Registration Dossier

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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

First-aid measures

INHALATION

Use a chemicals protection suit. Avoid inhalation of vapors. Remove victim from contaminated atmosphere. Avoid contact with skin and eyes. Promptly remove non-impervious clothing that becomes wet or contaminated. Emergency shower and facilities for eye rinsing shall be available.

SKIN CONTACT

Rinse immediately with plenty of water. Promptly remove non-impervious clothing that becomes wet or contaminated.

Immediately rinse with water for several minutes. Do not try to neutralize. Get medical attention if any discomfort

continues.

EYE CONTACT

Rinse immediately with plenty of water. Remove any contact lenses and continue rinsing with water for at least 15

minutes (keep the eyelids open). Get medical attention immediately. Continue to rinse.

INGESTION

DO NOT INDUCE VOMITING! Rinse nose and mouth with water. Immediately give a couple of glasses of water or milk,

provided the victim is fully conscious. Never give anything by mouth to an unconscious person.

Fire-fighting measures

EXTINGUISHING MEDIA

Can be extinguished with dry sand, powder or carbon dioxide. Use extinguishing media appropriate for surrounding fire.

IMPROPER EXTINGUISHING MEDIA

Do not use a direct water jet that could spread the fire.

FIRE AND EXPLOSION HAZARDS

Non-flammable. When heated, sulfur dioxide vapour will evolve.

PROTECTIVE EQUIPMENT FOR FIRE FIGHTERS

General: Evacuate all personnel, use protective equipment for fire fighting. Use a portable breathing apparatus when

the product is involved in a fire.

OTHER INFORMATION

Containers close to fire should be removed or cooled with water. Persons without protective equipment and clothing

restricted from hazard area.

Accidental release measures

PERSONAL PRECAUTIONS

Wear necessary protective equipment. Evacuate the area.

SAFETY ACTIONS TO PROTECT EXTERNAL ENVIRONMENT

Prevent dispersion through damming with sand, earth or other suitable material. Prevent discharge into the sewage

system or the immediate environment (potential aquatic toxicity).

METHODS FOR CLEANING UP

Stop leak if possible without risk. Pump up liquid spillage with explosion-proof pump or hand pump, or use suitable

absorbent material. Minor spillage should be wiped away or flushed away with water. Large quantities should be

collected for treatment (neutralisation, combustion) in accordance with the local regulations.

OTHER INFORMATION

Inform Authorities if large amounts are involved.

Handling and storage

STORAGE

Storage in well-designed closed tanks. Storage plant must present a sufficient ventilation.

Avoid proximity with compatible chemicals and ignition source

HANDLING PRECAUTIONS

The product is corrosive.

HANDLING ADVICE

Use a chemicals protection suit. Avoid inhalation of vapours. Avoid contact with skin and eyes. Promptly remove nonimpervious

clothing that becomes wet or contaminated. Emergency shower and facilities for eye rinsing shall be

available.

Transport information

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Marine transport (UN RTDG/IMDG)

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Exposure controls / personal protection

EXPOSURE CONTROL

Storage substance in well-designed closed. Storage tank with in particular appropriate devices for vents to avoid vapor exposure. Provide good ventilation. Emergency shower and facilities for eye rinsing shall be available. Good working hygiene must

always be observed when handling product. Promptly remove any clothing that becomes wet or contaminated. Use

appropriate skin cream to prevent drying of skin.

RESPIRATORY PROTECTION

In case of insufficient ventilation, wear suitable respiratory equipment.

EYE PROTECTION

Tight-fitting goggles and face mask if risk of splashes or direct contact.

HAND PROTECTION

Protective gloves (butyl rubber, fluorocarbon rubber). Protective gloves (polyethylene).

PROTECTIVE CLOTHING

Use protective clothing that is resistant to chemicals.

Exposure Guidelines (by INRS ND 1945-153-93 and ND 192-155-94)

VLE (France) : 5 ppm

VME (France) : 2 ppm

Stability and reactivity

STABILITY

Product is reactive.

MATERIALS TO AVOID

In an open container, ammoium thiosulfate, ammonium sulfate will be genrated and sulfur dioxide will be vented. Ammonium can be vented in case of addition of strong alkalis with heated conditions.

Strong oxidizers will reacts with reducive species. Strong alkalis will accelerate the evolution of ammonia with dispersion.

Strong acids will cause the release of sulfur dioxide, highly toxic gas.

Ammonium bisulfite is not compatible with copper, zinc or alloys like bronze, brass, galvanized metals.

HAZARDOUS DECOMPOSITION PRODUCTS

Disposal considerations