Registration Dossier

Diss Factsheets

Physical & Chemical properties

Flash point

Currently viewing:

Administrative data

Link to relevant study record(s)

Reference
Endpoint:
flash point of flammable liquids
Type of information:
experimental study
Adequacy of study:
key study
Study period:
15-08-2013 to 23-10-2013
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: Guideline study performed under GLP. All relevant validity criteria were met.
Qualifier:
according to guideline
Guideline:
EU Method A.9 (Flash-Point)
Deviations:
no
Qualifier:
according to guideline
Guideline:
ISO 3679 (Determination of flash point - Rapid equilibrium closed cup method)
Deviations:
no
Qualifier:
according to guideline
Guideline:
ASTM D3278 (Standard test methods for flash point of liquids by small scale closed-cup apparatus)
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Remarks:
inspected: November 2011 ; signature: March 2012
Type of method:
equilibrium method closed cup
Flash point apparatus:
other: Small Scale Closed-Cup apparatus
Flash point:
123.72 °C
Atm. press.:
101.325 kPa
Remarks on result:
other: 124 ± 2 °C ; Determination completed at 98.2 kPa atmospheric pressure and corrected to 101.325 kPa
Interpretation of results:
GHS criteria not met
Remarks:
EU criteria not met
Conclusions:
The flash point of the test item has been determined to be 124 ± 2 °C at 101.325 kPa.
Executive summary:

The flash point was determined using EU Method A.9 small scale closed cup equilibrium method under GLP. An aliquot of the test item was transferred to the sample cup of the rapid flash tester. The test item sample was heated and allowed to equilibrate at the set temperature. The test flame was introduced into the sample cup for approximately 2 seconds by sliding the cup shutter open. Observations were made for ignition of the vapour. If no ignition occurred, the temperature was increased and the test flame re-introduced. This was repeated until the lowest reproducible temperature at which a flash occurred, using a fresh sample, was determined. The results indicated are representative of the replicated (n ≥ 2) lowest temperature at which the test item measured under the conditions of this study causes the vapour of the liquid to ignite momentarily. Measurements were corrected to 101.325 kPa pressure. The flash point of the test item has been determined to be 124 ± 2 °C at 101.325 kPa.

Description of key information

FP: 124 ± 2 °C at 101.325 kPa, EU Method A.9 - small scale close cup equilibrium method, 2013

Key value for chemical safety assessment

Flash point at 101 325 Pa:
124 °C

Additional information

Key study : EU Method A.9, 2013 : The flash point was determined using EU Method A.9 small scale closed cup equilibrium method under GLP. An aliquot of the test item was transferred to the sample cup of the rapid flash tester. The test item sample was heated and allowed to equilibrate at the set temperature. The test flame was introduced into the sample cup for approximately 2 seconds by sliding the cup shutter open. Observations were made for ignition of the vapour. If no ignition occurred, the temperature was increased and the test flame re-introduced. This was repeated until the lowest reproducible temperature at which a flash occurred, using a fresh sample, was determined. The results indicated are representative of the replicated (n ≥ 2) lowest temperature at which the test item measured under the conditions of this study causes the vapour of the liquid to ignite momentarily. Measurements were corrected to 101.325 kPa pressure. The flash point of the test item has been determined to be 124 ± 2 °C at 101.325 kPa.