Registration Dossier

Administrative data

First-aid measures

4.1 Description of first aid measures
General advice
: Move out of dangerous area.
Consult a physician.
Show this safety data sheet to the doctor in attendance.
Do not leave the victim unattended.
If inhaled
: If unconscious, place in recovery position and get medical
attention immediately.
In case of skin contact
: If on skin, rinse well with water.
If on clothes, remove clothes.
Immediate medical treatment is necessary as untreated
wounds from corrosion of the skin heal slowly and with difficulty.
Wash contaminated clothing before reuse.
In case of eye contact
: Small amounts splashed into eyes can cause irreversible tissue
damage and blindness.
Remove contact lenses.
In the case of contact with eyes, rinse immediately with plenty
of water and seek medical advice.
Continue rinsing eyes during transport to hospital.
Protect unharmed eye.
Keep eye wide open while rinsing
If swallowed
: Clean mouth with water and drink afterwards plenty of water.
Keep respiratory tract clear.
Do NOT induce vomiting.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms : Skin contact may provoke the following symptoms:
Burn
corrosive effects
Redness
Inhalation may provoke the following symptoms:
Shortness of breath
Asthma
Ingestion may provoke the following symptoms:
Stomach/intestinal disorders
In case of eye contact
Excessive lachrymation
4.3 Indication of any immediate medical attention and special treatment needed

Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing media
: Use extinguishing measures that are appropriate to local circumstances
and the surrounding environment.
Water mist
Water spray jet
Foam
Carbon dioxide (CO2)
Dry chemical
Unsuitable extinguishing
media
: High volume water jet
5.2 Special hazards arising from the substance or mixture
Specific hazards during firefighting
: Do not allow run-off from fire fighting to enter drains or water
courses.
Hazardous combustion products
: Metal oxides
Nitrogen oxides (NOx)
Carbon oxides
Hazardous decomposition products due to incomplete combustion
5.3 Advice for firefighters
Special protective equipment
for firefighters
: No special protective equipment required.
Further information
: Collect contaminated fire extinguishing water separately. This
must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.

Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
Personal precautions
: Use personal protective equipment.
Evacuate personnel to safe areas.
6.2 Environmental precautions
Environmental precautions
: Prevent product from entering drains.
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform
respective authorities.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up
: Soak up with inert absorbent material (e.g. sand, silica gel,
acid binder, universal binder, sawdust).
Product may decompose into triethylamine and ethylene, both
of which are flammable gases.
Empty containers may contain one or both flammable gases
and should be handled appropriately. All equipment used in
cleaning containers should be grounded and bonded, including
the container, to prevent buildup and discharge of static
electricity which may cause fire or explosion.

Handling and storage

7.1 Precautions for safe handling
Advice on safe handling
: Do not breathe vapours/dust.
Avoid contact with skin and eyes.
For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the application
area.
Product may decompose into triethylamine and ethylene, both
of which are flammable gases.
Empty containers may contain one or both flammable gases
and should be handled appropriately. All equipment used in
cleaning containers should be grounded and bonded, including
the container, to prevent buildup and discharge of static
electricity which may cause fire or explosion.
Advice on protection against
fire and explosion
: Normal measures for preventive fire protection.
Hygiene measures
: Avoid contact with skin, eyes and clothing. General industrial
hygiene practice. Wash hands before breaks and immediately
after handling the product.
7.2 Conditions for safe storage, including any incompatibilities
Requirements for storage
areas and containers
: Keep container tightly closed in a dry and well-ventilated
place. Containers which are opened must be carefully resealed
and kept upright to prevent leakage. Electrical installations
/ working materials must comply with the technological
safety standards. To maintain product quality, do not store in
heat or direct sunlight.
Advice on common storage
: Do not store near acids.
Keep away from metals.
Storage class (TRGS 510)
: 8B, Non-combustible, corrosive hazardous materials
Further information on storage
stability
: Keep in a dry place. No decomposition if stored and applied
as directed.
7.3 Specific end use(s)

Transport information

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Marine transport (IMDG)

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Exposure controls / personal protection

8.1 Control parameters
Contains no substances with occupational exposure limit values.
8.2 Exposure controls
Engineering measures
Handle only in a place equipped with local exhaust (or other appropriate exhaust).
Personal protective equipment
Eye protection : Wear face-shield and protective suit for abnormal processing
problems.
Wear safety glasses with side shields or goggles.
Hand protection
Material : Chloroprene
Break through time : > 240 min
Glove thickness : > 0,6 mm
Skin and body protection : Impervious clothing
Footwear protecting against chemicals
Respiratory protection : ABEK-P3-filter
Filter type : Combined particulates, inorganic and acidic gas/vapour,
ammonia/amines and organic vapour type (ABEK-P)

Stability and reactivity

10.1 Reactivity
No dangerous reaction known under conditions of normal use.
10.2 Chemical stability
No decomposition if stored and applied as directed.
10.3 Possibility of hazardous reactions
Hazardous reactions
: Stable under recommended storage conditions.
10.4 Conditions to avoid
Conditions to avoid
: Do not allow evaporation to dryness.
Extremes of temperature and direct sunlight.
10.5 Incompatible materials
Materials to avoid
: Oxidizing agents
10.6 Hazardous decomposition products
Product may decompose into triethylamine and ethylene, both of which are flammable gases.

Disposal considerations

13.1 Waste treatment methods
Product : Dispose of in accordance with the European Directives on
waste and hazardous waste.
According to the European Waste Catalogue, Waste Codes
are not product specific, but application specific.
Waste codes should be assigned by the user, preferably in
discussion with the waste disposal authorities.
Do not dispose of waste into sewer.
Do not contaminate ponds, waterways or ditches with chemical
or used container.
Send to a licensed waste management company.
Dispose of as hazardous waste in compliance with local and
national regulations.
Contaminated packaging : Empty remaining contents.
Dispose of as unused product.
Do not re-use empty containers.
Product may decompose into triethylamine and ethylene, both
of which are flammable gases.
Empty containers may contain one or both flammable gases
and should be handled appropriately. All equipment used in
cleaning containers should be grounded and bonded, including
the container, to prevent buildup and discharge of static
electricity which may cause fire or explosion.