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Diss Factsheets

Physical & Chemical properties

Auto flammability

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Administrative data

Link to relevant study record(s)

Reference
Endpoint:
auto-ignition temperature (liquids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
From July 14, 2017 to November 13, 2017
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
Deviations:
not specified
GLP compliance:
yes
Key result
Auto-ignition temperature:
ca. 357 °C
Atm. press.:
ca. 102 kPa

Results

The autoignition temperature of test substance has been determined to be 357°C.

Hot flame autoignition temperature (AIT,°C)

357

Volume Injected (cm3)

0.10

Ignition delay time (s)

8.9

Observed exotherms

28 K at 355°C with injected quantity 0.30 cm3

Barometric Pressure (kPa)

102.0

 

Full test results

 

Volume Injected (cm3)

Inner Flask Temp (°C)

Ignition?

yes (y) / no (n)

DelayTime (s)

Exotherm(°C)

Clean Vessel

0.10

350

N

-

10

0.10

400

Y

6.7

-

0.10

390

Y

8.5

-

0.10

380

Y

6.9

-

0.10

370

Y

10.3

-

0.10

360

N

-

21

Clean Vessel

0.10

365

Y

4.5

-

0.10

360

Y

6.8

-

0.10

355

N

-

18

0.10

357

N

-

16

Clean Vessel

0.10

357

Y

8.9

-

0.10

355

N

-

12

0.07

355

N

-

12

0.05

355

N

-

10

0.20

355

N

-

24

Clean Vessel

0.30

355

N

-

28

0.40

355

N

-

24

0.20

355

N

-

25

No cool flames observed

Conclusions:
Under the study conditions, auto ignition temperature of the test substance was determined to be 357°C at 102 kPa.
Executive summary:

A study was conducted to determine the auto ignition temperature of the test substance, according to the EU Method A.15, in compliance with GLP. Under the study conditions, auto ignition temperature of the test substance was determined to be 357°C at 102 kPa (Chilworth, 2017).

Description of key information

The auto ignition temperature of the test substance was determined according to EU Method A.15 (Chilworth, 2017).

Key value for chemical safety assessment

Autoflammability / Self-ignition temperature at 101 325 Pa:
357 °C

Additional information

Value used for CSA: 357 °C at 102 kPa.