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Diss Factsheets

Administrative data

Link to relevant study record(s)

Reference
Endpoint:
explosive properties of explosives
Type of information:
experimental study
Adequacy of study:
key study
Study period:
22.-23.01.2020
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.14 (Explosive properties)
Deviations:
no
Qualifier:
according to guideline
Guideline:
other: OECD 113
Deviations:
no
GLP compliance:
no
Key result
Parameter:
other: thermal sensitivity
Remarks:
DSC
Remarks on result:
not thermal sensitive if heated under defined confinement

Thermal stability

Two DSC measurements in closed glass crucibles showed an endothermal effect in the temperature range of 35 - 70°C and an exothermal effect in the temperature range of 150 - 430 °C with a maximum energy release of 423 J/g. .

 

Ident-No.

Weigth/mg

Final temperature / °C

Temperature range / °C

Type of effect

Energy / J/g

38989

11.83

500

30 - 70

150 - 420

 

Endothermal

Exothermal

 

n.r.

423

38991

14,58

500

40 - 70

170 - 430

 

Endothermal

Exothermal

 

n.r.

252

 

Explosive properties

The heat of decomposition in the DCS measurements was below 500 J/g.Therefore, the main test on explosive properties was not necessary.

Interpretation of results:
GHS criteria not met
Conclusions:
The test item is not an explosive.
Executive summary:

The test item had no explosive properties in the sense of the European Commission Regulation (EC) No. 440/2008, Method A.14.

The heat of decomposition in the DCS measurements was below 500 J/g.Therefore, the main test on explosive properties was not necessary.

Description of key information

The test item had no explosive properties in the sense of the European Commission Regulation (EC) No. 440/2008, Method A. 14.

Key value for chemical safety assessment

Explosiveness:
non explosive

Additional information

Justification for classification or non-classification

Based on the result, the substance is not considered to be classified for explosiveness according to Classification, Labelling, and Packaging Regulation (EC) No 1272/2008.