Bis(N,N-dimethylpropane-1,3-diamine-N)[29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]cobalt(1+) chloride

Auto flammability

Administrative data

Endpoint:

relative self-ignition temperature (solids)

Type of information:

experimental study

Adequacy of study:

key study

Study period:

2018-02-07 to 2018-02-08

Reliability:

1 (reliable without restriction)

Rationale for reliability incl. deficiencies:

guideline study

Data source

Reference

Reference Type:

study report

Title:

Unnamed

Year:

2018

Materials and methods

Test guideline

Test guideline 1

Qualifier:

according to guideline

Guideline:

other: VDI 2263 (1990), sheet 1, Grewer Oven

Version / remarks:

1990

Deviations:

no

Test guideline 2

Qualifier:

according to guideline

Guideline:

other: Recommendations on the TRANSPORT OF DANGEROUS GOODS: Manual of Tests and Criteria, 6th edition, New York and Geneva, 2015: Appendix 6 Screening Procedures, Division 4.2: Substances which may be liable to spontaneous combustion

Version / remarks:

2015

Deviations:

no

GLP compliance:

yes (incl. QA statement)

Test material

Test material information

Constituent 1

Reference substance name:

Bis(N,N-dimethylpropane-1,3-diamine-N)[29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]cobalt(1+) chloride

EC Number:

284-943-5

EC Name:

Bis(N,N-dimethylpropane-1,3-diamine-N)[29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]cobalt(1+) chloride

Cas Number:

84989-53-7

Molecular formula:

C42H44CoN12.Cl

IUPAC Name:

hydroxylamine

Test material form:

solid: particulate/powder

Results and discussion

Relative self-ignition temperature (solids)

Key result

Relative self-ignition temperature:

320 °C

Remarks on result:

other: Onset self- ignition

Any other information on results incl. tables

An endothermic effect was detected between 140 °C and 160 °C. An exothermic effect was detected starting at 320 °C, which led to a maximum temperature of 550 °C. After the measurement a black residue remained in the basket. It can be concluded that in the screening test, the test item indicated a self-heating starting at 320°C, but that this on-set temperature was above the cut-off for classification.

For a Grewer oven, no classification is recommended if the on-set temperature for self-heating is > 220 °C (which is 80 °K above the reference temperature of 140°C).

Applicant's summary and conclusion

Conclusions:

The on-set temperature for self-ignition in the Grewer oven was 320 °C, which leaded to a maximum temperature of 550 °C.

Executive summary:

The objective of this study was the screen for the relative self-ignition temperature of the test item according to VDI 2263, sheet 1 and UN Class 4, Division 4.2. The test item was heated in a Grewer-oven. The on-set temperature for self-ignition was at approx. 320 °C, which led to a maximum temperature of 550 °C. For a Grewer oven, no classification is recommended if the on-set temperature for self-heating is > 220 °C (which is 80 °K above the reference temperature of 140°C). Since the on-set temperature is above the cut-off for classification, no classification is required.