Registration Dossier

Administrative data

First-aid measures

Description of first aid measures
Skin contact: Remove all contaminated clothes and footwear immediately unless stuck to skin. Wash immediately with plenty of soap and water.
Eye contact: Bathe the eye with running water for 15 minutes.
Ingestion: Wash out mouth with water. Do not induce vomiting. If conscious, give half a litre of water to drink immediately. Consult a doctor.
Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so. If conscious, ensure the casualty sits or lies down. Consult a doctor.

Fire-fighting measures

Extinguishing media
Extinguishing media: Water. Alcohol or polymer foam. Dry chemical powder. Carbon dioxide. Use water spray to cool containers.
Special hazards arising from the substance or mixture
Exposure hazards: In combustion emits toxic fumes of carbon dioxide / carbon monoxide. / In combustion emits toxic fumes of sulphur oxides. / In combustion emits toxic fumes of nitrogen oxides.
Advice for fire-fighters
Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes.

Accidental release measures

Personal precautions, protective equipment and emergency procedures
Personal precautions: Refer to section 8 of SDS for personal protection details. Do not create dust. Mark out the contaminated area with signs and prevent access to unauthorised personnel.
Environmental precautions
Environmental precautions: Contain the spillage using bunding. Do not discharge into drains or rivers.
Methods and material for containment and cleaning up
Clean-up procedures: Transfer to a closable, labelled salvage container for disposal by an appropriate method. Do not use equipment in clean-up procedure which may produce sparks.

Handling and storage

Handling and storage
Precautions for safe handling
Handling requirements: Ensure there is sufficient ventilation of the area. Avoid the formation or spread of dust in the air. Avoid direct contact with the substance. Use non-sparking tools.
Conditions for safe storage, including any incompatibilities
Storage conditions: Store in cool, well ventilated area. < 30 Celsius. Keep container tightly closed.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
UN3077
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Labels:
EHS, Class 9
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Marine transport (UN RTDG/IMDG)

UN number:
UN 3077
Shipping information
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
(1, 1, 3-tributylthiourea)
Chemical name:
1, 1, 3-tributylthiourea
Labels:
EHS, Class 9
Marine pollutant
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Air transport (UN RTDG/ICAO/IATA)

UN number:
UN 3077
Shipping information
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
(1, 1, 3-tributylthiourea)
Chemical name:
1, 1, 3-tributylthiourea
Labels:
EHS, Class 9
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Exposure controls / personal protection

Exposure controls
Engineering measures: Ensure there is sufficient ventilation of the area.
Respiratory protection: Respiratory protective device with particle filter.
Hand protection: PVC gloves. / Rubber gloves.
Eye protection: Safety glasses. Ensure eye bath is to hand.
Skin protection: Protective clothing. Boots.

Stability and reactivity

Reactivity
Reactivity: Stable under recommended transport or storage conditions.
Chemical stability: Stable under normal conditions.
Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions.
Decomposition may occur on exposure to conditions or materials listed below.

Disposal considerations

Waste treatment methods
Disposal operations: Transfer to a suitable container and arrange for collection by specialised disposal company.
Disposal of packaging: Dispose of in a regulated landfill site or other method for hazardous or toxic wastes.
NB: The user's attention is drawn to the possible existence of regional or national regulations regarding disposal.