Registration Dossier

Diss Factsheets

Administrative data

First-aid measures

As a general rule, in case of doubt or if symptoms persist, always call a doctor.
NEVER induce swallowing by an unconscious person.
4.1. Description of first aid measures
In the event of exposure by inhalation :
In the event of massive inhalation, remove the person exposed to fresh air. Keep warm and at rest.
If the person is unconscious, place in recovery position. Notify a doctor in all events, to ascertain whether observation and supportive hospital
care will be necessary.
If breathing is irregular or has stopped, effect mouth-to-mouth resuscitation and call a doctor.
In the event of splashes or contact with eyes :
Wash thoroughly with soft, clean water for 15 minutes holding the eyelids open.
If there is any redness, pain or visual impairment, consult an ophthalmologist.
In the event of splashes or contact with skin :
Remove contaminated clothing and wash the skin thoroughly with soap and water or a recognised cleaner.
Remove any soiled or splashed clothing immediately.
Watch out for any remaining product between skin and clothing, watches, shoes, etc.
In the event of an allergic reaction, seek medical attention.
If the contaminated area is widespread and/or there is damage to the skin, a doctor must be consulted or the patient transferred to hospital.
In the event of swallowing :
Do not give the patient anything orally.
In the event of swallowing, if the quantity is small (no more than one mouthful), rinse the mouth with water, administer activated medical charcoal
and consult a doctor.
Seek medical attention immediately, showing the label.
If swallowed accidentally, call a doctor to ascertain whether observation and hospital care will be necessary. Show the label.
4.2. Most important symptoms and effects, both acute and delayed
No data available.
4.3. Indication of any immediate medical attention and special treatment needed
No data available.

Fire-fighting measures

Non-flammable.
5.1. Extinguishing media
Suitable methods of extinction
In the event of a fire, use :
- sprayed water or water mist
- carbon dioxide (CO2)
- dry chemical agents
- foam
5.2. Special hazards arising from the substance or mixture
A fire will often produce a thick black smoke. Exposure to decomposition products may be hazardous to health.
Do not breathe in smoke.
In the event of a fire, the following may be formed :
- carbon monoxide (CO)
- carbon dioxide (CO2)
5.3. Advice for firefighters
Due to the toxicity of the gas emitted on thermal decomposition of the products, fire-fighting personnel are to be equipped with autonomous
insulating breathing apparatus.

Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
Consult the safety measures listed under headings 7 and 8.
For non first aid worker
Avoid inhaling the vapors.
Avoid any contact with the skin and eyes.
If a large quantity has been spilt, evacuate all personnel and only allow intervention by trained operators equipped with safety apparatus.
For first aid worker
First aid workers will be equipped with suitable personal protective equipment (See section 8).
6.2. Environmental precautions
Contain and control the leaks or spills with non-combustible absorbent materials such as sand, earth, vermiculite, diatomaceous earth in drums
for waste disposal.
Prevent any material from entering drains or waterways.
6.3. Methods and material for containment and cleaning up
Clean preferably with a detergent, do not use solvents.
6.4. Reference to other sections
No data available.

Handling and storage

Requirements relating to storage premises apply to all facilities where the mixture is handled.
Individuals with a history of skin sensitisation should not, under any circumstance, handle this mixture.
7.1. Precautions for safe handling
Always wash hands after handling.
Remove and wash contaminated clothing before re-using.
Fire prevention :
Handle in well-ventilated areas.
Prevent access by unauthorised personnel.
Recommended equipment and procedures :
For personal protection, see section 8.
Observe precautions stated on label and also industrial safety regulations.
Avoid inhaling vapors.
Avoid inhaling vapors. Carry out any industrial operation which may give rise to this in a sealed apparatus.
Provide vapor extraction at the emission source and also general ventilation of the premises.
Also provide breathing apparatus for certain short tasks of an exceptional nature and for emergency interventions.
In all cases, recover emissions at source.
Prohibited equipment and procedures :
No smoking, eating or drinking in areas where the mixture is used.
7.2. Conditions for safe storage, including any incompatibilities
No data available.
Storage
Keep the container tightly closed in a dry, well-ventilated place.
Keep away from food and drink, including those for animals.
Packaging
Always keep in packaging made of an identical material to the original.
7.3. Specific end use(s)
No data available.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
Exempt from transport classification and labelling.
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Inland waterway transport (UN RTDG/ADN(R))

UN number:
Exempt from transport classification and labelling.
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Marine transport (UN RTDG/IMDG)

UN number:
Exempt from transport classification and labelling.
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Air transport (UN RTDG/ICAO/IATA)

UN number:
Exempt from transport classification and labelling.
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Exposure controls / personal protection

8.1. Control parameters
Occupational exposure limits :
- USA / AIHA WEEL (American Industrial Hygiene Association, Workplace Environmental Exposure Limit, 2010) :
CAS TWA : STEL : Ceiling : Definition : Criteria :
100-52-7 2 ppm 4 ppm 4 ppm DSEN
8.2. Exposure controls
Personal protection measures, such as personal protective equipment
Pictogram(s) indicating the obligation of wearing personal protective equipment (PPE) :
Use personal protective equipment that is clean and has been properly maintained.
Store personal protective equipment in a clean place, away from the work area.
Never eat, drink or smoke during use. Remove and wash contaminated clothing before re-using. Ensure that there is adequate ventilation,
especially in confined areas.
- Eye / face protection
Avoid contact with eyes.
Use eye protectors designed to protect against liquid splashes
Before handling, wear safety goggles in accordance with standard EN166.
- Hand protection
Wear suitable protective gloves in the event of prolonged or repeated skin contact.
Use suitable protective gloves that are resistant to chemical agents in accordance with standard EN374.
Gloves must be selected according to the application and duration of use at the workstation.
Protective gloves need to be selected according to their suitability for the workstation in question : other chemical products that may be handled,
necessary physical protections (cutting, pricking, heat protection), level of dexterity required.
Recommended properties :
- Impervious gloves in accordance with standard EN374
- Body protection
Avoid skin contact.
Wear suitable protective clothing.
Suitable type of protective clothing :
In the event of substantial spatter, wear liquid-tight protective clothing against chemical risks (type 3) in accordance with EN14605 to prevent skin
contact.
In the event of a risk of splashing, wear protective clothing against chemical risks (type 6) in accordance with EN13034 to prevent skin contact.
Work clothing worn by personnel shall be laundered regularly.
After contact with the product, all parts of the body that have been soiled must be washed.
- Respiratory protection
Avoid breathing vapours.
If the ventilation is insufficient, wear appropriate breathing apparatus.
When workers are confronted with concentrations that are above occupational exposure limits, they must wear a suitable, approved, respiratory
protection device.
Anti-gas and vapour filter(s) (Combined filters) in accordance with standard EN14387 :
- A1 (Brown)

Stability and reactivity

10.1. Reactivity
No data available.
10.2. Chemical stability
This mixture is stable under the recommended handling and storage conditions in section 7.
10.3. Possibility of hazardous reactions
No data available.
10.4. Conditions to avoid
Avoid :
- heat
- contact with air
10.5. Incompatible materials
Keep away from :
- metals
- alkalis
- oxidising agents
- oxygen
10.6. Hazardous decomposition products
The thermal decomposition may release/form :
- carbon monoxide (CO)
- carbon dioxide (CO2)

Disposal considerations

Proper waste management of the mixture and/or its container must be determined in accordance with Directive 2008/98/EC.
13.1. Waste treatment methods
Do not pour into drains or waterways.
Waste :
Waste management is carried out without endangering human health, without harming the environment and, in particular without risk to water, air,
soil, plants or animals.
Recycle or dispose of waste in compliance with current legislation, preferably via a certified collector or company.
Do not contaminate the ground or water with waste, do not dispose of waste into the environment.
Soiled packaging :
Empty container completely. Keep label(s) on container.
Give to a certified disposal contractor.

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