workplace-signs

Workplace Signs - minimum requirements & signs on containers and pipes

EU. Workplace Signage: Annexes I and III, Directive 92/58/EEC, last amended by Directive 2014/27/EU, 5 March 2014

This list contains hazardous substances based on Table 3 of Annex VI to the CLP Regulation 1272/2008/EC. According to the annexes to Directive 92/58/EEC, storage areas and containers containing chemical substances or mixtures that are classified as hazardous according to the CLP Regulation must be duly marked and/or labeled. Directive 92/58/EEC requires employers to ensure proper signage is posted in areas where hazards cannot be avoided or reduced.

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Last updated 25 April 2024. Database contains 4307 unique substances/entries.
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Substance Name
EC No.
CAS No.
Index
Danger Symbols
 
Paraffin waxes (coal), brown-coal high-temp tar, clay-treated; Coal Tar Extract [A complex combination of hydrocarbons obtained by the treatment of lignite carbonization tar with bentonite for removal of trace constituents and impurities. It consists predominantly of saturated straight and branched chain hydrocarbons having carbon numbers predominantly greater than C12.]
A complex combination of hydrocarbons obtained by the treatment of lignite carbonization tar with bentonite for removal of trace constituents and impurities. It consists predominantly of saturated straight and branched chain hydrocarbons having carbon numbers predominantly greater than C12.
308-297-1
97926-77-7
648-053-00-4
Health hazard
 Details
Paraffin oils (petroleum), solvent-refined dewaxed heavy; Baseoil — unspecified [A complex combination of hydrocarbons obtained from sulfur-containing paraffinic crude oil. It consists predominantly of a solvent refined deparaffinated lubricating oil with a viscosity of 65cSt at 50 °C.]
A complex combination of hydrocarbons obtained from sulfur-containing paraffinic crude oil. It consists predominantly of a solvent refined deparaffinated lubricating oil with a viscosity of 65cSt at 50°C.
295-810-6
92129-09-4
649-500-00-6
Health hazard
 Details
Paraffin oils (petroleum), catalytic dewaxed light; Baseoil — unspecified [A complex combination of hydrocarbons obtained from a catalytic dewxing process. It consists predominantly of hydrocarbons having carbon numbers predominantly in the range of C15 through C30 and produces a finished oil with a viscosity of less than 100 SUS at 100 °F (19cSt at 40 °C).]
A complex combination of hydrocarbons obtained from a catalytic dewaxing process. It consists predominantly of hydrocarbons having carbon numbers predominantly in the range of C15 through C30 and produces a finished oil with a viscosity of less than 100 SUS at 100°F (19cSt at 40°C).
265-176-5
64742-71-8
649-478-00-8
Health hazard
 Details
Paraffin oils (petroleum), catalytic dewaxed heavy; Baseoil — unspecified [A complex combination of hydrocarbons obtained from a catalytic dewaxing process. It consists predominantly of hydrocarbons having carbon numbers predominantly in the range of C20 through C50 and produces a finished oil with a viscosity of at least 100 SUS at 100 °F (19cSt at 40 °C).]
A complex combination of hydrocarbons obtained from a catalytic dewaxing process. It consists predominantly of hydrocarbons having carbon numbers predominantly in the range of C20 through C50 and produces a finished oil with a viscosity of at least 100 SUS at 100°F (19cSt at 40°C).
265-174-4
64742-70-7
649-477-00-2
Health hazard
 Details
papain
232-627-2
9001-73-4
647-007-00-0
Health hazard
Exclamation mark
 Details
paclobutrazol (ISO); (2RS,3RS)-1-(4-chlorophenyl)-4,4-dimethyl-2-(1H-1,2,4-triazol-1-yl)pentan-3-ol
616-379-6
76738-62-0
603-239-00-4
Health hazard
Exclamation mark
 Details
oxiranemethanol, 4-methylbenzene-sulfonate, (S)-
DAISO CCS-1S-E; S-GLYTO
417-210-7
70987-78-9
607-411-00-X
Health hazard
Corrosion
Exclamation mark
 Details
oxasulfuron (ISO); oxetan-3-yl 2-[(4,6-dimethylpyrimidin-2-yl)-carbamoylsulfamoyl]benzoate
604-430-5
144651-06-9
616-112-00-3
Health hazard
 Details
oxalic acid, nickel salt
243-867-2
20543-06-0
028-039-00-9
Health hazard
Exclamation mark
 Details
oxadiargyl (ISO); 3-[2,4-dichloro-5-(2-propynyloxy)phenyl]-5-(1,1-dimethylethyl)-1,3,4-oxadiazol-2(3H)-one
254-637-6
39807-15-3
613-204-00-5
Health hazard
 Details
orthoboric acid, sodium salt
237-560-2
13840-56-7
005-011-00-4
Health hazard
 Details
olivine, nickel green
An inorganic pigment that is the reaction product of high temperature calcination in which nickel (II) oxide and silicon oxide in varying amounts are homogeneously and ionically interdiffused to form a crystalline matrix of olivine. Its composition may include any one or a combination of the modifiers alkali or alkaline earth halides.
271-112-7
68515-84-4
028-057-00-7
Health hazard
Exclamation mark
 Details
octamethylcyclotetrasiloxane; [D4]
209-136-7
556-67-2
014-018-00-1
Health hazard
 Details
o-tolidine based dyes; 4,4'-diarylazo-3,3'-dimethylbiphenyl dyes, with the exception of those mentioned elsewhere in this Annex
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N,N'-(3,3'-dimethylbiphenyl-4,4'-ylene)di(acetoacetamide) EC / List no: 202-111-1 | CAS no: 91-96-3
Tetrasodium 6,6'-((3,3'-dimethyl-(1,1'-biphenyl-4,4'diyl)bis(azo)bis(4-amino-5-hydroxy-1,3-naphthalenedisulphonate) EC / List no: 206-242-5 | CAS no: 314-13-6
Benzamide, 3,3'-((3,3'-dimethyl(1,1'-biphenyl)-4,4'-diyl)bis(imino(1-acetyl-2-oxo-2,1-ethanediyl)-2,1-diazenediyl))bis(4-methyl- EC / List no: - | CAS no: 64441-14-1
2,2'-[(3,3'-dimethyl[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis[4-nonylphenol] EC / List no: 268-048-7 | CAS no: 67990-27-6
N,N'-(3,3'-dimethyl[1,1'-biphenyl]-4,4'-diyl)bis[2-[(2,4-dichlorophenyl)azo]-3-oxobutyramide] EC / List no: 227-783-3 | CAS no: 5979-28-2
Tetrasodium 3,3'-[(3,3'-dimethyl[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis[4,5-dihydroxynaphthalene-2,7-disulphonate] EC / List no: 218-432-5 | CAS no: 2150-54-1
Disodium 3,3'-((3,3'-dimethyl(1,1'-biphenyl)-4,4'-diyl)bis(azo)bis(4-aminonaphthalene-1-sulphonate) EC / List no: 213-594-3 | CAS no: 992-59-6
N,N'-(3,3'-dimethyl[1,1'-biphenyl]-4,4'-diyl)bis(3-hydroxynaphthalene-2-carboxamide) EC / List no: 223-007-2 | CAS no: 3692-05-5
N,N'-(3,3'-dimethyl[1,1'-biphenyl]-4,4'-diyl)bis[3-oxobutyramide], disodium salt EC / List no: 271-328-1 | CAS no: 68540-94-3
2,2'-[(3,3'-dimethyl[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis[3-oxo-N-phenylbutyramide] EC / List no: 228-789-9 | CAS no: 6358-88-9
2,2'-[(3,3'-dimethyl-4,4'-biphenylylene)bis(azo)]bis[4-(1,1,3,3-tetramethylbutyl)phenol] EC / List no: 230-616-7 | CAS no: 7218-82-8
Tetrasodium 3,3'-[(3,3'-dimethyl[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis[5-amino-4-hydroxynaphthalene-2,7-disulphonate] EC / List no: 200-786-7 | CAS no: 72-57-1
Disodium 3,3'-[(3,3'-dimethyl[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis[2,4-diamino-5-methylbenzenesulphonate] EC / List no: 229-024-1 | CAS no: 6405-94-3
3,3'-[(3,3'-dimethyl[1,1'-biphenyl]-4,4'-diyl)bis[imino(1-acetyl-2-oxoethane-1,2-diyl)azo]]bis[bis(3-aminopropyl)(p-methoxybenzyl)methylammonium] dichloride EC / List no: 255-154-3 | CAS no: 40948-42-3
-
-
611-030-00-4
Health hazard
 Details
O-hexyl-N-ethoxycarbonylthiocarbamate
432-750-3
109202-58-6
006-102-00-1
Health hazard
Exclamation mark
 Details
o-dianisidine based azo dyes; 4,4'-diarylazo-3,3'-dimethoxybiphenyl dyes with the exception of those mentioned elsewhere in this Annex
show/hide
4,4'-[(3,3'-dimethoxy[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis[2,4-dihydro-5-methyl-2-phenyl-3H-pyrazol-3-one] EC / List no: 229-389-7 | CAS no: 6505-29-9
3,3'-(3,3'-dimethoxy-4,4'-biphenylene)bis(2,5-diphenyl-2H-tetrazolium) chloride EC / List no: 217-488-8 | CAS no: 1871-22-3
2,2'-[(3,3'-dimethoxy[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis[N-(4-chlorophenyl)-3-oxobutyramide] EC / List no: 241-469-3 | CAS no: 17453-73-5
2,7-Naphthalenedisulfonic acid, 3,3'-((3,3'-dimethoxy(1,1'-biphenyl)-4,4'-diyl)bis(2,1-diazenediyl))bis(5-amino-4-hydroxy-, lithium sodium salt (1:1:3) EC / List no: - | CAS no: 75659-72-2
6,6'-[(3,3'-dimethoxy[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis[4-amino-5-hydroxynaphthalene-1,3-disulphonic] acid EC / List no: 223-333-5 | CAS no: 3841-14-3
2-Naphthalenecarboxamide, N,N'-(3,3'-dimethoxy(1,1'-biphenyl)-4,4'-diyl)bis(3-hydroxy-, disodium salt EC / List no: - | CAS no: 52735-88-3
Tetrasodium 2,2'-[(3,3'-dimethoxy[1,1'-biphenyl]-4,4'-diyl)bis[azo(2-amino-5-hydroxy-7-sulphonato-6,1-naphthylene)azo]]bis[5-nitrobenzoate] EC / List no: 274-429-9 | CAS no: 70210-33-2
Disodium 4,4'-[(3,3'-dimethoxy[1,1'-biphenyl]-4,4'-diyl)bis[iminocarbonyl(2-hydroxy-4,1-phenylene)azo]]bis(3-hydroxynaphthalene-1-sulphonate) EC / List no: 274-498-5 | CAS no: 70247-69-7
2,2'-[(3,3'-dimethoxy[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis[N-(2-methylphenyl)-3-oxobutyramide] EC / List no: 230-458-9 | CAS no: 7147-42-4
Tetrasodium 3,3'-[(3,3'-dimethoxy[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis[5-(acetylamino)-4-hydroxynaphthalene-2,7-disulphonate] EC / List no: 267-711-8 | CAS no: 67906-44-9
Benzoic acid, 4,4'-((3,3'-dimethoxy(1,1'-biphenyl)-4,4'-diyl)bis(2,1-diazenediyl(2-acetyl-1-oxo-2,1-ethanediyl)imino))bis-, 1,1'-dibutyl ester EC / List no: - | CAS no: 820212-95-1
3,3'-dihydroxy-N,N'-(3,3'-dimethoxybiphenyl-4,4'-diyl)di-2-naphthamide EC / List no: 202-108-5 | CAS no: 91-92-9
2,7-Naphthalenedisulfonic acid, 3,3'-((3,3'-dimethoxy(1,1'-biphenyl)-4,4'-diyl)bis(2,1-diazenediyl))bis(5-amino-4-hydroxy-, lithium sodium salt (1:2:2) EC / List no: - | CAS no: 75659-73-3
1-Naphthalenesulfonic acid, 3,3'-((3,3'-dimethoxy(1,1'-biphenyl)-4,4'-diyl)bis(2,1-diazenediyl))bis(4-hydroxy-, lithium salt (1:2) EC / List no: - | CAS no: 75673-34-6
Tetralithium 3,3'-[(3,3'-dimethoxy[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis[5-amino-4-hydroxynaphthalene-2,7-disulphonate] EC / List no: 275-603-7 | CAS no: 71550-22-6
Disodium 2,2'-[(3,3'-dimethoxy-4,4'-biphenylylene)bis[azo(methylimino)]]di(ethanesulphonate) EC / List no: 241-085-6 | CAS no: 17011-51-7
N,N'-(3,3'-dimethoxy[1,1'-biphenyl]-4,4'-diyl)bis[3-oxobutyramide] EC / List no: 223-873-1 | CAS no: 4104-12-5
4,4'-[(3,3'-dimethoxy[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis[3-hydroxy-N-(2-methoxyphenyl)naphthalene-2-carboxamide] EC / List no: 226-614-0 | CAS no: 5437-88-7
3,3'-[(3,3'-dimethoxy[1,1'-biphenyl]-4,4'-diyl)diazo]bis[5-amino-4-hydroxynaphthalene-2,7-disulphonic] acid, sodium salt EC / List no: 273-439-0 | CAS no: 68966-50-7
Tetrasodium 6,6'-[(3,3'-dimethoxy[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis[4-amino-5-hydroxynaphthalene-1,3-disulphonate] EC / List no: 220-026-8 | CAS no: 2610-05-1
2,2'-[(3,3'-dimethoxy[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis[N-(2,4-dimethylphenyl)-3-oxobutyramide] EC / List no: 229-920-2 | CAS no: 6837-37-2
3,3'-(3,3'-dimethoxy[1,1'-biphenyl]-4,4'-diyl)bis[5-[4-(aminothioxomethyl)phenyl]-2-(p-nitrophenyl)-2H-tetrazolium] dichloride EC / List no: 253-257-8 | CAS no: 36889-43-7
Tetrasodium 3,3'-[(3,3'-dimethoxy[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis[5-amino-4-hydroxynaphthalene-2,7-disulphonate] EC / List no: 219-385-3 | CAS no: 2429-74-5
2,7-Naphthalenedisulfonic acid, 3,3'-((3,3'-dimethoxy(1,1'-biphenyl)-4,4'-diyl)bis(2,1-diazenediyl))bis(5-amino-4-hydroxy-, lithium sodium salt (1:3:1) EC / List no: - | CAS no: 75752-17-9
4,4'-[(3,3'-dimethoxy[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis[2,4-dihydro-5-methyl-2-(p-tolyl)-3H-pyrazol-3-one] EC / List no: 229-986-2 | CAS no: 6883-91-6
1-Naphthalenesulfonic acid, 3,3'-((3,3'-dimethoxy(1,1'-biphenyl)-4,4'-diyl)bis(2,1-diazenediyl))bis(4-hydroxy-, lithium sodium salt (1:1:1) EC / List no: - | CAS no: 75673-35-7
2,2'-[(3,3'-dimethoxy[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis[3-oxo-N-phenylbutyramide] EC / List no: 229-388-1 | CAS no: 6505-28-8
3,3'-[(3,3'-dimethoxy[1,1'-biphenyl]-4,4'-diyl)diazo]bis[5-amino-4-hydroxynaphthalene-2,7-disulphonic] acid, sodium salt, compound with 2,2'-iminodiethanol EC / List no: 273-433-8 | CAS no: 68966-43-8
5,5'-(3,3'-Dimethoxy(1,1'-biphenyl)-4,4'-diyl)bis(1-(4-nitrophenyl)-3-phenylformazan) EC / List no: - | CAS no: 63469-14-7
Butanamide, 2,2'-((3,3'-dimethoxy(1,1'-biphenyl)-4,4'-diyl)bis(2,1-diazenediyl))bis(N-(chlorophenyl)-3-oxo- EC / List no: - | CAS no: 72845-99-9
Tetrasodium 4,4'-[(3,3'-dimethoxy[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis[3-hydroxynaphthalene-2,7-disulphonate] EC / List no: 265-533-5 | CAS no: 65151-33-9
Disodium 3,3'-[(3,3'-dimethoxy[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis(4-hydroxynaphthalene-1-sulphonate) EC / List no: 219-382-7 | CAS no: 2429-71-2
5,5'-diphenyl-3,3'-bis(4-nitrophenyl)-2,2'-(3,3'-dimethoxybiphenyl-4,4'-ylene)ditetrazolium dichloride EC / List no: 206-067-4 | CAS no: 298-83-9
Copper, 3,3'-((3,3'-dimethoxy(1,1'-biphenyl)-4,4'-diyl)bis(2,1-diazenediyl))bis(5-amino-4-hydroxy-2,7-naphthalenedisulfonate) morpholine ammonium lithium sodium complexes EC / List no: - | CAS no: 96591-22-9
Tetrasodium 3,3'-[(3,3'-dimethoxy[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis[4,5-dihydroxynaphthalene-2,7-disulphonate] EC / List no: 224-091-3 | CAS no: 4198-19-0
3,3'-(3,3'-dimethoxy[1,1'-biphenyl]-4,4'-diyl)bis[2,5-bis(p-nitrophenyl)-2H-tetrazolium] dichloride EC / List no: 214-665-1 | CAS no: 1184-43-6
4,4'-[(3,3'-dimethoxy[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis[3-hydroxy-N-phenylnaphthalene-2-carboxamide] EC / List no: 233-354-1 | CAS no: 10127-03-4
-
-
611-029-00-9
Health hazard
 Details
o-(p-isocyanatobenzyl)phenyl isocyanate; diphenylmethane-2,4'-diisocyanate
227-534-9
5873-54-1
615-005-00-9
Health hazard
Exclamation mark
 Details
O, O'-(ethenylmethylsilylene)di[(4-methylpentan-2-one)oxime]
ASIL-322; OS-5200
421-870-1
156145-66-3
014-029-00-1
Health hazard
Exclamation mark
 Details
nonylphenol
246-672-0
25154-52-3
601-053-00-8
Health hazard
Corrosion
Exclamation mark
 Details
nonadecafluorodecanoic acid
206-400-3
335-76-2
607-720-00-X
Health hazard
 Details
nitrosodipropylamine
210-698-0
621-64-7
612-098-00-8
Health hazard
Exclamation mark
 Details
nitrofen (ISO); 2,4-dichlorophenyl 4-nitrophenyl ether
217-406-0
1836-75-5
609-040-00-9
Health hazard
Exclamation mark
 Details
nickel;nickel powder [particle diameter < 1mm]
231-111-4
7440-02-0
028-002-00-7
Health hazard
Exclamation mark
 Details
nickel;nickel powder [particle diameter < 1mm]
231-111-4
7440-02-0
028-002-01-4
Health hazard
Exclamation mark
 Details
nickel(II) trifluoroacetate
240-235-8
16083-14-0
028-054-00-0
Health hazard
 Details
nickel(II) sulfite
231-827-7
7757-95-1
028-055-00-6
Health hazard
 Details
nickel(II) stearate; nickel(II) octadecanoate
218-744-1
2223-95-2
028-026-00-8
Health hazard
 Details
nickel(II) silicate
244-578-4
21784-78-1
028-036-00-2
Health hazard
Exclamation mark
 Details
nickel(II) selenite
233-263-7
10101-96-9
028-048-00-8
Health hazard
 Details
nickel(II) propionate
222-102-6
3349-08-4
028-054-00-0
Health hazard
 Details
nickel(II) palmitate
237-138-8
13654-40-5
028-054-00-0
Health hazard
 Details
nickel(II) neoundecanoate
300-093-0
93920-09-3
028-054-00-0
Health hazard
 Details
nickel(II) neononanoate
300-094-6
93920-10-6
028-054-00-0
Health hazard
 Details
nickel(II) neodecanoate
287-469-7
85508-44-7
028-054-00-0
Health hazard
 Details
nickel(II) isooctanoate
249-555-2
29317-63-3
028-054-00-0
Health hazard
 Details
nickel(II) isodecanoate
287-468-1
85508-43-6
028-054-00-0
Health hazard
 Details
nickel(II) hydrogen citrate
242-533-3
18721-51-2
028-054-00-0
Health hazard
 Details
nickel zirkonium trioxide
274-755-1
70692-93-2
028-057-00-7
Health hazard
Exclamation mark
 Details
nickel tungsten tetraoxide
238-032-4
14177-51-6
028-057-00-7
Health hazard
Exclamation mark
 Details
nickel triuranium decaoxide
239-876-6
15780-33-3
028-045-00-1
Health hazard
Exclamation mark
 Details
nickel titanium trioxide
234-825-4
12035-39-1
028-057-00-7
Health hazard
Exclamation mark
 Details
nickel titanium oxide
235-752-0
12653-76-8
028-057-00-7
Health hazard
Exclamation mark
 Details
nickel tin trioxide; nickel stannate
234-824-9
12035-38-0
028-044-00-6
Health hazard
Exclamation mark
 Details
nickel tellurium trioxide
239-967-0
15851-52-2
028-055-00-6
Health hazard
 Details
nickel tellurium tetraoxide
239-974-9
15852-21-8
028-055-00-6
Health hazard
 Details
nickel telluride
235-260-6
12142-88-0
028-040-00-4
Health hazard
Exclamation mark
 Details
nickel sulfide
234-349-7
11113-75-0
028-006-00-9
Health hazard
Exclamation mark
 Details
nickel sulfate
232-104-9
7786-81-4
028-009-00-5
Health hazard
Exclamation mark
 Details
nickel silicate (3:4)
250-788-7
31748-25-1
028-036-00-2
Health hazard
Exclamation mark
 Details
nickel selenide
215-216-2
1314-05-2
028-049-00-3
Health hazard
Exclamation mark
 Details
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