Registration Dossier
Registration Dossier
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EC number: 240-040-8 | CAS number: 15901-40-3
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
Description of first aid measures
General information:
In case of accident or if you feel unwell seek medical advice immediately (show the label if possible).
After contact with the eyes:
Rinse immediately with plenty of water for 10-15 minutes and seek medical advice. Keep eyelids well open to rinse the whole eye
surface and eyelids with water. Continue to bathe eyes during transport to medical practitioner.
After contact with the skin:
Wash with plenty of water or soap and water; immediately remove all contaminated clothing. Seek medical advice and clearly
identify substance.
After inhalation:
Provide fresh air. Seek medical advice and clearly identify substance.
After swallowing:
If conscious, give several small portions of water to drink. Do not induce vomiting. Seek medical advice immediately and produce
the label or packaging.
Most important symptoms and effects, both acute and delayed
Any relevant information can be found in other parts of this section.
Indication of any immediate medical attention and special treatment needed
Further toxicology information must be observed.
General information:
In case of accident or if you feel unwell seek medical advice immediately (show the label if possible).
After contact with the eyes:
Rinse immediately with plenty of water for 10-15 minutes and seek medical advice. Keep eyelids well open to rinse the whole eye
surface and eyelids with water. Continue to bathe eyes during transport to medical practitioner.
After contact with the skin:
Wash with plenty of water or soap and water; immediately remove all contaminated clothing. Seek medical advice and clearly
identify substance.
After inhalation:
Provide fresh air. Seek medical advice and clearly identify substance.
After swallowing:
If conscious, give several small portions of water to drink. Do not induce vomiting. Seek medical advice immediately and produce
the label or packaging.
Most important symptoms and effects, both acute and delayed
Any relevant information can be found in other parts of this section.
Indication of any immediate medical attention and special treatment needed
Further toxicology information must be observed.
Fire-fighting measures
Extinguishing media
Suitable extinguishing media:
extinguishing powder , foam , carbon dioxide .
Extinguishing media which must not be used for safety reasons:
water .
Special hazards arising from the substance or mixture
Hazardous combustion products: nitrous gases . Hazardous decomposition products: corrosive substances .
Advice for firefighters
Special protective equipment for fire fighting:
Use respiratory protection independent of recirculated air.
Suitable extinguishing media:
extinguishing powder , foam , carbon dioxide .
Extinguishing media which must not be used for safety reasons:
water .
Special hazards arising from the substance or mixture
Hazardous combustion products: nitrous gases . Hazardous decomposition products: corrosive substances .
Advice for firefighters
Special protective equipment for fire fighting:
Use respiratory protection independent of recirculated air.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
Wear personal protection equipment. Avoid inhaling mists and vapours. Avoid contact with eyes and skin. Keep
unprotected persons away. Do not walk through spilled material.
Environmental precautions
Prevent material from entering sewers or surface waters. Contain any fluid that runs out using suitable material (e.g. earth).
Methods and material for containment and cleaning up
Absorb with a liquid binding material such as diatomaceous earth and dispose of according to local/state/federal regulations. Do
not flush away with water. Contain larger amounts and pump up into suitable containers.
Further information:
Eliminate all sources of ignition.
Reference to other sections
Relevant information in other sections has to be considered. This applies in particular for information given on personal protective
equipment and on disposal.
Wear personal protection equipment. Avoid inhaling mists and vapours. Avoid contact with eyes and skin. Keep
unprotected persons away. Do not walk through spilled material.
Environmental precautions
Prevent material from entering sewers or surface waters. Contain any fluid that runs out using suitable material (e.g. earth).
Methods and material for containment and cleaning up
Absorb with a liquid binding material such as diatomaceous earth and dispose of according to local/state/federal regulations. Do
not flush away with water. Contain larger amounts and pump up into suitable containers.
Further information:
Eliminate all sources of ignition.
Reference to other sections
Relevant information in other sections has to be considered. This applies in particular for information given on personal protective
equipment and on disposal.
Handling and storage
Precautions for safe handling
Precautions for safe handling:
Ensure adequate ventilation. Avoid contact with acids.
Precautions against fire and explosion:
Take precautionary measures against electrostatic charging. Cool endangered containers with water. Flammable vapors may
accumulate and form explosive mixtures with air in containers, process vessels, including partial, empty and uncleaned containers
and vessels, or other enclosed spaces. Keep away from open flames, heat and sparks.
Conditions for safe storage, including any incompatibilities
Conditions for storage rooms and vessels:
none known .
Advice for storage of incompatible materials:
not applicable
Further information for storage:
Store in a dry and cool place. Protect against moisture. Do not store in open air. Keep container tightly closed.
Specific end use(s)
No data
Precautions for safe handling:
Ensure adequate ventilation. Avoid contact with acids.
Precautions against fire and explosion:
Take precautionary measures against electrostatic charging. Cool endangered containers with water. Flammable vapors may
accumulate and form explosive mixtures with air in containers, process vessels, including partial, empty and uncleaned containers
and vessels, or other enclosed spaces. Keep away from open flames, heat and sparks.
Conditions for safe storage, including any incompatibilities
Conditions for storage rooms and vessels:
none known .
Advice for storage of incompatible materials:
not applicable
Further information for storage:
Store in a dry and cool place. Protect against moisture. Do not store in open air. Keep container tightly closed.
Specific end use(s)
No data
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- 2735
Shipping information
- Proper shipping name and description:
- Amine, flüssig, ätzend, n.a.g. (Enthält Trialkyl-methylsilantriamin)
SpecialProvisionsopen allclose all
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- 2735
Shipping information
- Proper shipping name and description:
- Amine, flüssig, ätzend, n.a.g. (Enthält Trialkyl-methylsilantriamin)
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- 2735
Shipping information
- Proper shipping name and description:
- Amines, liquid, corrosive, n.o.s. (contains Trialkyl-methylsilane-triamine)
Special provisions / remarks
- Remarks:
- Bulk transport in tankers is not intended.
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- 2735
Shipping information
- Proper shipping name and description:
- Amines, liquid, corrosive, n.o.s. (contains Trialkyl-methylsilane-triamine)
Remarksopen allclose all
SpecialProvisionsopen allclose all
Exposure controls / personal protection
Control parameters
Maximum airborne concentrations at the workplace:
CAS No. Material Type mg/m3 ppm
108-91-8 Cyclohexylamine OEL 41,0 10,0
108-88-3 Toluene OEL 191,0 50,0
Exposure controls
Exposure in the work place limited and controlled
General protection and hygiene measures:
Do not eat, drink or smoke when handling. Avoid contact with eyes and skin. Do not breathe vapours.
Personal protection equipment:
Respiratory protection
In case of long or strong exposure: gas mask filter K .
Eye protection
tight fitting protective goggles . Provide work station with eye bathing equipment.
Hand protection
Protective gloves made of butyl rubber . Gloves suitable for up to 60 minutes' use.
Skin protection
protective clothing . Where there is risk of splashing: protective clothing, protective goggles/face protection .
Exposure to the environment limited and controlled
Prevent material from entering surface waters and soil.
Maximum airborne concentrations at the workplace:
CAS No. Material Type mg/m3 ppm
108-91-8 Cyclohexylamine OEL 41,0 10,0
108-88-3 Toluene OEL 191,0 50,0
Exposure controls
Exposure in the work place limited and controlled
General protection and hygiene measures:
Do not eat, drink or smoke when handling. Avoid contact with eyes and skin. Do not breathe vapours.
Personal protection equipment:
Respiratory protection
In case of long or strong exposure: gas mask filter K .
Eye protection
tight fitting protective goggles . Provide work station with eye bathing equipment.
Hand protection
Protective gloves made of butyl rubber . Gloves suitable for up to 60 minutes' use.
Skin protection
protective clothing . Where there is risk of splashing: protective clothing, protective goggles/face protection .
Exposure to the environment limited and controlled
Prevent material from entering surface waters and soil.
Stability and reactivity
Reactivity; Chemical stability; Possibility of hazardous reactions
If stored and handled in accordance with standard industrial practices no hazardous reactions are known.
Relevant information can possibly be found in other parts of this section.
Conditions to avoid
moisture
Incompatible materials
Reacts with: water . Reaction causes the formation of: amines .
Hazardous decomposition products
Under the effect of humidity, water and protic agents: cyclohexylamine .
If stored and handled in accordance with standard industrial practices no hazardous reactions are known.
Relevant information can possibly be found in other parts of this section.
Conditions to avoid
moisture
Incompatible materials
Reacts with: water . Reaction causes the formation of: amines .
Hazardous decomposition products
Under the effect of humidity, water and protic agents: cyclohexylamine .
Disposal considerations
Waste treatment methods
Material
Recommendation:
Dispose of according to regulations by incineration in a special waste incinerator. Observe local/state/federal regulations.
Uncleaned packaging
Recommendation:
Completely discharge containers (no tear drops, no powder rest, scraped carefully). Containers may be recycled or re-used.
Observe local/state/federal regulations. Uncleaned packaging should be treated with the same precautions as the material.
Waste Disposal Legislation Ref.No.(EC)
It is not possible to determine a waste code for this product in accordance with the European Waste Catalogue (EWC) since it is
only possible to classify it according to how it is used by the customer. The waste code is to be determined within the EU in liaison
with the waste-disposal operator.
Material
Recommendation:
Dispose of according to regulations by incineration in a special waste incinerator. Observe local/state/federal regulations.
Uncleaned packaging
Recommendation:
Completely discharge containers (no tear drops, no powder rest, scraped carefully). Containers may be recycled or re-used.
Observe local/state/federal regulations. Uncleaned packaging should be treated with the same precautions as the material.
Waste Disposal Legislation Ref.No.(EC)
It is not possible to determine a waste code for this product in accordance with the European Waste Catalogue (EWC) since it is
only possible to classify it according to how it is used by the customer. The waste code is to be determined within the EU in liaison
with the waste-disposal operator.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
