Registration Dossier

Data platform availability banner - registered substances factsheets

Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Melting point / freezing point

Currently viewing:

Administrative data

Link to relevant study record(s)

Reference
Endpoint:
melting point/freezing point
Data waiving:
study technically not feasible
Justification for data waiving:
other:

Description of key information

OO-tert-butyl monoperoxymaleate in its marketed form is a suspension at 20 °C. OO-tert-butyl monoperoxymaleate is a solid, but due to the substance's thermal instability (SADT +55 °C) it is only available together with a liquid phlegmatizer. According to Guidance on Information Requirements and Chemical Safety Assessment Chapter R.7a: Endpoint specific guidance, Chapter R.7.1.2, the “melting point / freezing point” is defined as "the temperature at which the phase transition from the solid to the liquid state occurs at atmospheric pressure and this temperature ideally corresponds to the freezing temperature”.

This definition is not applicable to the test item, which is a suspension at 20 °C. The study is disregarded because for the determination of the actual melting point of the active ingredient OO-tert-butyl monoperoxymaleate, which is the solid component of the suspension, the test item needs to be heated. During heating, solving effects of the liquid phlegmatizer may occur and the differentiation between a real phase transition (melting) and solving is not possible. Additionally, the test item is only stable up to a temperature of +55 °C and afterwards decomposes thermally.

Key value for chemical safety assessment

Additional information