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Administrative data

Endpoint:
water solubility
Type of information:
experimental study
Adequacy of study:
key study
Study period:
Study plan:16/06/2021
Draft report: 14/10/2021
Final report: 16/Nov/2021
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: GLP compliant

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2021
Report date:
2021

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
other: OECD No. 29. Guidance document on transformation/dissolution of metals and metal compounds in aqueous media.
Deviations:
no
GLP compliance:
yes
Type of method:
other: Transformation/dissolution

Test material

Constituent 1
Reference substance name:
Amorphous barium copper zinc borobismuthate
Molecular formula:
Not applicable as UVCB
IUPAC Name:
Amorphous barium copper zinc borobismuthate
Test material form:
solid: particulate/powder

Results and discussion

Water solubilityopen allclose all
Water solubility:
ca. 40.74 µg/L
Incubation duration:
ca. 28 d
pH:
ca. 8
Remarks on result:
other: Solubility of Zn. Temperature not reported.
Water solubility:
ca. 33.18 µg/L
Incubation duration:
ca. 7 d
pH:
ca. 8
Remarks on result:
other: Solubility of Zn. Temperature not reported.
Water solubility:
ca. 6.05 µg/L
Incubation duration:
ca. 28 d
pH:
ca. 8
Remarks on result:
other: Solubility of Cu. Temperature not reported.
Water solubility:
ca. 5.53 µg/L
Incubation duration:
ca. 7 d
pH:
ca. 8
Remarks on result:
other: Solubility of Cu. Temperature not reported.
Water solubility:
ca. 6.2 µg/L
Incubation duration:
ca. 28 d
pH:
ca. 6
Remarks on result:
other: Solubility of Bi. Temperature not reported.
Water solubility:
ca. 51.55 µg/L
Incubation duration:
ca. 7 d
pH:
ca. 6
Remarks on result:
other: Solubility of Bi. Temperature not reported.
Water solubility:
ca. 40.01 µg/L
Incubation duration:
ca. 24 h
pH:
ca. 8
Remarks on result:
other: Solubility of Zn. Temperature not reported.
Water solubility:
ca. 36.9 µg/L
Incubation duration:
ca. 24 h
pH:
ca. 6
Remarks on result:
other: Solubility of Zn. Temperature not reported.
Water solubility:
ca. 2.63 µg/L
Incubation duration:
ca. 24 h
pH:
ca. 8
Remarks on result:
other: Solubility of Cu. Temperature not reported.
Water solubility:
ca. 5.54 µg/L
Incubation duration:
ca. 24 h
pH:
ca. 6
Remarks on result:
other: Solubility of Cu. Temperature not reported.
Water solubility:
4.89 µg/L
Incubation duration:
ca. 24 h
pH:
6
Remarks on result:
other: Solubility of Bi. Temperature not reported.
Water solubility:
83.68 µg/L
Incubation duration:
ca. 24 h
pH:
8
Remarks on result:
other: Solubility of Bi. Temperature not reported.
Details on results:
24 h & Full test 28 days

Applicant's summary and conclusion

Conclusions:
Amorphous barium copper zinc borobismuthate was measured for Bi, Cu and Zn solubility in a 24 h transformation/dissolution test at pH 6 and pH 8.
The highest concentration of Bi was 83.68 ug/L (pH 8) after 24h.
The highest concentration of Cu was 5.54 ug/L (pH 6) after 24h.
The highest concentration of Zn was 40.01 ug/L (pH 8) after 24h.

The highest concentration of Bi was 51.55 ug/L (pH 6) after 7d.
The highest concentration of Cu was 5.53 ug/L (pH 8) after 7d.
The highest concentration of Zn was 33.18 ug/L (pH 8) after 7d.

The highest concentration of Bi was 6.2 ug/L (pH 6) after 28d.
The highest concentration of Cu was 6.05 ug/L (pH 8) after 28d.
The highest concentration of Zn was 40.74 ug/L (pH 8) after 28d.
Executive summary:

Table below compares the acute and chronic ERVs for Zn and Cu in the EU with the 7 and 28 d release rates measured by the transformation dissolution protocol for a dosing of 1 mg/l at pH 8.


The values in green would correspond with no hazard classifications, Acute and Chronic, due to a lower TDp release than the corresponding ERVs values.




























Sample name



Zn


Acute ERV in µg/l          


 



7 d Zn release in µg/l



Zn


chronic ERV in µg/l          


 



28 d Zn release in µg/l



Cu


Acute ERV in µg/l          


 



7 d Cu release in µg/l



Cu


chronic ERV in µg/l          


 



28 d Cu


 release in µg/l



Glass powder lot.No.2102151



413



33,18



82



40,78



12



5,53



13



6,05