workplace-signs

Workplace Signs - minimum requirements & signs on containers and pipes

This directive requires employers to ensure proper signage is posted in areas where hazards cannot be avoided or reduced. The annexes to this directive provide detailed information about the minimum requirements for all safety and health signs. According to the annexes to the directive, storage areas and containers containing chemical substances or mixtures that are classified as hazardous according to the CLP Regulation (1272/2008/EC) must be marked and/or labeled.

Index
081-002-00-9
Danger Symbols
Skull and crossbones

Health hazard


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Group members
This group of substance has the following member substances:
Name EC / List no. CAS no. Association
Sulfuric acid, thallium(3+) salt (2:1), dihydrate - 87963-73-3 Expert judgement
Dithallium sulphate 231-201-3 7446-18-6 Expert judgement
Thallium hydrotris(1-pyrazolyl)borate - 34269-45-9 Expert judgement
Sulfuric acid, aluminum thallium salt - 52238-56-9 Expert judgement
Leach residues, zinc refining flue dust, cadmium-thallium ppt.
Sponge produced by leaching and precipitating cadmium and thallium fumes and flue dusts from lead/zinc smelting operations.
296-097-4 92257-11-9 Expert judgement
Thallium (III) acetate sesquihydrate 219-913-2 2570-63-0 Expert judgement
Thallium, (4-methylphenyl)bis(trifluoroacetato-O)- 631-044-4 23586-55-2 Expert judgement
Sulfuric acid, thallium(3+) salt (2:1), tetrahydrate - 37667-57-5 Expert judgement
Thallium hydrogen carbonate 249-868-4 29809-42-5 Expert judgement
Thallium(1+) propan-2-olate 254-386-2 39262-04-9 Expert judgement
Thallium acetate 239-947-1 15843-14-8 Expert judgement
Thallium fluoride 232-154-1 7789-27-7 Expert judgement
Oxalic acid dithallium(I) salt - 30737-24-7 Expert judgement
Mercury thallium dinitrate 301-543-9 94022-47-6 Expert judgement
Thallium (201Tl) Chloride Injection - 55172-29-7 Expert judgement
2-Butanol, 2-methyl-, thallium(1+) salt - 75222-21-8 Expert judgement
Thallium phosphate 257-461-8 51833-34-2 Expert judgement
Sulfuric acid, thallium salt - 10031-59-1 Expert judgement
Dithallium oxide 215-220-4 1314-12-1 Expert judgement
Dithallium sulphide 215-250-8 1314-97-2 Expert judgement
Bismuth, compound with thallium (1:1) 234-982-9 12048-36-1 Expert judgement
Sulfuric acid, thallium(2+) salt - 37475-01-7 Expert judgement
Dithallium dichromate 236-626-8 13453-35-5 Expert judgement
Thallium triarsenide 281-902-3 84057-85-2 Expert judgement
Thallium trichloride 236-625-2 13453-32-2 Expert judgement
Acetic acid, fluoro-, thallium(I) salt - 63905-90-8 Expert judgement
Bismuth thallium( 1) cation pentadecaiodide - 67338-06-1 Expert judgement
Thallium acetate 209-257-5 563-68-8 Expert judgement
Thallium telluride (Tl2Te3) - 12040-16-3 Expert judgement
Residues, thallium - 69029-81-8 Expert judgement
Dithallium trioxide 215-229-3 1314-32-5 Expert judgement
Thallium selenide 234-895-6 12039-52-0 Expert judgement
Thallium iodate 238-831-8 14767-09-0 Expert judgement
Thallium telluride (TlTe) - 12040-12-9 Expert judgement
Antimony, compound with thallium (1:1) 249-428-1 29095-38-3 Expert judgement
Selenious acid, dithallium(1+) salt - 15123-92-9 Expert judgement
Thallium(3+) triformate 276-195-3 71929-23-2 Expert judgement
Thallium hydroxide 234-708-8 12026-06-1 Expert judgement
Carbamic acid, diethyldithio-, thallium complex - 18756-72-4 Expert judgement
Thallium(i) metaborate - 16979-36-5 Expert judgement
Perrhenic acid, thallium salt 683-357-0 14013-75-3 Expert judgement
Slimes and Sludges, thallium
Product of adding a sulfidizer to a thallium-rich solution during lead refining. Consists primarily of thallium and cadmium sulfides.
273-835-3 69029-95-4 Expert judgement
Thallium nitrate 233-273-1 10102-45-1 Expert judgement
m-Toluic acid, alpha,alpha,alpha-trifluoro-, thallium salt - 63980-13-2 Expert judgement
Sulfuric acid, thallium(3+) salt (2:1), monohydrate - 37667-58-6 Expert judgement
Sulfuric acid, thallium(1+) tin(2+) salt (2:2:1) - 27790-36-9 Expert judgement
Thallium(3+) perchlorate 239-677-4 15596-83-5 Expert judgement
Dithallium telluride 234-916-9 12040-13-0 Expert judgement
Thallium iodide 232-199-7 7790-30-9 Expert judgement
Dithallium chromate 236-750-2 13473-75-1 Expert judgement
Thallium tribromide 237-232-9 13701-90-1 Expert judgement
Cyclopentadienylthallium 252-229-2 34822-90-7 Expert judgement
Thallium trifluoride 232-010-8 7783-57-5 Expert judgement
Niobium thallium trioxide 235-634-9 12396-77-9 Expert judgement
Thallium trinitrate 237-325-4 13746-98-0 Expert judgement
Trimethyl thallium - 3003-15-4 Expert judgement
(pentane-2,4-dionato-O,O')thallium 238-081-1 14219-90-0 Expert judgement
Thallium(III) trifluoroacetate 245-761-1 23586-53-0 Expert judgement
Thallium arsenide 234-481-5 12006-09-6 Expert judgement
Thallium chloride 232-241-4 7791-12-0 Expert judgement
Thallium triiodide 236-627-3 13453-37-7 Expert judgement
Thallium iodide (TlI2) - 57232-83-4 Expert judgement
Slimes and Sludges, thallium carbonate - 69029-96-5 Expert judgement
Thallic nitrate, trihydrate 627-221-0 13453-38-8 Expert judgement
Dithallium tris(sulphate) 240-349-8 16222-66-5 Expert judgement
Waste solids, cadmium-electrolysis, thallium-rich
Residue obtained in the electrolysis of cadmium, composed primarily of thallium chromate. Other non-ferrous metals or metal compounds may also be present.
285-572-1 85117-20-0 Expert judgement
Thallium thiocyanate 222-571-7 3535-84-0 Expert judgement
Dithallium trisulphide 234-886-7 12039-17-7 Expert judgement
Dithallium malonate 220-414-7 2757-18-8 Expert judgement
Thallium (I) ethanolate 243-786-2 20398-06-5 Expert judgement
Nitric acid, thallium salt - 16901-76-1 Expert judgement
Dithallium difluoride - 31970-97-5 Expert judgement
Sulfuric acid, thallium(3+) salt (2:1) - 15478-75-8 Expert judgement
Silver thallium dinitrate 247-283-9 25822-21-3 Expert judgement
Dithallium selenide 239-627-1 15572-25-5 Expert judgement
Thallium bromide 232-163-0 7789-40-4 Expert judgement
Dithallium carbonate 229-434-0 6533-73-9 Expert judgement
Chloric acid, thallium(1+) salt - 13453-30-0 Expert judgement
Thallium formate 213-599-0 992-98-3 Expert judgement
lambda1-thallanylium hexafluoro-lambda5-phosphanuide 633-081-1 60969-19-9 Expert judgement

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