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First-aid measures

Description of first aid measures

General advice:

First aider needs to protect himself. Move out of dangerous area. Take off all contaminated clothing immediately. Victim to lie down in the recovery position, cover and keep him warm. Call a physician immediately.

Inhalation:

Move to fresh air. Call a physician immediately.

Skin contact:

Take off all contaminated clothing immediately. Wash off immediately with plenty of water. First treatment with calcium gluconate paste. Call a physician immediately.

Eye contact:

Protect unharmed eye. Rinse thoroughly with plenty of water, also under the eyelids. Call a physician immediately.

Ingestion:

A person suspected to have swallowed the substance who is conscious should be given water to drink. Take to a doctor immediately together with this card

Fire-fighting measures

Extinguishing media

Suitable extinguishing media:

Water spray jet

Dry powder

Foam

Carbon dioxide (CO2)

Extinguishing media which shall not be used for safety reasons:

High volume water jet

Special hazards arising from the substance or mixture

Hazardous decomposition products formed under fire conditions.

Pyrolysis products containing fluoride

The product itself does not burn.

Advice for firefighters

Wear self-contained breathing apparatus and protective suit.

No unprotected exposed skin areas.

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Accidental release measures

Personal precautions, protective equipment and emergency procedures

Avoid dust formation. Wear personal protective equipment. Unprotected persons must be kept away.

Environmental precautions

Prevent further leakage or spillage if safe to do so.

Methods and materials for containment and cleaning up

Pick up mechanically and dispose of.

Knock down dust with water spray jet.

Handling and storage

Precautions for safe handling

Advice on safe handling:

Exhaust ventilation at the object is necessary. Plan first aid action before beginning work with this product. Wear personal protective equipment. Avoid formation of respirable particles.

Advice on protection against fire and explosion:

The product itself does not burn. Normal measures for preventive fire protection.

Hygiene measures:

Separate rooms are required for washing, showering and changing clothes. Keep working clothes separately.

Conditions for safe storage, including any incompatibilities

Further information on storage conditions:

Keep only in the original container, tightly closed, in a well ventilated place. Do not leave vessels/containers open Avoid product residues in/on containers

Transport information

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Marine transport (UN RTDG/IMDG)

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Exposure controls / personal protection

Occupational exposure controls

The Personal Protective Equipment must be in accordance with EN standards:respirator EN 136, 140, 149; safety glasses EN 166; protective suit: EN 340, 463, 468, 943-1, 943-2; gloves EN 374, safety shoes EN-ISO 20345.

Engineering measures

Jointless smooth floor

Local exhaust

Personal protective equipment

Respiratory protection:

In the case of dust or aerosol formation use respirator with an approved filter.

Hand protection:

Glove material: Fluorinated rubber

Glove thickness: 0,7 mm

Vitoject® 890

Gloves must be inspected prior to use.

Replace when worn.

Remarks:Supplementary note: The specifications are based on information and tests from similar substances by analogy. Due to varying conditions ( e.g.temperature or other strains) it must be considered that the usage of a chemical protective glove in practice may be much shorter than the permeation time determined in accordance with EN 374. Since actual conditions of practical use often deviate from standardised conditions according EN 374 the glove manufacturer reccomends to use the chemical protective glove in practice not longer than 50% of the recomended permeation time. Manufacturer´s directions for use should be observed because of great diversity of types . Suitable gloves tested according EN 374 are supplied e.g. from KCL GmbH, D-36124 Eichenzell, Vertrieb@kcl.de

Eye protection:

Safety goggles

Skin and body protection:

Complete suit protecting against chemicals

Environmental exposure controls

Handle in accordance with local environmental regulations and good industrial practices.

Stability and reactivity

Reactivity

No decomposition if stored and applied as directed.

10.2. Chemical stability

>500 °C

Hazardous decomposition products formed under fire conditions.

10.3. Possibility of hazardous reactions

No dangerous reaction known under conditions of normal use.

10.4. Conditions to avoid

Avoid dust formation.

10.5. Incompatible materials

Contact with strong acids liberates hydrogen fluoride.

10.6. Hazardous decomposition products

Risk of formation of toxic pyrolysis products containing fluorine.

Disposal considerations

Waste treatment methods

Product:

Dispose according to legal requirements.

Packaging:

Legal requirements are to be considered in regard of reuse or disposal of used packaging materials

Further information:

Provisions relating to waste:

EC Directive 2006/12/EC; 2008/98/EEC

Regulation No. 1013/2006

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