Registration Dossier

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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

First-aid measures

Emergency measure - Inhalation: Remove patient from exposure. Obtain medical attention if

ill effects occur.

Emergency measure - Eyes: Remove particles by irrigating with eye wash solution or

clean water, holding the eyelids apart. Obtain medical

attention.

Emergency measure - Skin: Remove contaminated clothing. Wash skin with water. If

symptoms (irritation or blistering) occur obtain medical

attention.

Emergency measure - Ingestion: Do not induce vomiting. Wash out mouth with water. Obtain

medical attention if ill effects occur.

Fire-fighting measures

Recommended extinguishing agent: Extinguish with dry chemical or foam.

Product arising from burning: Carbon dioxide, Carbon monoxide, oxides of Phosphorus.

Product determined by test: N

Protective equipment: A self contained breathing apparatus and suitable protective

clothing should be worn in fire conditions.

Accidental release measures

Emergency measures in case of spillage: Avoid release to the environment. Spillages of Alpha Ligand

will be easily detected because of the pungent

characteristic smell. Collect using a high efficiency vacuum

cleaner. Transfer to a container for disposal or recovery.

Spillages or uncontrolled discharges into watercourses must

be alerted to the appropriate regulatory body.

Material is suitable for recovery. Spent catalyst or waste

material to be returned to manufacturer for

recovery/recycling.

Handling and storage

Handling: Alpha Ligand is an air and moisture sensitive material. It

will arrive on-site in specially designed, air-tight

packaging, which is designed so that it can be transferred

to a process vessel with no exposure to air. It should not

be transferred to another container prior to use.

Storage: Keep only in the original container. Keep container tightly

closed and dry. Store under Nitrogen. Material will be

present on manufacturing sites in relatively small

quantities i.e. less than 500 Kg at any given time. Storage

temperature 0-40 deg C.

Packaging of the substance and or preparation: 60L Stainless Steel pressure vessel (UN Tariff No. BOE-6000)

.

Transport information

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Marine transport (UN RTDG/IMDG)

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Air transport (UN RTDG/ICAO/IATA)

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Special provisions / remarks
Remarks:
Transport code: UN No. 3077
Transport: Proper Shipping Name: UN3077, ENVIRONMENTALLY HAZARDOUS
SUBSTANCE, SOLID, N.O.S. (1,2-Bis(di-
tertbutylphosphinomethyl)benzene), 9, lll.

Class: 9

Packing group: III

Marine Pollutant: Classified as a Marine Pollutant.

ADR Classification Code: M7

ADR HIN: 90

ADR Transport Category: 3

UK CDG Road, Emergency Action Code: 2Z
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Exposure controls / personal protection

Stability and reactivity

Danger other than fire: None known.

Chemical reaction with water: The substance will react with any dissolved oxygen in water.

Dust explosion: Unlikely to pose dust explosion hazard.

Dust explosion determined by test: N

Disposal considerations

Industry - Possibility of recovery/recycling: The used material will be returned to the manufacturer for

recycling.

Industry - Possibility of neutralisation: None known. The substance reacts with oxygen to form

phosphine oxides however the toxicity of the oxides should

be regarded as comparable to the toxicity of the substance

itself.

Industry - Possibility of destruction: controlled discharge: Not recommended.

Industry - Possibility of destruction - incineration: Disposal by incineration with waste gas treatment is possibl

e.

Industry - Possibility of destruction - water purification: Not recommended.

Public at large - Possibility of recovery/recycling: The substance will not enter the public domain.