Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

Eye contact: Holding the eyelids apart, flush eyes promptly with copious flowing water for at least 20 minutes. Get medical attention immediately.
Skin contact: Remove contaminated clothing. Wash skin thoroughly with mild soap and plenty of water for at least 15 minutes. Wash clothing before re-use. Get medical attention if irritation occurs.
Inhalation: In case of inhalation, remove person to fresh air. Keep him quiet and warm. Apply artificial respiration if necessary and get medical
attention immediately.
Ingestion: If swallowed, wash mouth thoroughly with plenty of water. Get medical attention immediately.

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NOTE: Never give an unconscious person anything to drink.
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Notes to the physician: Treat symptomatically and supportively. No specific antidote.

Fire-fighting measures

Suitable extinguishing media: Material is not combustible. Use extinguishing media appropriate to surrounding fire conditions.
Fire fighting procedure: Fire fighters should wear full protective clothing and self-contained breathing apparatus (SCBA). Contain runoff to prevent entry into water or drainage systems.
Unusual fire and explosion hazards: When heated to decomposition, may release poisonous and corrosive fumes of Carbon Dioxide, Carbon Monoxide, Phosphorus Oxides and Phosphoric Acid.

Accidental release measures

Personal precautions: Wear appropriate safety clothing and eye/face protection.
Methods for cleaning up: Soak up with sand or other suitable absorbant and dispose of as solid waste. Collect in suitable and properly labeled containers. Ventilate area and wash spill site after material pickup is complete.
Environmental precautions: Prevent product from entering drains, ditches and rivers.

Handling and storage

Handling: Avoid bodily contact. Keep containers tightly closed.
Storage: Store in a dry, cool, well-ventilated area away from incompatible materials.

Transport information

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Marine transport (UN RTDG/IMDG)

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Exposure controls / personal protection

Exposure Limits :
Components ACGIH-TLV Data OSHA (PEL) Data
Phosphoric trichloride,polymer with 1,3- benzenediol, phenyl ester (125997-21-9) Not determined Not determined
Triphenyl phosphate (115-86-6) 3 mg/m³ 3 mg/m³

Ventilation requirements: Ventilation must be sufficient to maintain atmospheric concentration below recommended exposure limit.

Personal protective equipment:
- Respiratory protection: In case of insufficient ventilation wear suitable respiratory equipment.
- Hand protection: Neoprene gloves
- Eye protection: Chemical safety goggles
- Skin and body protection: Use protective clothing impervious to this material.

Hygiene measures: Safety shower and eye bath should be provided. Do not eat, smoke or drink where material is handled, processed or stored. Wash hands carefully before eating or smoking.

Stability and reactivity

Stability: Stable under normal conditions.
Materials to avoid: Strong oxidizers, strong acids and strong alkalis. It hydrolyzes slowly at normal temperatures in acidic or alkaline aqueous solutions.
Conditions to avoid: Heating above decomposition temperature Under wet alkaline or neutral conditions this product hydrolyzes slowly and nonviolentley. Also, hydrolyzes at 150 F (66°C) or above in moist air to form phenol, resorcinol and allyl phosphoric acids. Prevent moisture condensation in the container.
Hazardous decomposition products: Carbon dioxide and carbon monoxide, Phosphorus oxides.
Hazardous polymerization: Not expected to occur.

Disposal considerations

Waste disposal: Observe all federal, state and local environmental regulations when disposing of this material.