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Diss Factsheets

Physical & Chemical properties

Explosiveness

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Administrative data

Endpoint:
explosive properties of explosives
Type of information:
experimental study
Adequacy of study:
supporting study
Study period:
18 Apr 2018
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study

Data source

Referenceopen allclose all

Reference Type:
study report
Title:
Unnamed
Year:
2019
Report date:
2019
Reference Type:
study report
Title:
Unnamed
Year:
2018
Report date:
2018

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
EU Method A.14 (Explosive properties)
GLP compliance:
no

Test material

Constituent 1
Chemical structure
Reference substance name:
2-[(3,5-dimethyl-1H-pyrazole-1-carbonyl)amino]ethyl 2-methylprop-2-enoate
EC Number:
680-413-6
Cas Number:
217437-44-0
Molecular formula:
C12H17N3O3
IUPAC Name:
2-[(3,5-dimethyl-1H-pyrazole-1-carbonyl)amino]ethyl 2-methylprop-2-enoate

Results and discussion

Small-scale preliminary testsopen allclose all
Key result
Parameter:
thermal sensitivity - Koenen test: limiting diameter (mm)
Remarks on result:
not thermal sensitive if heated under defined confinement
Remarks:
Limiting diameter <1 mm
Key result
Parameter:
sensitiveness to impact: impact energy (J)
Remarks on result:
not sensitive to impact using an impact energy of 40 J
Remarks:
Limiting impact energy >50 J

Any other information on results incl. tables

Thermal test result

 

 

Diameter of orifice plate (mm)

Time (seconds)

Type of Fragmentation

Test1

Test2

Test3

Test1

Test2

Test3

1.5

 

 

1.0

300

300

300

300

300

300

No explosion (O)

-

-

No explosion (O)

No explosion (O)

No explosion (O)

 

Where:

Explosion Type O = Tube unchanged

 

Test condition: Temperature: 18 °C; Humidity: 32%

 

Limiting diameter (largest diameter of the orifice at which the result “explosion” is obtained): <1.0 mm

The substance does show no effect on heating under confinement.

 

 

Shock test result

 

Weight (kg)

Height (m)

Impact Energy (J)

1

2

3

4

5

6

5

0.20

0.40

0.60

10

20

30

N

N

N

N

N

N

N

N

N

N

N

N

N

N

N

N

N

N

10

0.40

0.50

40

50

N

N

N

N

N

N

N

N

N

N

N

N

 

Where:

N = no evidence of ignition, explosion or decomposition.

 

Test condition: Temperature: 20 °C; Humidity: 32%

 

1/6 explosion point (lowest impact energy at which at least one “explosion” occurs in six trials): > 50 J

Test result: -

 

 

Conclusion

Based on the chemical structure, Koenen test and BAM test of the test material the result for the explosive properties has been negative.

Applicant's summary and conclusion

Interpretation of results:
study cannot be used for classification
Conclusions:
The substance did not show explosive behaviour neither when heated nor upon mechanical shock.