Registration Dossier
Registration Dossier
Use of this information is subject to copyright laws and may require the permission of the owner of the information, as described in the ECHA Legal Notice.
EC number: 309-665-4 | CAS number: 100683-96-3
Oxidising properties
Administrative data
- Endpoint:
- oxidising liquids
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Study period:
- From 3 February 2015 to 10 March 2015
- Reliability:
- 1 (reliable without restriction)
Data source
Reference
- Reference Type:
- study report
- Title:
- Unnamed
- Year:
- 2 015
- Report date:
- 2015
Materials and methods
Test guideline
- Qualifier:
- according to guideline
- Guideline:
- other: In compliance with United Nations Recommendations on the Transport of Dangerous Goods - Manual of Tests and Criteria Fifth revised edition (2009) - Method O.2 (Part III, Section 34.4.2) EC No. 1272/2008 (CLP)
- Deviations:
- yes
- Remarks:
- The deviation was not considered to have affected the quality or the interpretation of the results obtained.
- Principles of method if other than guideline:
- The test item is mixed in a 1 to 1 ratio by weight with dried fibrous cellulose and introduced into a pressure vessel. If during mixing or filling spontaneous ignition occurs no further testing is necessary and the test item is considered as an oxidizer.
If spontaneous ignition does not occur, the full test is carried out. The mixture is heated in a pressure vessel and the mean time taken for the pressure to rise from 690 to 2070 kPa above atmospheric pressure is determined. This is compared with the mean pressure rise time of three reference items, each one mixed in 1:1 proportion with the dried fibrous cellulose. According to the pressure rise times obtained, the test item is classified in different packing groups.
The following deviation was recorded:
Deviation No. 1: The mean pressure rise time obtained with the sodium chlorate / cellulose mixture recorded was 853 ms instead of about 2500 ms as expected following the guideline.
The mean pressure rise time obtained with the nitric acid / cellulose mixture recorded was 2584 ms instead of about 4767 ms as expected following the guideline.
The mean pressure rise time obtained with the perchloric acid / cellulose mixture recorded was 72 ms instead of about 121 ms as expected following the guideline.
As the pressure rise time of the test item / cellulose mixture recorded was 27817 ms, this deviation was not considered to have affected the quality or the interpretation of the results obtained. - GLP compliance:
- yes (incl. QA statement)
Test material
- Reference substance name:
- Cabohydrates and Sugars, hexitols, anhydro
- IUPAC Name:
- Cabohydrates and Sugars, hexitols, anhydro
- Reference substance name:
- Carbohydrates and Sugars, hexitols, anhydro
- EC Number:
- 309-665-4
- EC Name:
- Carbohydrates and Sugars, hexitols, anhydro
- Cas Number:
- 100683-96-3
- IUPAC Name:
- 2-(1,2-dihydroxyethyl)oxolane-3,4-diol; hexahydrofuro[3,2-b]furan-3,6-diol
- Test material form:
- other: Brown opaque viscous liquid
Constituent 1
Constituent 2
Results and discussion
Test results (Oxidising liquids)open allclose all
- Sample tested:
- test mixture (not specified)
- Remarks:
- migrated information
- Parameter:
- mean pressure rise time
- Result:
- 27 817 ms
- Sample tested:
- reference mixture (not specified)
- Remarks:
- migrated information
- Parameter:
- mean pressure rise time
- Result:
- 2 584 ms
- Sample tested:
- reference mixture (not specified)
- Remarks:
- migrated information
- Parameter:
- mean pressure rise time
- Result:
- 853 ms
- Sample tested:
- reference mixture (not specified)
- Remarks:
- migrated information
- Parameter:
- mean pressure rise time
- Result:
- 72 ms
Applicant's summary and conclusion
- Interpretation of results:
- other: no oxidising properties
- Remarks:
- Migrated information
- Conclusions:
- The mean pressure rise time obtained with the test item / cellulose mixture was higher than the mean pressure rise time obtained with the three mixtures of reference item / cellulose.
The test item was not classified as an oxidising liquid of Division 5.1 and not classified following EC No. 1272/2008 (CLP) under the experimental conditions used. - Executive summary:
The mean pressure rise times obtained with the three reference item / cellulose mixtures and with the test item / cellulose mixture were:
Mean pressure rise time (ms)
Reference items
Test item
50% perchloric acid solution 72 27817 40% aqueous sodium chlorate solution 853 27817 65% aqueous nitric acid solution 2584 27817
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
