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Reference
Endpoint:
auto-ignition temperature (liquids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
This study was conducted between 19 September 2016 and 22 September 2016
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
Version / remarks:
EC No. 440/2008 30 May 2008
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Key result
Auto-ignition temperature:
> 383 - < 393 °C
Atm. press.:
> 101.7 - < 101.8 kPa

Results of the auto-ignition temperature determination are shown in the following table:

 Test temperature (ºC)  Test volume (µL)  Ignition delay (s)  Observations
 200 (clean flask)  70  >300  No ignition
 250 (clean flask)  70  >300  No ignition. Grey fumes emitted
 300 (clean flask)  70  >300   No ignition. Grey fumes emitted
 350  70  >300   No ignition. Grey fumes emitted
400   70  18   A green flame. Grey fumes emitted
 390  70  >300   No ignition. Grey fumes emitted
392 (clean flask)   70  15   A green flame. Grey fumes emitted
 390 (clean flask)  70  >300   No ignition. Grey fumes emitted
390 (clean flask)   200  >300   No ignition. Grey fumes emitted
390 (clean flask)   400  >300   No ignition. Grey fumes emitted
390 (clean flask)   600  33   A green flame. Grey fumes emitted
 388 (clean flask)  600  >300   No ignition. Grey fumes emitted
 388 (clean flask)  800  28   A green flame. Grey fumes emitted
 386 (clean flask)  800  >300   No ignition. Grey fumes emitted
  386 (clean flask)  1000  >300   No ignition. Grey fumes emitted
  386 (clean flask)  1200  >300   No ignition. Grey fumes emitted
  386 (clean flask)  1400  >300   No ignition. Grey fumes emitted
Conclusions:
The test item has been determined to have an auto-ignition temperature of 388 ± 5 °C.
Executive summary:

The hazardous physico-chemical properties of (μ(5-amino-1,3,3-trimethylcycloihexylamine-N,N')hexafluorodiboron have been determined.  

Auto-Ignition Temperature (Liquids and Gases).

388 ± 5 °C, using a procedure designed to be compatible with Method A.15 Auto-Ignition Temperature (Liquids and Gases) of Commission Regulation (EC) No 440/2008 of 30 May 2008.

Description of key information

The test item has been determined to have an auto-ignition temperature of 388 ± 5 °C.

Key value for chemical safety assessment

Autoflammability / Self-ignition temperature at 101 325 Pa:
388 °C

Additional information

Auto-Ignition Temperature (Liquids and Gases).

388 ± 5 °C, using a procedure designed to be compatible with Method A.15 Auto-Ignition Temperature (Liquids and Gases) of Commission Regulation (EC) No 440/2008 of 30 May 2008.