Reaction mass of (E)-3-methylcyclotetradec-5-en-1-one and (Z)-3-methylcyclotetradec-5-en-1-one

Flammability

Administrative data

Endpoint:

flammable liquids: obsolete as covered by section 'Flash point'

Data waiving:

study technically not feasible

Justification for data waiving:

the study does not need to be conducted because the substance is a liquid

Cross-reference

Cross-reference 1

Reason / purpose for cross-reference:

data waiving: supporting information

Reference

Name:

Reaction mass of (E)-3-methylcyclotetradec-5-en-1-one and (Z)-3-methylcyclotetradec-5-en-1-one

Type of composition:

legal entity composition of the substance

State / form:

liquid

Reference substance:

Reaction mass of (E)-3-methylcyclotetradec-5-en-1-one and (Z)-3-methylcyclotetradec-5-en-1-one

Reference substance:

Reaction mass of (E)-3-methylcyclotetradec-5-en-1-one and (Z)-3-methylcyclotetradec-5-en-1-one

Cross-reference 2

Reason / purpose for cross-reference:

data waiving: supporting information

Reference

Endpoint:

flash point of flammable liquids

Type of information:

experimental study

Adequacy of study:

key study

Study period:

January 9 to February 12, 2004

Reliability:

1 (reliable without restriction)

Rationale for reliability incl. deficiencies:

test procedure in accordance with national standard methods

Remarks:

conducted under GLP conditions

Qualifier:

according to guideline

Guideline:

EU Method A.9 (Flash-Point)

Deviations:

no

Qualifier:

according to guideline

Guideline:

other: DIN 51758

Deviations:

no

GLP compliance:

yes (incl. QA statement)

Type of method:

closed cup

Flash point apparatus:

Pensky-Martens apparatus

Specific details on test material used for the study:

Aspect: colourless to pale yellow liquid
Lo No. TQT 0300497
Purity (GC): 65.7% E isomer, 25.2% Z isomer
Expiration date: November 28, 2004

Key result

Flash point:

134 °C

Atm. press.:

>= 963 - <= 979 hPa

The results of the two main tests are :

 

Test No.	Date	Atmos. pressure [hPa]	Measured flash point [°C]	Corrected flash point [°C]
1 (fast progr.)	January 16, 2004	963	134.2
2 (DIN 51758)	January 19, 2004	979	134.1	135.0
3 (DIN 51758)	January 19, 2004	979	133.1	134.0

 

The results of tests 2 and 3 were averaged and rounded down to the nearest degree to obtain the final flash point value:

 

Flash point of KARMALONE : 134 °C.

Interpretation of results:

GHS criteria not met

Conclusions:

Flash point of KARMALONE : 134 °C.

Executive summary:

The flash point of Karmalone was determined by the Pensky Martens method according to DIN 51758.

Flash point of Karmalone = 134°C

The substance is NOT CLASSIFIED as flammable liquid according to UN GHS criteria and Regulation (EC) N°1272/2008 (CLP) criteria: flash point > 60°C