
1975
Deviations:
no
GLP compliance:
yes

Test material

Constituent 1
Chemical structure
Reference substance name:
Tributyl-2-thiourea
EC Number:
219-350-2
EC Name:
Tributyl-2-thiourea
Cas Number:
2422-88-0
Molecular formula:
C13H28N2S
IUPAC Name:
1,1,3-tributylthiourea
Test material form:
liquid
Details on test material:
- Name of test material (as cited in study report): Tri butyl thiourea
- Appearance: Clear pale to medium brown liquid
- Storage conditions: At room temperature

Results and discussion

Auto-ignition temperature (liquids / gases)
Key result
Auto-ignition temperature:
285 °C
Atm. press.:
>= 1 010.6 - <= 1 013.4 hPa

Any other information on results incl. tables

Table: Results of the auto-ignition temperature measurements

 

Test

Volume
[uL]

Auto-ignition
temperature
[°C]

Ignition delay

[s]

Colour of the flame

Minimum auto-ignition
temperature
[°C]

1

70

304

19

Orange/blue

287

 

150

290

34

Orange/blue

 

 

250

287

35

Orange/blue

 

 

400

292

22

Orange/blue

 

2

100

294

38

Orange/blue

289

 

300

289

32

Orange/blue

 

 

450

298

19

Orange/blue

 

3

200

294

25

Orange/blue

291

 

320

292

24

Orange/blue

 

 

500

291

27

Orange/blue

 

 

550

292

22

Orange/blue

 

 

Applicant's summary and conclusion

Conclusions:
The auto-ignition temperature of the substance was determined to be 285°C (at 1011-1013 hPa).
Executive summary:

The auto-ignition temperature of the substance was determined to be 285°C (at 1011 -1013 hPa) in a GLP study according to EC A.15, DIN 51794 and IEC 79-4.