Registration Dossier
Registration Dossier
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EC number: 203-716-3 | CAS number: 109-89-7
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
Most important symptoms and effects, both acute and delayed:
• Causes skin and eye burns
• If ingested, severe burns of the mouth and throat, as well as a danger of perforation of the esophagus and the stomach
• Inhalation of vapors is irritating to the respiratory system, may cause throat pain and cough
• Risk of serious damage to the lungs (by inhalation)
• Aspiration may cause pulmonary edema and pneumonitis
• Symptoms may be delayed
General Advice: If symptoms persist, call a physician. Show this material safety data sheet to the doctor in attendance.
Eye Contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes Obtain medical attention.
Skin Contact: Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Consult a physician.
Inhalation: Remove from exposure, lie down. Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Symptoms may be delayed Immediate medical attention is required.
Ingestion: Drink plenty of water. Never give anything by mouth to an unconscious person. Do not induce vomiting. Immediate medical attention is required
• Causes skin and eye burns
• If ingested, severe burns of the mouth and throat, as well as a danger of perforation of the esophagus and the stomach
• Inhalation of vapors is irritating to the respiratory system, may cause throat pain and cough
• Risk of serious damage to the lungs (by inhalation)
• Aspiration may cause pulmonary edema and pneumonitis
• Symptoms may be delayed
General Advice: If symptoms persist, call a physician. Show this material safety data sheet to the doctor in attendance.
Eye Contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes Obtain medical attention.
Skin Contact: Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Consult a physician.
Inhalation: Remove from exposure, lie down. Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Symptoms may be delayed Immediate medical attention is required.
Ingestion: Drink plenty of water. Never give anything by mouth to an unconscious person. Do not induce vomiting. Immediate medical attention is required
Fire-fighting measures
Suitable Extinguishing Media
• carbon dioxide (CO2)
• water spray
• dry chemical
• Alcohol-resistant foam
Extinguishing media which must not be used for safety reasons
• high volume water jet
Specific Hazards Arising from the Chemical:
Heating or fire can release toxic gas:
• Nitrogen oxides (NOx)
• Carbon monoxide
• Ammonia
Specific methods
• Highly flammable
• In the event of fire, cool tanks with water spray
• Vapors may form explosive mixtures with air
• Vapors are heavier than air and may spread along floors
• Keep product and empty container away from heat and sources of ignition
• Collect contaminated fire extinguishing water separately. This must not be discharged into drains
Protective Equipment and Precautions for Firefighters
Wear full protective clothing and self-contained breathing apparatus
• carbon dioxide (CO2)
• water spray
• dry chemical
• Alcohol-resistant foam
Extinguishing media which must not be used for safety reasons
• high volume water jet
Specific Hazards Arising from the Chemical:
Heating or fire can release toxic gas:
• Nitrogen oxides (NOx)
• Carbon monoxide
• Ammonia
Specific methods
• Highly flammable
• In the event of fire, cool tanks with water spray
• Vapors may form explosive mixtures with air
• Vapors are heavier than air and may spread along floors
• Keep product and empty container away from heat and sources of ignition
• Collect contaminated fire extinguishing water separately. This must not be discharged into drains
Protective Equipment and Precautions for Firefighters
Wear full protective clothing and self-contained breathing apparatus
Accidental release measures
Personal precautions, protective equipment and emergency procedures:
• Avoid contact with skin, eyes and clothing
• Evacuate personnel to safe areas
• Keep people away from and upwind of spill/leak
• Wear self-contained breathing apparatus and protective suit
• Rubber gloves
• Rubber or plastic boots
Environmental precautions:
• Remove immediately adhering matter
• Hose down gases, fumes and/or dust with water
• Prevent product from entering drains
• Do not flush into surface water or sanitary sewer system
Methods and materials for containment and cleaning up:
• Use explosion-proof equipment
• Wear self-contained breathing apparatus and protective suit
• Absorb spill with inert material (e.g. dry sand or earth), then place in a chemical waste container
• Neutralize with hydrochloric or sulfuric acids
• Avoid contact with skin, eyes and clothing
• Evacuate personnel to safe areas
• Keep people away from and upwind of spill/leak
• Wear self-contained breathing apparatus and protective suit
• Rubber gloves
• Rubber or plastic boots
Environmental precautions:
• Remove immediately adhering matter
• Hose down gases, fumes and/or dust with water
• Prevent product from entering drains
• Do not flush into surface water or sanitary sewer system
Methods and materials for containment and cleaning up:
• Use explosion-proof equipment
• Wear self-contained breathing apparatus and protective suit
• Absorb spill with inert material (e.g. dry sand or earth), then place in a chemical waste container
• Neutralize with hydrochloric or sulfuric acids
Handling and storage
Precautions for safe handling
• Use product only in closed system
• Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapours)
• Use only in area provided with appropriate exhaust ventilation
• Use spark-proof tools and explosion-proof equipment
• Wear personal protective equipment
• Do not eat, drink or smoke when using this product
• Wash hands after handling
• Remove contaminated clothing and protective equipment before entering eating areas
• Ensure that eyewash stations and safety showers are close to the workstation location
• Avoid breathing vapors or mists
Conditions for safe storage, including any incompatibilities
• Protect from light
• Keep in properly labelled containers
• Keep away from open flames, hot surfaces and sources of ignition
• Keep container tightly closed
• Keep in a dry, cool and well-ventilated place
• Use product only in closed system
• Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapours)
• Use only in area provided with appropriate exhaust ventilation
• Use spark-proof tools and explosion-proof equipment
• Wear personal protective equipment
• Do not eat, drink or smoke when using this product
• Wash hands after handling
• Remove contaminated clothing and protective equipment before entering eating areas
• Ensure that eyewash stations and safety showers are close to the workstation location
• Avoid breathing vapors or mists
Conditions for safe storage, including any incompatibilities
• Protect from light
• Keep in properly labelled containers
• Keep away from open flames, hot surfaces and sources of ignition
• Keep container tightly closed
• Keep in a dry, cool and well-ventilated place
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- 1154
Shipping information
- Proper shipping name and description:
- DIETHYLAMINE
- Language:
- English
- Labels:
- 3 + 8
Special provisions / remarks
- Special provisions:
- none
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- 1154
Shipping information
- Proper shipping name and description:
- DIETHYLAMINE
- Language:
- English
- Labels:
- 3 + 8
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- 1154
Shipping information
- Proper shipping name and description:
- DIETHYLAMINE
- Labels:
- 3 + 8
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- 1154
Shipping information
- Proper shipping name and description:
- DIETYLAMINE
- Labels:
- 3 + 8
Remarksopen allclose all
SpecialProvisionsopen allclose all
Exposure controls / personal protection
Control parameters / Exposure Guidelines:
ACGIH TLV: TWA: 5 ppm, STEL: 15 ppm, Skin
RL 2006/15/EG: Recommended indicative occupational exposure limit value for the European Community
8 hours limit value : 15 mg/m3 (5 ppm)
Short term limit value: 30 mg/m3 (10 ppm)
A national occupational exposure limit value has to be set.
TRGS 900 - GERMAN OCCUPATIONAL EXPOSURE LIMIT VALUES (Source: DFG)
5 ml/m³
15 mg/m³
Category I - Substances for which local irritant effects determine the exposure limit value, also respiratory allergens
Momentary value: 2
-times limit value should not be exceeded
Risk of percutaneous absorption
Exposure controls:
Engineering Controls • Local exhaust
Personal Protective Equipment:
Eye/face Protection
• Tightly fitting safety goggles
• Face-shield
• Respirator with a full face mask
Skin Protection
• Wear suitable protective equipment
• Complete suit protecting against chemicals
Hand Protection
• Neoprene gloves
• Solvent-resistant gloves (butyl-rubber)
• The selected protective gloves have to satisfy the specifications of EU Directive 89/689/EEC and the standard EN 374 derived from it
• The suitability for a specific workplace should be discussed with the producers of the protective gloves
Respiratory Protection
• In the case of vapor formation use a respirator with filter model K
• Self-contained breathing apparatus (EN 133) (in case of higher concentration)
Environmental exposure controls
• Prevent product from entering drains
• Do not contaminate surface water
• Avoid subsoil penetration
ACGIH TLV: TWA: 5 ppm, STEL: 15 ppm, Skin
RL 2006/15/EG: Recommended indicative occupational exposure limit value for the European Community
8 hours limit value : 15 mg/m3 (5 ppm)
Short term limit value: 30 mg/m3 (10 ppm)
A national occupational exposure limit value has to be set.
TRGS 900 - GERMAN OCCUPATIONAL EXPOSURE LIMIT VALUES (Source: DFG)
5 ml/m³
15 mg/m³
Category I - Substances for which local irritant effects determine the exposure limit value, also respiratory allergens
Momentary value: 2
-times limit value should not be exceeded
Risk of percutaneous absorption
Exposure controls:
Engineering Controls • Local exhaust
Personal Protective Equipment:
Eye/face Protection
• Tightly fitting safety goggles
• Face-shield
• Respirator with a full face mask
Skin Protection
• Wear suitable protective equipment
• Complete suit protecting against chemicals
Hand Protection
• Neoprene gloves
• Solvent-resistant gloves (butyl-rubber)
• The selected protective gloves have to satisfy the specifications of EU Directive 89/689/EEC and the standard EN 374 derived from it
• The suitability for a specific workplace should be discussed with the producers of the protective gloves
Respiratory Protection
• In the case of vapor formation use a respirator with filter model K
• Self-contained breathing apparatus (EN 133) (in case of higher concentration)
Environmental exposure controls
• Prevent product from entering drains
• Do not contaminate surface water
• Avoid subsoil penetration
Stability and reactivity
Reactivity
Chemical Stability:
• Stable under normal conditions
• Hazardous polymerisation does not occur
Possibility of hazardous reactions:
None under normal processing
Conditions to Avoid:
• Heat, flames and sparks
• Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapors)
• Handle under nitrogen, protect from moisture
Incompatible materials to avoid:
• Zinc
• Copper
• Aluminum
• Strong acids and oxidizing agents
• Halogenated hydrocarbons
The reaction with nitrosation agents can result in the formation of the respective carcinogenic N-nitrosamines.
Hazardous Decomposition Products:
Heating or fire can release toxic gas:
• Nitrogen oxides (NOx)
• Carbon monoxide
• Ammonia
Chemical Stability:
• Stable under normal conditions
• Hazardous polymerisation does not occur
Possibility of hazardous reactions:
None under normal processing
Conditions to Avoid:
• Heat, flames and sparks
• Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapors)
• Handle under nitrogen, protect from moisture
Incompatible materials to avoid:
• Zinc
• Copper
• Aluminum
• Strong acids and oxidizing agents
• Halogenated hydrocarbons
The reaction with nitrosation agents can result in the formation of the respective carcinogenic N-nitrosamines.
Hazardous Decomposition Products:
Heating or fire can release toxic gas:
• Nitrogen oxides (NOx)
• Carbon monoxide
• Ammonia
Disposal considerations
Waste Disposal Method
• Should not be released into the environment
Contaminated Packaging
• Empty containers should be taken for local recycling, recovery or waste disposal
• Should not be released into the environment
Contaminated Packaging
• Empty containers should be taken for local recycling, recovery or waste disposal
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
