Registration Dossier

Administrative data

First-aid measures

Description of first aid measures
Eye contact:
Get medical attention immediately. Immediately flush eyes with plenty of water,
occasionally lifting the upper and lower eyelids. Continue to rinse for at least 10
minutes. Chemical burns must be treated promptly by a physician.

Inhalation:
Get medical attention immediately. Remove victim to fresh air and keep at rest in a
position comfortable for breathing. If it is suspected that fumes are still present, the
rescuer should wear an appropriate mask or self-contained breathing apparatus. If
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation. If unconscious, place in
recovery position and get medical attention immediately. Maintain an open airway.
Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of
decomposition products in a fire, symptoms may be delayed. The exposed person
may need to be kept under medical surveillance for 48 hours.

Skin Contact:
Get medical attention immediately. Wash contaminated skin with soap and water.
Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly
with water before removing it, or wear gloves. Continue to rinse for at least 10
minutes. Chemical burns must be treated promptly by a physician. Wash clothing
before reuse. Clean shoes thoroughly before reuse.

Ingestion:
Get medical attention immediately. Wash out mouth with water. Remove dentures
if any. Remove victim to fresh air and keep at rest in a position comfortable for
breathing. If material has been swallowed and the exposed person is conscious,
give small quantities of water to drink. Stop if the exposed person feels sick as
vomiting may be dangerous. Do not induce vomiting unless directed to do so by
medical personnel. If vomiting occurs, the head should be kept low so that vomit
does not enter the lungs. Chemical burns must be treated promptly by a physician.
Never give anything by mouth to an unconscious person. If unconscious, place in
recovery position and get medical attention immediately. Maintain an open airway.
Loosen tight clothing such as a collar, tie, belt or waistband.

Fire-fighting measures

Extinguishing media:
Suitable extinguishing media:
Use an extinguishing agent suitable for the surrounding fire.

Unsuitable extinguishing media: None known

Hazardous decomposition products:
Decomposition products may include the following materials:
metal oxide/oxides

Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency personnel:
No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilt material. Do not breathe vapour or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.

Environmental precautions:
Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air). Water polluting material. May be harmful
to the environment if released in large quantities.

Methods and materials for containment and cleaning up:
Small spill:
Stop leak if without risk. Move containers from spill area. Dilute with water and mop
up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry
material and place in an appropriate waste disposal container. Dispose of via a
licensed waste disposal contractor.

Large spill:
Move containers from spill area. Use spark-proof tools and explosionproof equipment. Approach the release from upwind. Prevent entry into
sewers, water courses, basements or confined areas. Avoid dust
generation. Do not dry sweep. Vacuum dust with equipment fitted with
a HEPA filter and place in a closed, labeled waste container. Avoid
creating dusty conditions and prevent wind dispersal. Dispose via
a licensed waste contractor.

Handling and storage

The information in this section contains generic advice and guidance not specifically related to SCC.

Precautions for safe handling
Protective measures:
Put on appropriate personal protective equipment.
Do not get in eyes or on skin or clothing. Do not breathe vapour or mist. Do not ingest.
Avoid release to the environment. Refer to special instructions/safety data sheet.Use only
with adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Keep in the original container or an approved alternative made from a compatible
material, kept tightly closed when not in use. Keep away from alkalis. Empty containers retain
product residue and can be hazardous. Do not reuse container.

Conditions for safe storage, including any incompatibilities:
Store in accordance with local regulations. Store in original container protected
from direct sunlight in a dry, cool and well-ventilated area, away from incompatible
materials, food and drink. Separate from alkalis. Keep container tightly closed and
sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabelled containers.
Use appropriate containment to avoid environmental contamination.

Transport information

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Marine transport (UN RTDG/IMDG)

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Exposure controls / personal protection

Statement on SCC:
This substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 17(3) for on-site isolated intermediates and, in case the substance is transported to other sites for further processing, the substance should be handled at these sites under the Strictly Controlled Conditions as specified in REACH regulation Article 18(4). Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at each manufacturing site.
Written confirmation of application of Strictly Controlled Conditions has been received from every affected Distributor and Downstream Processor/User of the Registrants intermediate.

See Appendix 3 attached in section 13 of this dossier for details of RMM related to manufacture and use of the intermediate solution under SCC.

Stability and reactivity

Disposal considerations