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Classification & Labelling & PBT assessment

GHS

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General Information

Implementation:
EU
Remarks:
Hexane and/or hexene may be generated by degradation of the material; hence classification and labelling contribution of these substances is considered to be an appropriate consideration. The classification is made according to CLP, with due application of the mixture rule to classify the substance containing hexane or hexane as an impurity. Variation in composition and classification is appropriate as degradation products differ per manufacturer for the substance.

Related composition

Related composition:
Trihexylaluminium, where hexene / hexane content is 0 to <2.5%

Classificationopen allclose all

Explosives
Reason for no classification:
data conclusive but not sufficient for classification
Flammable gases and chemically unstable gases
Reason for no classification:
data conclusive but not sufficient for classification
Aerosols
Reason for no classification:
data conclusive but not sufficient for classification
Reason for no classification:
hazard class not assessed
Oxidising gases
Reason for no classification:
data conclusive but not sufficient for classification
Gases under pressure
Reason for no classification:
data conclusive but not sufficient for classification
Flammable liquids
Reason for no classification:
data conclusive but not sufficient for classification
Flammable solids
Reason for no classification:
data conclusive but not sufficient for classification
Self-reactive substances and mixtures
Reason for no classification:
data conclusive but not sufficient for classification
Pyrophoric liquids
Hazard category:
Pyr. Liquid 1
Hazard statement:
H250: Catches fire spontaneously if exposed to air.
Pyrophoric solids
Reason for no classification:
data conclusive but not sufficient for classification
Self-heating substances and mixtures
Reason for no classification:
data conclusive but not sufficient for classification
Substances and mixtures which in contact with water emit flammable gases
Hazard category:
Water React. Flam. Gas 1
Hazard statement:
H260: In contact with water releases flammable gases which may ignite spontaneously.
Oxidising liquids
Reason for no classification:
data conclusive but not sufficient for classification
Oxidising solids
Reason for no classification:
data conclusive but not sufficient for classification
Organic peroxides
Reason for no classification:
data conclusive but not sufficient for classification
Corrosive to metals
Reason for no classification:
data lacking
Desensitized explosives
Reason for no classification:
data lacking
Acute toxicity - oral
Reason for no classification:
data lacking
Acute toxicity - dermal
Reason for no classification:
data lacking
Acute toxicity - inhalation
Reason for no classification:
data lacking
Skin corrosion / irritation
Hazard category:
Skin Corr. 1B
Hazard statement:
H314: Causes severe skin burns and eye damage.
Serious eye damage / eye irritation
Reason for no classification:
data lacking
Respiratory sensitisation
Reason for no classification:
data lacking
Skin sensitisation
Reason for no classification:
data lacking
Aspiration hazard
Reason for no classification:
data lacking
Reproductive toxicity
Reason for no classification:
data lacking
Effects on or via lactation
Reason for no classification:
data lacking
Germ cell mutagenicity
Reason for no classification:
data lacking
Carcinogenicity
Reason for no classification:
data lacking
1. Specific target organ toxicity - single (STOT-SE)
Reason for no classification:
data lacking
1. Specific target organ toxicity - repeated (STOT-RE)
Reason for no classification:
data lacking
Hazardous to the aquatic environment (acute / short-term)
Reason for no classification:
data conclusive but not sufficient for classification
Hazardous to the aquatic environment (long-term)
Reason for no classification:
data conclusive but not sufficient for classification
Hazardous to the ozone layer
Reason for no classification:
data lacking

Labelling

Signal word:
Danger

Hazard pictogram

GHS02: flame
GHS05: corrosion

Hazard statements

H250: Catches fire spontaneously if exposed to air.
H260: In contact with water releases flammable gases which may ignite spontaneously.
H314: Causes severe skin burns and eye damage.

Precautionary statements

P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P222: Do not allow contact with air.
P223: Do not allow contact with water.
P231+P232: Handle and store contents under inert gas/… . Protect from moisture.
P260: Do not breathe dust/fume/gas/mist/vapours/spray.
P264: Wash ... thoroughly after handling.
hands and clothing
P280: Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...
P301+P330+P331: IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P302+P334: IF ON SKIN: Immerse in cool water [or wrap in wet bandages].
P303+P361+P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower].
P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER/doctor/…
P321: Specific treatment (see ... on this label).
guidance
P302+P335+P334: IF ON SKIN: Brush off loose particles from skin. Immerse in cool water [or wrap in wet bandages].
P363: Wash contaminated clothing before reuse.
P370+P378: In case of fire: Use... to extinguish.
CO2 or dry powder. DO NOT USE WATER or FOAM
P402+P404: Store in a dry place. Store in a closed container.
P405: Store locked up.
P501: Dispose of contents/container to ...
industrial waste processor.

Additional labelling requirements

EUH014: Reacts violently with water.

Notes