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Physical & Chemical properties

Flash point

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Administrative data

Link to relevant study record(s)

Reference
Endpoint:
flash point, other
Type of information:
experimental study
Adequacy of study:
key study
Study period:
1994-02-18 to 1994-03-02
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Remarks:
The EU Method A.9 is applicable to liquid substances or low melting solids whose vapours can be ignited by ignition sources, only. Since the substances melts at 51.9 °C, the test system is considered as valid for that test item.
Qualifier:
according to guideline
Guideline:
EU Method A.9 (Flash-Point)
Version / remarks:
1992
Deviations:
yes
Remarks:
The test item is a low melting point solid and therefore a syringe could not be used to add the test material to the sample cup. Instead the test material was weighed into the sample cup.
Qualifier:
according to guideline
Guideline:
ISO 1523 (Determination of flash point - Closed cup equilibrium method)
Version / remarks:
1983
Deviations:
not specified
GLP compliance:
yes (incl. QA statement)
Remarks:
signed 1994-03-16
Type of method:
equilibrium method closed cup
Flash point apparatus:
other: no data
Key result
Flash point:
157 °C
Atm. press.:
101.83 kPa
Remarks on result:
other: ± 2 °C

RESULTS

Temperature (°C) Observations

20, 25, 30, 35, 40, 45, 50, 55* (Fresh Sample), 60, 65, 70, 75, 80, 85, 90, 95, 100, 105, 105 (Fresh Sample), 110, 115, 120, 125, 130, 135, 140, 145, 150, 155

No flash
155 (Fresh Sample) Small flash which did not spread across the sample cup
160 A flash spread across the sample cup
155 (Fresh Sample), 156 No flash
157, 157 (Fresh Sample), 157 (Fresh Sample) A flash spread across the sample cup
155 (Fresh Sample), 155 (Fresh Sample) No flash

* = liquid above 52 °C.

Atmospheric pressure = 101.83 kPa

Corrected flash point = 156.884 °C

Interpretation of results:
other: According to CLP regulation, a substance is not considered flammable when the flash point is greater than 60 °C.
Conclusions:
According to Council Directive 92/69/EEC A.9, the flash point of the test item was determined to be 157 ± 2 °C at 101.83 kPa.

Description of key information

The flash point of the test item was determined to be 157 ± 2 °C at 101.83 kPa.

The EU Method A.9 is applicable to liquid substances or low melting solids (i.e., < 160°C) whose vapours can be ignited by ignition sources, only. Since the melting point of the test item is 52 °C, the test system is considered as valid for that substance.

Key value for chemical safety assessment

Flash point at 101 325 Pa:
157 °C

Additional information