Titanium(4+) ethanolate

Oxidising properties

Administrative data

Endpoint:

oxidising properties, other

Data waiving:

study scientifically not necessary / other information available

Justification for data waiving:

the study does not need to be conducted because there are no chemical groups present in the molecule which are associated with oxidising properties and hence, the classification procedure does not need to be applied

Cross-reference

Reason / purpose for cross-reference:

data waiving: supporting information

Reference

Endpoint:

auto-ignition temperature (liquids)

Type of information:

experimental study

Adequacy of study:

key study

Study period:

2016-11-11 to 2016-11-15

Reliability:

1 (reliable without restriction)

Rationale for reliability incl. deficiencies:

guideline study

Qualifier:

according to guideline

Guideline:

other: OECD Guideline 113, Screening Test for Thermal Stability and Stability in Air

Deviations:

no

GLP compliance:

yes (incl. QA statement)

Remarks:

Landesamt für Umwelt, Wasserwirtschaft und Gewerbeaufsicht

Key result

Auto-ignition temperature:

325.9 °C

Atm. press.:

1 013 hPa

Remarks on result:

other: exothermic event at 325.9 °C was observed, possibly caused by decomposition.

As the exothermic event yielded an energy < 300 J/g the test item is no subject to the classification procedures for self-reactive substances and the acceptance

procedures for Class 1 explosives need not to be applied. The second event began above 500 °C and showed a clear endothermic reaction. Therefore it was not taken into account.

Conclusions:

During the DSC run an exothermic event at 325.9 °C was observed, which could be caused by decomposition.
As the exothermic event yielded an energy < 300 J/g the test item is no subject to the classification procedures for self-reactive substances and the acceptance procedures for Class 1 explosives need not to be applied. The second event began above 500 °C and showed a clear endothermic reaction