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Auto flammability

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Administrative data

Endpoint:
auto-ignition temperature, other
Remarks:
thermal stability
Type of information:
experimental study
Adequacy of study:
supporting study
Study period:
2018-02-19 to 2018-03-09
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Cross-reference
Reason / purpose for cross-reference:
reference to same study
Reference
Endpoint:
melting point/freezing point
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2018-02-19 to 2018-03-09
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Reason / purpose for cross-reference:
reference to same study
Qualifier:
according to guideline
Guideline:
OECD Guideline 102 (Melting point / Melting Range)
Version / remarks:
1995
Deviations:
no
Qualifier:
according to guideline
Guideline:
EU Method A.1 (Melting / Freezing Temperature)
Version / remarks:
2008
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Remarks:
signed 2017-02-28
Type of method:
differential scanning calorimetry
Atm. press.:
>= 954.1 - <= 996.5 hPa
Decomposition:
yes
Decomp. temp.:
ca. 440 °C
Sublimation:
no
Remarks on result:
other: no melting/boiling point up to the decomposition at approx. 440 °C

In DSC runs PN15120 and PN15121 the test item showed a small exothermic effect in the temperature range of 440 – 460 °C, with a decomposition energy of approx. -20 J/g. An endothermic effect was detected in the temperature range of 460 – 480 °C. In DSC runs PN15139 and PN15140 the test item only showed an endothermic effect in the temperature range of 460 – 500 °C. No further thermal effects were observed up to the test end temperature of 500 and 600 °C, respectively.

Results of the DSC-measurements

No. Sample weight [mg] Onset of Effect [°C] Range of effect [°C] Weight loss [mg] Atmospheric pressure [hPa]
PN15120

11.95

---

461.79

440 – 460 (exo)
460 – 480 (endo)

3.27

984.1

PN15121

14.37

---

461.31

440 – 460 (exo)

460 – 480 (endo)

2.88

984.1

PN15139

12.18

463.63

460 – 500 (endo)

2.98

996.5

PN15140

16.68

462.15

460 – 490 (endo)

3.92

996.5

Due to the fact the test item showed a decomposition before reaching its melting point, the test item has no melting or boiling point up to its decomposition starting at a temperature of approx. 440 °C.

Conclusions:
The test item barium di(acetate) has no melting and point up to its decomposition starting at a temperature of approx. 440 °C at atmospheric pressure (1013 hPa) as determined by differential scanning calorimetry according to Regulation EC No. 440/2008 Method A.1.,A.2. and OECD Test Guideline 102 (1995), 103 (1995).

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2018

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
other: OECD Test Guideline 113: Thermal Stability
Version / remarks:
1981
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Remarks:
signed 2017-02-28

Test material

Constituent 1
Chemical structure
Reference substance name:
Barium di(acetate)
EC Number:
208-849-0
EC Name:
Barium di(acetate)
Cas Number:
543-80-6
Molecular formula:
Ba(C2H3O2)2
IUPAC Name:
barium di(acetate)
Test material form:
solid: particulate/powder
Details on test material:
- State of aggregation: white solid (powder)

Results and discussion

Auto-ignition temperature (liquids / gases)
Remarks on result:
not measured/tested

Any other information on results incl. tables

In the temperature range of 450 – 460 °C a small exothermic effect was observed, with a decomposition energy of -10 J/g. An endothermic effect was detected in the temperature range of 460 – 480 °C. The test was terminated at 600 °C.

Results of the DSC-measurement

No. Sample weight [mg] Start [°C] Energy [J/g]
PN1496 7.16

450 (exothermic)

460 (endothermic)

-10

100

PN14965 10.68

450 (exothermic)

460 (endothermic)

-10

100

Applicant's summary and conclusion

Conclusions:
The thermal stability of the test item Barium di(acetate) showed a small exothermic effect in the temperature range of 450 – 460 °C, with a decomposition energy of -10 J/g directly followed by an endotermic effect in the temperature range of 460 – 480 °C, according to OECD Test Guideline 113 (1981)