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Link to relevant study record(s)

Reference
Endpoint:
relative self-ignition temperature (solids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2016-11-23 to 2016-11-25
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.16 (Relative Self-Ignition Temperature for Solids)
Version / remarks:
Commission Directive 92/69/EEC, Commission Regulation (EC) No. 440/2008
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Key result
Remarks on result:
no self-ignition observed up to the melting point

Results

Assay No. 1

Duration of the test: 794.5 min

Rate: 0.50°C/min

Observations:                   

At the start of the test, the test item was a white powder.

At the end of the test, the cube was empty, the test item melted

The plot/curve is shown in figure attached (Graph 1)

 

Assay No. 2

Duration of the test: 796.5 min

Rate: 0.50°C/min

Observations

At the start of the test, the test item was a white powder.

At the end of the test, the cube was empty, the test item melted

The plot/curve is shown in figure attached (Graph 2)

Conclusion

No self-ignition temperature of the test item was observed up to the melting point at about 200°C (corresponding to the small endothermic peak).

Conclusions:
No self-ignition temperature of the test item was observed up to the melting point at about 200°C using a relevant test method and in compliance with GLP. The result is considered to be reliable.

Description of key information

Self-ignition temperature: no self-ignition up to the melting point of 200°C (EU Method A.16)

Key value for chemical safety assessment

Additional information

The self-ignition temperature of the substance was assessed in a study that was conducted in accordance with EU Method A.16 and in compliance with GLP. During the study, no self-ignition temperature of the test item was observed up to the melting point at about 200°C. The result is considered to be reliable and is used as key study.

A minimum cloud ignition temperature value of 590°C was determined for the milled sample (<63 µm) of the substance in accordance with BS EN 50281-2-1:1999.