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Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

As a general rule, in case of doubt or if symptoms persist, always call a doctor.

NEVER induce swallowing by an unconscious person.

Description of first aid measures

In the event of exposure by inhalation :

In the event of massive inhalation, remove the person exposed to fresh air. Keep warm and at rest.

If the person is unconscious, place in recovery position. Notify a doctor in all events, to ascertain whether observation and

supportive hospital care will be necessary.

If breathing is irregular or has stopped, effect mouth-to-mouth resuscitation and call a doctor.

In the event of splashes or contact with eyes :

Wash thoroughly with fresh, clean water for 15 minutes holding the eyelids open.

If there is any redness, pain or visual impairment, consult an ophthalmologist.

In the event of splashes or contact with skin :

Remove contaminated clothing and wash the skin thoroughly with soap and water or a recognised cleaner.

Watch out for any remaining product between skin and clothing, watches, shoes, etc.

If the contaminated area is widespread and/or there is damage to the skin, a doctor must be consulted or the patient transferred

to hospital.

In the event of swallowing :

Do not give the patient anything orally.

In the event of swallowing, if the quantity is small (no more than one mouthful), rinse the mouth with water, administer

activated medical charcoal and consult a doctor.

Seek medical attention immediately, showing the label.

If swallowed accidentally, do not allow to drink, do not induce vomiting and transfer to hospital immediately by ambulance.

Show the label to the doctor.

Fire-fighting measures

Non-flammable.

1. Extinguishing media

Suitable methods of extinction

In the event of a fire, use :

All means of extinstion can be used.

Unsuitable methods of extinction

In the event of a fire, do not use :

Strong water jet

2. Special hazards arising from the substance or mixture

A fire will often produce a thick black smoke. Exposure to decomposition products may be hazardous to health.

Do not breathe in smoke.

In the event of a fire, the following may be formed :

- carbon monoxide (CO)

- carbon dioxide (CO2)

- Chlorine compounds

3. Advice for firefighters

Due to the toxicity of the gas emitted on thermal decomposition of the products, fire-fighting personnel are to be equipped

with autonomous insulating breathing apparatus.

Accidental release measures

1. Personal precautions, protective equipment and emergency procedures

Consult the safety measures listed under sections "Handling and Storage" and "Exposure controls/ Personal Protection"

For non first aid worker

Avoid inhaling the vapors.

Avoid any contact with the skin and eyes.

If a large quantity has been spilt, evacuate all personnel and only allow intervention by trained operators equipped with safety

apparatus.

For first aid worker

First aid workers will be equipped with suitable personal protective equipment (See section "Exposure Controls/ Personal Protection).

2. Environmental precautions

Contain and control the leaks or spills with non-combustible absorbent materials such as sand, earth, vermiculite,

diatomaceous earth in drums for waste disposal.

Prevent any material from entering drains or waterways.

3. Methods and material for containment and cleaning up

Clean preferably with a detergent, do not use solvents.

Handling and storage

Requirements relating to storage premises apply to all facilities where the substance is handled.

1. Precautions for safe handling

Always wash hands after handling.

Remove and wash contaminated clothing before re-using.

Fire prevention :

Handle in well-ventilated areas.

Prevent access by unauthorised personnel

Recommended equipment and procedures :

For personal protection, see section "Exposure Controls/ Personal Protection".

Observe precautions stated on label and also industrial safety regulations.

Avoid inhaling vapors.

Avoid inhaling vapors. Carry out any industrial operation which may give rise to this in a sealed apparatus.

Provide vapor extraction at the emission source and also general ventilation of the premises.

Also provide breathing apparatus for certain short tasks of an exceptional nature and for emergency interventions.

In all cases, recover emissions at source.

Avoid skin and eye contact with this substance.

Avoid exposure - obtain special instructions before use.

Prohibited equipment and procedures :

No smoking, eating or drinking in areas where the substance is used.

2. Conditions for safe storage, including any incompatibilities

recommended storage temperature : 2 - 8 °C

Storage

Keep the container tightly closed in a dry, well-ventilated place.

Keep away from food and drink, including those for animals.

Packaging

Always keep in packaging made of an identical material to the original.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
3277
Shippingopen allclose all
Labels:
6.1+8
SpecialProvisionsopen allclose all
Shippingopen allclose all
Remarksopen allclose all

Marine transport (UN RTDG/IMDG)

UN number:
3277
Shipping information
Proper shipping name and description:
EQ: E4
Stowage Handling : Category A SW1 SW2 H1 H2
Segregation SGGI SG36 SG49
Chemical name:
CHLOROFORMATES, TOXIC, CORROSIVE, N.O.S
(2-chloroethyl chloroformate)
Labels:
6.1 + 8
Remarksopen allclose all

Air transport (UN RTDG/ICAO/IATA)

UN number:
3277
Shipping information
Chemical name:
CHLOROFORMATES, TOXIC, CORROSIVE, N.O.S
(2-chloroethyl chloroformate)
Labels:
6.1 + 8
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Exposure controls

Personal protection measures, such as personal protective equipment

Pictogram(s) indicating the obligation of wearing personal protective equipment (PPE) :

Protective Gloves, Protective Glasses, Protective Clothes and cartridge mask

Use personal protective equipment that is clean and has been properly maintained.

Store personal protective equipment in a clean place, away from the work area.

Never eat, drink or smoke during use. Remove and wash contaminated clothing before re-using. Ensure that there is adequate

ventilation, especially in confined areas.

- Eye / face protection

Avoid contact with eyes.

Use eye protectors designed to protect against liquid splashes

Before handling, wear safety goggles with protective sides accordance with standard EN166.

In the event of high danger, protect the face with a face shield.

Prescription glasses are not considered as protection.

Individuals wearing contact lenses should wear prescription glasses during work where they may be exposed to irritant

vapours.

Provide eyewash stations in facilities where the product is handled constantly.

- Hand protection

Wear suitable protective gloves in the event of prolonged or repeated skin contact.

Use suitable protective gloves that are resistant to chemical agents in accordance with standard EN374.

Gloves must be selected according to the application and duration of use at the workstation.

Protective gloves need to be selected according to their suitability for the workstation in question : other chemical products

that may be handled, necessary physical protections (cutting, pricking, heat protection), level of dexterity required.

- Body protection

Avoid skin contact.

Wear suitable protective clothing.

Work clothing worn by personnel shall be laundered regularly.

After contact with the product, all parts of the body that have been soiled must be washed.

- Respiratory protection

Avoid breathing vapours.

cartridge mask or air supply system

Stability and reactivity

1.Chemical stability

This substance is stable under the recommended handling and storage conditions in section "Handling ans Storage".

2. Conditions to avoid

Avoid :

- heat

3. Incompatible materials

Keep away from :

- strong oxidising agents

- acids

- alcohols

- strong bases

- amines

4. Hazardous decomposition products

The thermal decomposition may release/form :

- carbon monoxide (CO)

- carbon dioxide (CO2)

Chlorin compounds

Disposal considerations

Proper waste management of the substance and/or its container must be determined in accordance with Directive 2008/98/EC.

1. Waste treatment methods

Do not pour into drains or waterways.

Waste :

Waste management is carried out without endangering human health, without harming the environment and, in particular

without risk to water, air, soil, plants or animals.

Recycle or dispose of waste in compliance with current legislation, preferably via a certified collector or company.

Do not contaminate the ground or water with waste, do not dispose of waste into the environment.

Soiled packaging :

Empty container completely. Keep label(s) on container.

Give to a certified disposal contractor.