Registration Dossier

Administrative data

First-aid measures

Inhalation:
Remove person to fresh air. If you feel unwell, get medical attention.

Skin Contact:
Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention.

Eye Contact:
Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical attention.

If Swallowed:
Rinse mouth. If you feel unwell, get medical attention.

Most important symptoms and effects, both acute and delayed:
See SDS Section 11.1. Information on toxicological effects.

Indication of any immediate medical attention and special treatment required
Not applicable

Fire-fighting measures

Extinguishing media
Non-combustible. Use a fire fighting agent suitable for surrounding fire. Material will not burn.

Special hazards arising from the substance or mixture
Exposure to extreme heat can give rise to thermal decomposition.

Advice for fire-fighters
When fire fighting conditions are severe and total thermal decomposition of the product is possible, wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. No unusual effects are anticipated during fire extinguishing operations. Avoid breathing the products and substances that may result from the thermal decomposition of the product or the other substances in the fire zone. Keep containers cool with water spray when exposed to fire to avoid rupture.

Accidental release measures

Personal precautions, protective equipment and emergency procedures
Evacuate area. Ventilate the area with fresh air.

Environmental precautions
Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water.

Methods and material for containment and cleaning up
Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with water. Seal the container. Dispose of collected material as soon as possible.

Reference to other sections
Refer to SDS Section 8 and Section 13 for more information.

Handling and storage

Precautions for safe handling
Avoid breathing dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse.

Conditions for safe storage including any incompatibilities
Store away from heat. Store away from strong bases. Store away from areas where product may come into contact with food or pharmaceuticals.

Specific end use(s)
See information in SDS Section 7.1 and 7.2 for handling and storage recommendations. See SDS Section 8 for exposure controls and personal protection recommendations.

Transport information

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Marine transport (IMDG)

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Exposure controls / personal protection

In addition, refer to the SDS annex for more information.

Engineering controls

Provide appropriate local exhaust when product is heated. For those situations where the material might be exposed to extreme overheating due to misuse or equipment failure, use with appropriate local exhaust ventilation sufficient to maintain levels of thermal decomposition products below their exposure guidelines. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment.

Personal protective equipment (PPE)

Eye/face protection
Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles

Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity.
Gloves made from the following material(s) are recommended:

Material Thickness (mm) Breakthrough Time
Polymer laminate No data available No data available


If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an exposure assessment. The following protective clothing material(s) are recommended: Apron - polymer laminate

Respiratory protection
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure:
During heating:
Use a positive pressure supplied-air respirator if there is a potential for over exposure from an uncontrolled release, exposure levels are not known, or under any other circumstances where air-purifying respirators may not provide adequate protection.

Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates
For questions about suitability for a specific application, consult with your respirator manufacturer.

Environmental exposure controls
Refer to SDS Annex

Stability and reactivity

Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section.

Chemical stability
Stable.

Possibility of hazardous reactions
Hazardous polymerization will not occur.

Conditions to avoid
None known.

Incompatible materials
Strong bases

Hazardous decomposition products
Substance Condition
Carbon monoxide At Elevated Temperatures
Carbon dioxide At Elevated Temperatures
Hydrogen Fluoride At Elevated Temperatures
Ammonia At Elevated Temperatures
Toxic Vapor, Gas, Particulate At Elevated Temperatures

If the product is exposed to extreme condition of heat from misuse or equipment failure, toxic decomposition products that include hydrogen fluoride and perfluoroisobutylene can occur. Extreme heat arising from situations such as misuse or equipment failure can generate hydrogen fluoride as a decomposition product.

Disposal considerations

Waste treatment methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations.

Dispose of waste product in a permitted industrial waste facility. As a disposal alternative, incinerate in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. Combustion products will include halogen acid (HCl/HF/HBr). Facility must be capable of handling halogenated materials. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities.

The coding of a waste stream is based on the application of the product by the consumer. Since this is out of the control of 3M, no waste code(s) for products after use will be provided. Please refer to the European Waste Code (EWC - 2000/532/CE and amendments) to assign the correct waste code to your waste stream. Ensure national and/or regional regulations are complied with and always use a licensed waste contractor

EU waste code (product as sold)
070107* Halogenated still bottoms and reaction residues