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Administrative data

First-aid measures

General advice:
In the case of accident or if you feel unwell, seek medical advice immediately.
When symptoms persist or in all cases of doubt seek medical advice.

Protection of first-aiders:
First Aid responders should pay attention to self-protection, and use the recommended personal protective equipment when the potential for exposure exists.

IIf inhaled:
If inhaled, remove to fresh air.
If not breathing, give artificial respiration.
If breathing is difficult, give oxygen.
Get medical attention.


In case of skin contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Get medical attention.
Wash clothing before reuse.
Thoroughly clean shoes before reuse.



In case of eye contact:
Flush eyes with water as a precaution.
Get medical attention if irritation develops and persists.



If swallowed:
If swallowed, DO NOT induce vomiting.
Get medical attention.
Rinse mouth thoroughly with water.
Never give anything by mouth to an unconscious person.




Most important symptoms and effects, both acute and delayed

Risks:
Causes skin irritation.
Toxic if inhaled.
Suspected of damaging fertility.
Causes damage to organs.


Indication of any immediate medical attention and special treatment needed
Treatment
Treat symptomatically and supportively.

Fire-fighting measures

Extinguishing media
Suitable extinguishing media:
Water spray
Alcohol-resistant foam
Carbon dioxide (CO2)
Dry chemical

Unsuitable extinguishing media:
None known.

Special hazards arising from the substance or mixture
Specific hazards during fire-fighting: Exposure to combustion products may be a hazard to health.

Hazardous combustion products:
Hydrogen fluoride
carbonyl fluoride
potentially toxic fluorinated compounds
aerosolized particulates
Carbon oxides
Fluorine compounds
Iodine compounds


Advice for firefighters
Special protective equipment for firefighters: In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment.

Specific extinguishing methods:
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Use water spray to cool unopened containers.
Remove undamaged containers from fire area if it is safe to do so.
Evacuate area.

Accidental release measures

Environmental precautions:
Discharge into the environment must be avoided.
Prevent further leakage or spillage if safe to do so.
Prevent spreading over a wide area (e.g. by containment or oil barriers).
Retain and dispose of contaminated wash water.
Local authorities should be advised if significant spillages cannot be contained.

6.3 Methods and material for containment and cleaning up
Methods for cleaning up:
Soak up with inert absorbent material.
For large spills, provide diking or other appropriate containment to keep material from spreading. If diked material can be pumped, store recovered material in appropriate container.
Clean up remaining materials from spill with suitable absorbent.
Local or national regulations may apply to releases and disposal of this material, as well as those materials and items employed in the clean-up of releases. You will need to determine which regulations are applicable.

Handling and storage

Technical measures: See Engineering measures under EXPOSURE CONTROLS/PERSONAL PROTECTION section.

Local/Total ventilation: Use with local exhaust ventilation.

Advice on safe handling:
Do not get on skin or clothing.
Do not breathe vapours or spray mist.
Do not swallow.
Avoid contact with eyes.
Handle in accordance with good industrial hygiene and safety practice, based on the results of the workplace exposure assessment
Keep container tightly closed.
Take care to prevent spills, waste and minimize release to the environment.

Hygiene measures:
Ensure that eye flushing systems and safety showers are located close to the working place.
When using do not eat, drink or smoke.
Wash contaminated clothing before re-use.

Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers:
Keep in properly labelled containers.
Store locked up.
Keep tightly closed.
Keep in a cool, well-ventilated place.
Store in accordance with the particular national regulations.

Advice on common storage:
Do not store with the following product types:
Strong oxidizing agents
Organic peroxides
Explosives
Gases

Transport information

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Marine transport (UN RTDG/IMDG)

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Exposure controls / personal protection

Engineering measures
Processing may form hazardous compounds.
Minimize workplace exposure concentrations.
Use with local exhaust ventilation.


Personal protective equipment

Eye protection:Wear the following personal protective equipment: Safety glasses. Equipment should conform to BS EN 166


Hand protection: Material :Chemical-resistant gloves
Remarks: Choose gloves to protect hands against chemicals depend-ing on the concentration and quantity of the hazardous sub-stance and specific to place of work. Breakthrough time is not determined for the product. Change gloves often! For special applications, we recommend clarifying the re-sistance to chemicals of the aforementioned protective gloves with the glove manufacturer. Wash hands before breaks and at the end of workday.


Skin and body protection:
Select appropriate protective clothing based on chemical resistance data and an assessment of the local exposure potential.
Skin contact must be avoided by using impervious protec-tive clothing (gloves, aprons, boots, etc).

Respiratory protection: Use respiratory protection unless adequate local exhaust ventilation is provided or exposure assessment demonstrates that exposures are within recommended exposure guidelines.
Filter type: Combined acidic gas/vapour and organic vapour type (AE)

Stability and reactivity

Reactivity
Not classified as a reactivity hazard.

Chemical stability
Stable under normal conditions.

Possibility of hazardous reactions
Hazardous reactions: Can react with strong oxidizing agents. Hazardous decomposition products will be formed at elevated temperatures.

Conditions to avoid
Conditions to avoid: None known.

Incompatible materials
Materials to avoid: Oxidizing agents

Hazardous decomposition products
Thermal decomposition:
Hydrofluoric acid
Carbonyl difluoride
Carbon dioxide
Carbon monoxide

Disposal considerations

Waste treatment methods
Product : Dispose of in accordance with local regulations.
According to the European Waste Catalogue, Waste Codes are not product specific, but application specific.
Waste codes should be assigned by the user, preferably in discussion with the waste disposal authorities.

Contaminated packaging: Empty containers should be taken to an approved waste handling site for recycling or disposal.
If not otherwise specified: Dispose of as unused product.

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