Registration Dossier
Registration Dossier
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EC number: 237-742-1 | CAS number: 13963-58-1
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
Description of first aid measures
General advice:
First aider needs to protect himself. Move out of dangerous area. Take off all contaminated clothing immediately. Show this safety data sheet to the doctor in attendance.
Inhalation:
If inhaled, remove to fresh air. Call a physician if irritation develops or persists.
Skin contact:
After contact with skin, wash immediately with plenty of water. Get medical attention if irritation develops and persists.
Eye contact:
In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
Ingestion:
If swallowed, DO NOT induce vomiting unless directed to do so by medical personnel. If victim is fully conscious, give a cupful of water. Call a physician.
General advice:
First aider needs to protect himself. Move out of dangerous area. Take off all contaminated clothing immediately. Show this safety data sheet to the doctor in attendance.
Inhalation:
If inhaled, remove to fresh air. Call a physician if irritation develops or persists.
Skin contact:
After contact with skin, wash immediately with plenty of water. Get medical attention if irritation develops and persists.
Eye contact:
In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
Ingestion:
If swallowed, DO NOT induce vomiting unless directed to do so by medical personnel. If victim is fully conscious, give a cupful of water. Call a physician.
Fire-fighting measures
Extinguishing media
Suitable extinguishing media:
Water spray
Foam
Carbon dioxide (CO2)
Dry powder
Extinguishing media which shall not be used for safety reasons:
High volume water jet
Special hazards arising from the substance or mixture
The product is not flammable.
Fire may cause evolution of:
carbon oxides (CO, CO2), nitrogen oxides (NOx).
Cobalt/Cobalt oxides
Hydrogen cyanide (hydrocyanic acid)
Advice for firefighters
Wear self-contained breathing apparatus and protective suit.
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Suitable extinguishing media:
Water spray
Foam
Carbon dioxide (CO2)
Dry powder
Extinguishing media which shall not be used for safety reasons:
High volume water jet
Special hazards arising from the substance or mixture
The product is not flammable.
Fire may cause evolution of:
carbon oxides (CO, CO2), nitrogen oxides (NOx).
Cobalt/Cobalt oxides
Hydrogen cyanide (hydrocyanic acid)
Advice for firefighters
Wear self-contained breathing apparatus and protective suit.
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
Wear personal protective equipment. Unprotected persons must be kept away. Ensure adequate ventilation. Avoid dust formation. Avoid breathing dust. Avoid contact with skin, eyes and clothing.
Environmental precautions
Do not let product enter drains. If the product contaminates rivers and lakes or drains inform respective authorities.
Methods and materials for containment and cleaning up
Use mechanical handling equipment.
Sweep up and shovel into suitable containers for disposal.
Dispose of in accordance with local regulations.
Wear personal protective equipment. Unprotected persons must be kept away. Ensure adequate ventilation. Avoid dust formation. Avoid breathing dust. Avoid contact with skin, eyes and clothing.
Environmental precautions
Do not let product enter drains. If the product contaminates rivers and lakes or drains inform respective authorities.
Methods and materials for containment and cleaning up
Use mechanical handling equipment.
Sweep up and shovel into suitable containers for disposal.
Dispose of in accordance with local regulations.
Handling and storage
Precautions for safe handling
Advice on safe handling:
Exhaust ventilation at the object is necessary. Wear suitable protective clothing and gloves.
Advice on protection against fire and explosion:
Normal measures for preventive fire protection.
Hygiene measures:
Keep working clothes separately. Wash hands before breaks and at the end of workday.
Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers:
Store in original container. Keep containers tightly closed in a dry, cool and well-ventilated place.
Advice on safe handling:
Exhaust ventilation at the object is necessary. Wear suitable protective clothing and gloves.
Advice on protection against fire and explosion:
Normal measures for preventive fire protection.
Hygiene measures:
Keep working clothes separately. Wash hands before breaks and at the end of workday.
Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers:
Store in original container. Keep containers tightly closed in a dry, cool and well-ventilated place.
Transport information
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Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
Control parameters
Occupational exposure limits:
Components Basis / Value type Value / Form of exposure Exceeding Factor Remarks
Tripotassium hexacyanocobaltate
EH40 WEL
TWA
0,1 mg/m3
as Co
TWA - Time weighted average
DNEL/ PNEC-Values
No DNEL-data available.
No PNEC data available.
Exposure controls
Occupational exposure controls
The Personal Protective Equipment must be in accordance with EN standards:respirator EN 136, 140,149; safety glasses EN 166; protective suit: EN 340, 463, 468, 943-1, 943-2; gloves EN 374, 511; safety shoes EN-ISO 20345.
Do not breathe vapours/dust.
Wash hands before breaks and at the end of workday.
Engineering measures
Use with local exhaust ventilation.
Personal protective equipment
Respiratory protection:
In case of insufficient ventilation, wear suitable respiratory equipment.
Hand protection:
Glove material: Natural Latex
Break through time: > 480 min
Glove thickness: 0,6 mm
Lapren®706
Gloves must be inspected prior to use.
Replace when worn.
Remarks:Supplementary note: The specifications are based on information and tests from similar substances by analogy. Due to varying conditions ( e.g.temperature or other strains) it must be considered that the usage of a chemical protective glove in practice may be much shorter than the permeation time determined in accordance with EN 374. Since actual conditions of practical use often deviate from standardised conditions according EN 374 the glove manufacturer reccomends to use the chemical protective glove in practice not longer than 50% of the recomended permeation time. Manufacturer´s directions for use should be observed because of great diversity of types . Suitable gloves tested according EN 374 are supplied e.g. from KCL GmbH, D-36124 Eichenzell, Vertrieb@kcl.de
Eye protection:
Safety glasses with side-shields
Skin and body protection:
Protective suit
Environmental exposure controls
Handle in accordance with local environmental regulations and good industrial practices.
Occupational exposure limits:
Components Basis / Value type Value / Form of exposure Exceeding Factor Remarks
Tripotassium hexacyanocobaltate
EH40 WEL
TWA
0,1 mg/m3
as Co
TWA - Time weighted average
DNEL/ PNEC-Values
No DNEL-data available.
No PNEC data available.
Exposure controls
Occupational exposure controls
The Personal Protective Equipment must be in accordance with EN standards:respirator EN 136, 140,149; safety glasses EN 166; protective suit: EN 340, 463, 468, 943-1, 943-2; gloves EN 374, 511; safety shoes EN-ISO 20345.
Do not breathe vapours/dust.
Wash hands before breaks and at the end of workday.
Engineering measures
Use with local exhaust ventilation.
Personal protective equipment
Respiratory protection:
In case of insufficient ventilation, wear suitable respiratory equipment.
Hand protection:
Glove material: Natural Latex
Break through time: > 480 min
Glove thickness: 0,6 mm
Lapren®706
Gloves must be inspected prior to use.
Replace when worn.
Remarks:Supplementary note: The specifications are based on information and tests from similar substances by analogy. Due to varying conditions ( e.g.temperature or other strains) it must be considered that the usage of a chemical protective glove in practice may be much shorter than the permeation time determined in accordance with EN 374. Since actual conditions of practical use often deviate from standardised conditions according EN 374 the glove manufacturer reccomends to use the chemical protective glove in practice not longer than 50% of the recomended permeation time. Manufacturer´s directions for use should be observed because of great diversity of types . Suitable gloves tested according EN 374 are supplied e.g. from KCL GmbH, D-36124 Eichenzell, Vertrieb@kcl.de
Eye protection:
Safety glasses with side-shields
Skin and body protection:
Protective suit
Environmental exposure controls
Handle in accordance with local environmental regulations and good industrial practices.
Stability and reactivity
Reactivity
Stable under recommended storage conditions.
Chemical stability
No decomposition if used as directed.
Possibility of hazardous reactions
Hazardous polymerisation does not occur.
Conditions to avoid
Avoid dust formation.
Incompatible materials
Strong acids
Hazardous decomposition products
Fire may cause evolution of:
carbon oxides (CO, CO2) and nitrogen oxides (NOx).
Cobalt/Cobalt oxides
Hydrogen cyanide (hydrocyanic acid)
Stable under recommended storage conditions.
Chemical stability
No decomposition if used as directed.
Possibility of hazardous reactions
Hazardous polymerisation does not occur.
Conditions to avoid
Avoid dust formation.
Incompatible materials
Strong acids
Hazardous decomposition products
Fire may cause evolution of:
carbon oxides (CO, CO2) and nitrogen oxides (NOx).
Cobalt/Cobalt oxides
Hydrogen cyanide (hydrocyanic acid)
Disposal considerations
Waste treatment methods
Product:
Dispose according to legal requirements.
Packaging:
Legal requirements are to be considered in regard of reuse or disposal of used packaging materials
Further information:
Provisions relating to waste:
EC Directive 2006/12/EC; 2008/98/EEC
Regulation No. 1013/2006
Product:
Dispose according to legal requirements.
Packaging:
Legal requirements are to be considered in regard of reuse or disposal of used packaging materials
Further information:
Provisions relating to waste:
EC Directive 2006/12/EC; 2008/98/EEC
Regulation No. 1013/2006
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
