Registration Dossier
Registration Dossier
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EC number: 418-410-7 | CAS number: 139122-78-4
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
Description of first aid measures:
Pay attention to self-protection.
Remove victims from hazardous area.
Immediately remove soiled or soaked clothing and remove it to a safe distance.
Keep victim warm, in a stabilized position and covered.
Do not leave victims unattended.
If the casualty is unconscious: Place the victim in the recovery position.
Inhalation:
Potential for exposure by inhalation if dusts or smoke are generated.
Move victims into fresh air.
With labored breathing: Provide with oxygen.
Consult a doctor.
If the casualty is not breathing: Perform mouth-to-mouth resuscitation, notify emergency physician immediately.
Skin contact:
Wash off affected area immediately with plenty of water for at least 15 minutes.
If symptoms persist, consult a physician for treatment.
Eye contact:
With eye held open, thoroughly rinse immediately with plenty of water for at least 10 minutes.
Consult an ophthalmologist immediately if the symptoms persist.
Ingestion:
Rinse out mouth.
Immediately give large quantities of water to drink.
Consult a physician immediately.
Most important symptoms and effects, both acute and delayed:
Indication of any immediate medical attention and special treatment needed:
The initial focus is only on the local action, possibly characterized by a progressive tissue irritation.
In the eye, irritating solids cause, depending on the intensity of exposure, irritation of the conjunctiva and, in exceptional cases, damage to the cornea.
There is a danger of blindness if corneas are damaged!
Superficial irritations and only infrequent damage with ulcerations develop on the skin.
Pay attention to self-protection.
Remove victims from hazardous area.
Immediately remove soiled or soaked clothing and remove it to a safe distance.
Keep victim warm, in a stabilized position and covered.
Do not leave victims unattended.
If the casualty is unconscious: Place the victim in the recovery position.
Inhalation:
Potential for exposure by inhalation if dusts or smoke are generated.
Move victims into fresh air.
With labored breathing: Provide with oxygen.
Consult a doctor.
If the casualty is not breathing: Perform mouth-to-mouth resuscitation, notify emergency physician immediately.
Skin contact:
Wash off affected area immediately with plenty of water for at least 15 minutes.
If symptoms persist, consult a physician for treatment.
Eye contact:
With eye held open, thoroughly rinse immediately with plenty of water for at least 10 minutes.
Consult an ophthalmologist immediately if the symptoms persist.
Ingestion:
Rinse out mouth.
Immediately give large quantities of water to drink.
Consult a physician immediately.
Most important symptoms and effects, both acute and delayed:
Indication of any immediate medical attention and special treatment needed:
The initial focus is only on the local action, possibly characterized by a progressive tissue irritation.
In the eye, irritating solids cause, depending on the intensity of exposure, irritation of the conjunctiva and, in exceptional cases, damage to the cornea.
There is a danger of blindness if corneas are damaged!
Superficial irritations and only infrequent damage with ulcerations develop on the skin.
Fire-fighting measures
Suitable extinguishing media:
Water spray, foam, CO2, dry powder.
Unsuitable extinguishing media:
High volume water jet.
Special hazards arising from the substance or mixture:
Toxic gases/vapours
Carbon monoxide
Nitrogen oxides (NOx).
Special protective equipment for fire-fighters:
Have ready/wear respiratory protection equipment.
Wear a self contained respiratory apparatus
Advice for firefighters:
Water used to extinguish fire should not enter drainage systems, soil, or stretches of water Ensure there are sufficient retaining facilities for water used to extinguish fire.
Contaminated fire-extinguishing water must be disposed of in accordance with the regulations issued by the appropriate local authorities.
Fire residues should be disposed of in accordance with the regulations.
Water spray, foam, CO2, dry powder.
Unsuitable extinguishing media:
High volume water jet.
Special hazards arising from the substance or mixture:
Toxic gases/vapours
Carbon monoxide
Nitrogen oxides (NOx).
Special protective equipment for fire-fighters:
Have ready/wear respiratory protection equipment.
Wear a self contained respiratory apparatus
Advice for firefighters:
Water used to extinguish fire should not enter drainage systems, soil, or stretches of water Ensure there are sufficient retaining facilities for water used to extinguish fire.
Contaminated fire-extinguishing water must be disposed of in accordance with the regulations issued by the appropriate local authorities.
Fire residues should be disposed of in accordance with the regulations.
Accidental release measures
Personal precautions, protective equipment and emergency procedures:
Avoid dust formation.
Wear personal protective equipment.
Keep unauthorized persons away.
Environmental precautions:
Do not allow to sink into ground water, sewers or into surface water.
Methods and material for containment and cleaning up:
Use mechanical handling equipment.
Collect in suitable containers.
Avoid dust formation.
Wear personal protective equipment.
Keep unauthorized persons away.
Environmental precautions:
Do not allow to sink into ground water, sewers or into surface water.
Methods and material for containment and cleaning up:
Use mechanical handling equipment.
Collect in suitable containers.
Handling and storage
Handling:
Precautions for safe handling:
Avoid dust formation.
Provide good ventilation or extraction.
Wear personal protective equipment.
Advice on protection against fire and explosion:
Take precautionary measures against static discharges.
Keep away from sources of ignition - No smoking.
Storage:
Conditions for safe storage, including any incompatibilities
Keep container tightly closed in a dry and well-ventilated place.
Precautions for safe handling:
Avoid dust formation.
Provide good ventilation or extraction.
Wear personal protective equipment.
Advice on protection against fire and explosion:
Take precautionary measures against static discharges.
Keep away from sources of ignition - No smoking.
Storage:
Conditions for safe storage, including any incompatibilities
Keep container tightly closed in a dry and well-ventilated place.
Transport information
Land transport (UN RTDG/ADR/RID)
Shippingopen allclose all
Special provisions / remarks
- Remarks:
- Not dangerous according to transport regulations.
Inland waterway transport (UN RTDG/ADN(R))
Shippingopen allclose all
Special provisions / remarks
- Remarks:
- Not dangerous according to transport regulations.
Marine transport (UN RTDG/IMDG)
Shippingopen allclose all
Special provisions / remarks
- Remarks:
- Not dangerous according to transport regulations.
Air transport (UN RTDG/ICAO/IATA)
Shippingopen allclose all
Special provisions / remarks
- Remarks:
- Not dangerous according to transport regulations.
SpecialProvisionsopen allclose all
Exposure controls / personal protection
Control parameters:
- Methanol, CAS-No. 67-56-1, EC-No. 200-659-6
Control parameters: 200 ppm; 260 mg/m³
Time Weighted Average (TWA): (EU ELV)
Indicative.
Control parameters:
Skin designation: (EU ELV)
Can be absorbed through the skin.
Engineering measures:
Provide sufficient air exchange and/or exhaust in work rooms.
Prevent the formation of dust.
Personal protective equipment:
Respiratory protection:
In case of dusts/vapours/aerosols being formed or if the limit values like TLV are exceeded:
Use respiratory equipment with suitable filter or wear a self contained respiratory apparatus
If dust occurs: Respirator with P2 particle filter
Note time limit for wearing respiratory protective equipment.
Hand protection:
Applies to handling for longer periods or of large amounts
Glove material Nitrile/Chloroprene, for example: Nitopren 717, Camapren (720), Camapren 722, Kächele-Cama Latex GmbH (KCL), Germany
Material thickness 0.65 mm
Method DIN EN 374
Eye protection:
Close-fitting protective goggles (e.g. closed goggles)
Skin and body protection:
Suitable protective clothing.
Use disposable clothing if appropriate.
Hygiene measures:
Avoid contact with eyes.
Do not breathe dust.
No eating, drinking, smoking, or snuffing tobacco at work. Wash face and/or hands before break and end of work.
Protective measures:
The personal protective equipment used must meet the requirements of directive 89/686/EEC and amendments (CE certification).
- Methanol, CAS-No. 67-56-1, EC-No. 200-659-6
Control parameters: 200 ppm; 260 mg/m³
Time Weighted Average (TWA): (EU ELV)
Indicative.
Control parameters:
Skin designation: (EU ELV)
Can be absorbed through the skin.
Engineering measures:
Provide sufficient air exchange and/or exhaust in work rooms.
Prevent the formation of dust.
Personal protective equipment:
Respiratory protection:
In case of dusts/vapours/aerosols being formed or if the limit values like TLV are exceeded:
Use respiratory equipment with suitable filter or wear a self contained respiratory apparatus
If dust occurs: Respirator with P2 particle filter
Note time limit for wearing respiratory protective equipment.
Hand protection:
Applies to handling for longer periods or of large amounts
Glove material Nitrile/Chloroprene, for example: Nitopren 717, Camapren (720), Camapren 722, Kächele-Cama Latex GmbH (KCL), Germany
Material thickness 0.65 mm
Method DIN EN 374
Eye protection:
Close-fitting protective goggles (e.g. closed goggles)
Skin and body protection:
Suitable protective clothing.
Use disposable clothing if appropriate.
Hygiene measures:
Avoid contact with eyes.
Do not breathe dust.
No eating, drinking, smoking, or snuffing tobacco at work. Wash face and/or hands before break and end of work.
Protective measures:
The personal protective equipment used must meet the requirements of directive 89/686/EEC and amendments (CE certification).
Stability and reactivity
Further information:
Stable under normal conditions.
Stable under normal conditions.
Disposal considerations
With respect to local regulations, e.g. dispose of to suitable waste incineration plant.
The waste key number must be determined as per the European Waste Types List (decision on EU Waste Types List 2000/532/EC) in cooperation with the disposal firm / producing firm / official authority.
The waste key number must be determined as per the European Waste Types List (decision on EU Waste Types List 2000/532/EC) in cooperation with the disposal firm / producing firm / official authority.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
