workplace-signs

Workplace Signs - minimum requirements & signs on containers and pipes

EU. Workplace Signage: Annexes I and III, Directive 92/58/EEC, last amended by Directive 2014/27/EU, 5 March 2014

This list contains hazardous substances based on Table 3 of Annex VI to the CLP Regulation 1272/2008/EC. According to the annexes to Directive 92/58/EEC, storage areas and containers containing chemical substances or mixtures that are classified as hazardous according to the CLP Regulation must be duly marked and/or labeled. Directive 92/58/EEC requires employers to ensure proper signage is posted in areas where hazards cannot be avoided or reduced.

Last updated 20 January 2022. Database contains 4247 unique substances/entries.
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607-052-00-9
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2-tert-butyl-4,6-dinitrophenyl acetate ecnumber: 221-706-7 | casnumber: 3204-27-1
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609-031-00-X
Skull and crossbones
Health hazard
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Sodium 2-(1-methylpropyl)-4,6-dinitrophenolate ecnumber: 252-331-7 | casnumber: 35040-03-0
Dinoseb acetate ecnumber: 220-560-1 | casnumber: 2813-95-8
Ammonium 2-sec-butyl-4,6-dinitrophenolate ecnumber: 228-858-3 | casnumber: 6365-83-9
Binapacryl ecnumber: 207-612-9 | casnumber: 485-31-4
2-sec-butyl-4,6-dinitrophenol, compound with 1-aminopropan-2-ol (1:1) ecnumber: 275-931-0 | casnumber: 71735-19-8
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609-026-00-2
Skull and crossbones
Health hazard
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609-034-00-6
Skull and crossbones
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609-029-00-9
Skull and crossbones
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607-042-00-4
Exclamation mark
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425-210-3
169939-84-8
607-557-00-4
Exclamation mark
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200-712-3
69-72-7
607-732-00-5
Health hazard
Exclamation mark
Corrosion
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202-345-4
94-59-7
605-020-00-9
Health hazard
Exclamation mark
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200-545-6
8051-02-3
613-062-00-4
Exclamation mark
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618-004-1
87392-12-9
607-432-00-4
Exclamation mark
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243-193-9
19622-19-6
006-061-00-X
Exclamation mark
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249-013-5
28434-00-6
006-025-00-3
Exclamation mark
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2635-50-9
015-075-00-5
Skull and crossbones
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2703-37-9
015-065-00-0
Skull and crossbones
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953-17-3
015-132-00-4
Skull and crossbones
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436-690-9
220727-26-4
014-038-00-0
Exclamation mark
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A complex combination derived from tall oil. Composed primarily of tricyclic monocarboxylic acids, mainly abietic and dehydroabietic acids. Includes tall-oil rosin stabilized by catalytic disproportionation.
232-484-6
8052-10-6
650-015-00-7
Exclamation mark
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277-299-1
73138-82-6
650-015-00-7
Exclamation mark
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203-585-2
108-46-3
604-010-00-1
Exclamation mark
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202-987-5
101-90-6
603-065-00-9
Health hazard
Skull and crossbones
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233-940-7
10453-86-8
613-060-00-3
Exclamation mark
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A complex combination of hydrocarbons produced as the residual fraction from the distillation of heavy coker gas oil and vacuum gas oil. It predominantly consists of hydrocarbons having carbon numbers predominantly greater than C13 and boiling above approximately 230°C (446°F).
270-796-4
68478-17-1
649-026-00-X
Health hazard
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A complex combination of hydrocarbons obtained by the treatment and distillation of raw steam-cracked naphtha. It consists predominantly of unsaturated hydrocarbons boiling in the range above approximately 180°C (356°F).
308-733-0
98219-64-8
649-046-00-9
Health hazard
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A complex residuum from the vacuum distillation of the residuum from the atmospheric distillation of crude oil. It consists of hydrocarbons having carbon numbers predominantly greater than C13 and boiling above approximately 230°C (446°F).
270-984-6
68512-62-9
649-028-00-0
Health hazard
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A very complex combination of hydrocarbons produced as the residual fraction from the distillation of vacuum residuum and the products from a thermal cracking process. It consists predominantly of hydrocarbons having carbon numbers predominantly greater than C20 and boiling above approximately 350°C (662°F). This stream is likely to contain 5 wt. % or more of 4- to 6-membered condensed ring aromatic hydrocarbons.
272-187-9
68783-13-1
649-033-00-8
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A complex residuum from the vacuum distillation of the residuum from atmospheric distillation of crude oil. It consists predominantly of hydrocarbons having carbon numbers predominantly greater than C24 and boiling above approximately 390°C (734°F).
292-658-2
90669-76-4
649-041-00-1
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A low-sulfur complex combination of hydrocarbons produced as the residual fraction from the topping plant distillation of crude oil. It is the residuum after the straight-run gasoline cut, kerosene cut and gas oil cut have been removed.
271-763-7
68607-30-7
649-031-00-7
Health hazard
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A complex combination of hydrocarbons produced as the residual fraction from distillation of the product from a thermal cracking process. It consists predominantly of unsaturated hydrocarbons having carbon numbers predominantly greater than C20 and boiling above approximately 350°C (662°F). This stream is likely to contain 5 wt. % or more of 4- to 6-membered condensed ring aromatic hydrocarbons.
265-081-9
64741-80-6
649-013-00-9
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A complex combination of hydrocarbons obtained as the residual fraction from the distillation of the products of a steam cracking process (including steam cracking to produce ethylene). It consists predominantly of unsaturated hydrocarbons having carbon numbers predominantly greater than C14 and boiling above approximately 260°C (500°F). This stream is likely to contain 5 wt. % or more of 4- to 6-membered condensed ring aromatic hydrocarbons.
265-193-8
64742-90-1
649-018-00-6
Health hazard
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A complex residuum from the distillation of steam-cracked petroleum residues.
273-272-3
68955-36-2
649-035-00-9
Health hazard
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A complex combination of hydrocarbons obtained during the production of refined petroleum tar by the distillation of steam cracked tar. It consists predominantly of aromatic and other hydrocarbons and organic sulfur compounds.
292-657-7
90669-75-3
649-040-00-6
Health hazard
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A complex combination of hydrocarbons obtained as a column bottom from the separation of effluents from steam cracking naphtha at a high temperature. It boils in the range of approximately 147°C to 300°C (297°F to 572°F) and produces a finished oil having a viscosity of 18cSt at 50°C.
295-517-3
92062-04-9
649-446-00-3
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A complex residuum from the distillation of the products from a steam-cracking process. It consists predominantly of aromatic and unsaturated hydrocarbons having carbon numbers greater than C7 and boiling in the range of approximately 101°C to 555°C (214°F to 1030°F).
271-013-9
68513-69-9
649-029-00-6
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A complex combination of hydrocarbons obtained by the distillation of the products of steam cracking or similar processes after taking off the very light products resulting in a residue starting with hydrocarbons having carbon numbers greater than C5. It consists predominantly of aromatic hydrocarbons having carbon numbers greater than C5 and boiling above approximately 40°C (104°F).
310-057-6
102110-55-4
649-400-00-2
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A complex combination of hydrocarbons obtained as residue from the distillation of steam cracked heat soaked naphtha and boiling in the range of approximately 150°C to 350°C (302°F to 662°F).
297-905-8
93763-85-0
649-448-00-4
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A complex combination of hydrocarbons obtained as a residual fraction from the distillation of hydrotreated steam-cracked naphtha. It consists predominantly of hydrocarbons boiling in the range of approximately 200°C to 350°C (32°F to 662°F).
295-514-7
92062-00-5
649-445-00-8
Health hazard
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A complex combination of hydrocarbons obtained by treating an atmospheric tower residuum with hydrogen in the presence of a catalyst under conditions primarily to remove organic sulfur compounds. It consists of hydrocarbons having carbon numbers predominantly greater than C20 and boiling above approximately 350°C (662°F). This stream is likely to contain 5 wt. % or more of 4- to 6-membered condensed ring aromatic hydrocarbons.
265-181-2
64742-78-5
649-016-00-5
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A complex combination of hydrocarbons produced as the residual fraction from distillation of the products of a hydrocracking process. It consists of hydrocarbons having carbon numbers predominantly greater than C20 and boiling above approximately 350°C (662°F).
265-076-1
64741-75-9
649-012-00-3
Health hazard
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A complex combination of hydrocarbons produced as the residual fraction from the distillation of heavy coker gas oil and light vacuum gas oil. It consists predominantly of hydrocarbons having carbon numbers predominantly greater than C13 and boiling above approximately 230°C(446°F).
270-983-0
68512-61-8
649-027-00-5
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A complex combination of hydrocarbons produced as the residual fraction from distillation of the product from a catalytic reforming process. It consists of predominantly aromatic hydrocarbons having carbon numbers predominantly in the range of C10 through C25 and boiling in the range of approximately 160°C to 400°C (320°F to 725°F). This stream is likely to contain 5 wt. % or more of 4- or 6-membered condensed ring aromatic hydrocarbons.
265-069-3
64741-67-9
649-048-00-X
Health hazard
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A complex residuum from the distillation of catalytic reformer fractionator residue. It boils approximately above 399°C (750°F).
270-792-2
68478-13-7
649-025-00-4
Health hazard
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A complex combination of hydrocarbons produced as the residual fraction from the distillation of the products from a catalytic cracking process. It consists predominantly of hydrocarbons having carbon numbers predominantly greater than C11 and boiling above approximately 200°C (392°F).
295-511-0
92061-97-7
649-043-00-2
Health hazard
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A complex residuum from the catalytic reforming of C6-8 feed. It consists of hydrocarbons having carbon numbers predominantly in the range of C2 through C6.
270-794-3
68478-15-9
649-303-00-5
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A complex residuum from the distillation of butane stream. It consists of aliphatic hydrocarbons having carbon numbers predominantly in the range of C4 through C6.
270-791-7
68478-12-6
649-364-00-8
Health hazard
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A complex residuum from atmospheric distillation of crude oil. It consists of hydrocarbons having carbon numbers predominantly greater than C11 and boiling above approximately 200°C (392°F). This stream is likely to contain 5 wt.% or more of 4- to 6-membered condensed ring aromatic hydrocarbons.
269-777-3
68333-22-2
649-019-00-1
Health hazard
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A complex residuum from the atmospheric distillation of crude oil. It consists of hydrocarbons having carbon numbers predominantly greater than C20 and boiling above approximately 350°C (662°F). This stream is likely to contain 5 wt. % or more of 4- to 6-membered condensed ring aromatic hydrocarbons.
265-045-2
64741-45-3
649-008-00-1
Health hazard
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A complex residuum from the distillation of streams from various refinery operations. It consists of hydrocarbons having carbon numbers in the range of C4 through C5, predominantly butane and boiling in the range of approximately -11.7°C to 27.8°C (11°F to 82°F).
271-010-2
68513-66-6
649-087-00-2
Gas cylinder
Flame
Health hazard
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A cohesive powder composed of coal mineral matter and undissolved coal remaining after extraction of coal by a liquid solvent.
302-681-2
94114-46-2
648-142-00-8
Health hazard
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Residue from the fractional distillation of pitch distillate boiling in the range of approximately 400°C to 470°C (752°F to 846°F). Composed primarily of polynuclear aromatic hydrocarbons, and heterocyclic compounds.
295-507-9
92061-94-4
648-058-00-1
Health hazard
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The residue from the fractional distillation of wash oil boiling in the approximate range of 270°C to 330°C (518°F to 626°F). It consists predominantly of dinuclear aromatic and heterocyclic hydrocarbons.
295-506-3
92061-93-3
648-080-00-1
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The residue from the fraction distillation of crude anthracene boiling in the approximate range of 340°C to 400°C (644°F to 752°F). It consists predominantly of tri- and polynuclear aromatic and heterocyclic hydrocarbons.
295-505-8
92061-92-2
648-105-00-6
Health hazard
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A complex combination of hydrocarbons obtained as the solvent insoluble fraction from solvent refining of a residuum using a polar organic solvent such as phenol or furfural. It consists of hydrocarbons having carbon numbers predominantly higher than C25 and boiling above approximately 400°C (752°F).
265-101-6
64742-01-4
649-459-00-4
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A complex combination of hydrocarbons, sulfur compounds and metal-containing organic compounds obtained as the residue from refinery fractionation cracking processes. It produces a finished oil with a viscosity above 2cSt. at 100°C.
298-754-0
93821-66-0
649-045-00-3
Health hazard
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A complex combination of hydrocarbons obtained by removal of long, branched chain hydrocarbons from a residual oil by solvent crystallization. It consists of hydrocarbons having carbon numbers predominantly greater than C25 and boiling above approximately 400°C (752°F).
265-166-0
64742-62-7
649-471-00-X
Health hazard
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A complex combination of hydrocarbons obtained as the solvent soluble fraction from C3 - C4 solvent deasphalting of a residuum. It consists of hydrocarbons having carbon numbers predominantly higher than C25 and boiling above approximately 400°C (752°F).
265-096-0
64741-95-3
649-456-00-8
Health hazard
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A complex combination of hydrocarbons obtained by treating a petroleum fraction with hydrogen in the presence of a catalyst. It consists of hydrocarbons having carbon numbers predominantly greater than C25 and boiling above approximately 400°C (752°F).
265-160-8
64742-57-0
649-470-00-4
Health hazard
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292-656-1
90669-74-2
649-491-00-9
Health hazard
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A complex combination of hydrocarbons produced by solvent removal of paraffins from the residue of the distillation of acid-treated, hydrocracked heavy paraffins and boiling approximately above 380°C (716°F).
295-499-7
92061-86-4
649-499-00-2
Health hazard
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A complex residuum from the atmospheric distillation of the butane-butylene stream. It consists of aliphatic hydrocarbons having carbon numbers predominantly in the range of C4 through C6.
270-795-9
68478-16-0
649-365-00-3
Health hazard
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A complex combination of hydrocarbons obtained by treatment of a residual oil with a natural or modified clay in either a contacting or percolation process to remove the trace amounts of polar compounds and impurities present. It consists of hydrocarbons having carbon numbers predominantly higher than C25 and boiling above approximately 400°C (752°F).
265-143-5
64742-41-2
649-462-00-0
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A complex combination of hydrocarbons obtained by treatment of solvent-dewaxed petroleum residual oils with bleaching earth for the removal of trace polar constituents and impurities.
309-711-3
100684-38-6
649-526-00-8
Health hazard
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294-843-3
91770-57-9
649-492-00-4
Health hazard
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A complex combination of hydrocarbons obtained by the treatment of solvent-dewaxed petroleum residual oils with activated charcoal for the removal of trace polar constituents and impurities.
309-710-8
100684-37-5
649-525-00-2
Health hazard
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232-645-0
9001-98-3
647-009-00-1
Health hazard
Exclamation mark
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Glass, oxide, chemicals
This category encompasses the various chemical substances manufactured in the production of inorganic glasses. For purposes of this category, 'glass' is defined as an amorfous, inorganic, transparent, translucent or opaque material traditionally formed by fusion of sources of silica with a flux, such as an alkali-metal carbonate, boron oxide, etc. and a stabilizer, into a mass which is cooled to a rigid condition without crystallization in the case of transparent or liquid-phase separated glass or with controlled crystallization in the case of glass-ceramics. The category consists of the various chemical substances, other than by-products or impurities, which are formed during the production of various glasses and concurrently incorporated into a glass mixture. All glasses contain one or more of these substances, but few, if any, contain all of them. The elements listed below are principally present as components of oxide systems but some may also be present as halides or chalcogenides, in multiple oxidation states, or in more complex compounds. Trace amounts of other oxides or chemical compounds may be present. Oxides of the first seven elements listed* comprise more than 95 percent, by weight, of the glass produced. @Aluminium*@Lead@Boron*@Lithium@Calcium*@Manganese@Magnesium*@Molybdenum@Potassium*@Neodymium@Silicon*@Nickel@Sodium*@Niobium@Antimony@Nitrogen@Arsenic@Phosphorus@Barium@Praseodymium@Bismuth@Rubidium@Cadmium@Selenium@Carbon@Silver@Cerium@Strontium@Cesium@Sulfur@Chromium@Tellurium@Cobalt@Tin@Copper@Titanium@Germanium@Tungsten@Gold@Uranium@Holmium@Vanadium@Iron@Zinc@Lanthanum@Zirconium
ecnumber: 266-046-0 | casnumber: 65997-17-3
Zirconia Aluminosilicate Refractory Ceramic Fibres
are fibres covered by index number 650-017-00-8 in Annex VI, part 3, table 3.1 of Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, and fulfil the three following conditions: a) oxides of aluminium, silicon and zirconium are the main components present (in the fibres) within variable concentration ranges b) fibres have a length weighted geometric mean diameter less two standard geometric errors of 6 or less micrometres (µm). c) alkaline oxide and alkali earth oxide (Na2O+K2O+CaO+MgO+BaO) content less or equal to 18% by weight
ecnumber: - | casnumber: -
Aluminosilicate Refractory Ceramic Fibres
are fibres covered by index number 650-017-00-8 in Annex VI, part 3, table 3.1 of Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, and fulfil the three following conditions: a) oxides of aluminium and silicon are the main components present (in the fibres) within variable concentration ranges b) fibres have a length weighted geometric mean diameter less two standard geometric errors of 6 or less micrometres (µm) c) alkaline oxide and alkali earth oxide (Na2O+K2O+CaO+MgO+BaO) content less or equal to 18% by weight
ecnumber: - | casnumber: -
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650-017-00-8
Health hazard
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231-768-7
7723-14-0
015-002-00-7
Flame
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410-880-1
-
612-159-00-9
Corrosion
Exclamation mark
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406-620-1
129217-90-9
616-093-00-1
Exclamation mark
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408-250-6
-
074-002-00-5
Flame
Corrosion
Exclamation mark
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-
612-291-00-7
Health hazard
Exclamation mark
Corrosion
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-
-
612-290-00-1
Health hazard
Skull and crossbones
Corrosion
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432-440-8
220444-73-5
612-254-00-5
Corrosion
Health hazard
Exclamation mark
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426-860-0
191877-09-5
613-242-00-2
Corrosion
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500-033-5
25068-38-6
603-074-00-8
Exclamation mark
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428-630-5
-
603-182-00-5
Exclamation mark
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417-450-2
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650-042-00-4
Exclamation mark
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420-980-7
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613-200-00-3
Corrosion
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424-510-1
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611-139-00-7
Corrosion
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PES-SOLID
420-070-1
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650-048-00-7
Flame
Corrosion
Exclamation mark
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R633
406-230-1
224635-63-6
650-018-00-3
Flame
Health hazard
Corrosion
Exclamation mark
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420-310-3
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650-043-00-X
Exclamation mark
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424-250-9
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611-135-00-5
Corrosion
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417-110-3
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650-045-00-0
Flame
Corrosion
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401-530-9
-
014-022-00-3
Flame
Health hazard
Exclamation mark
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431-120-5
-
607-615-00-9
Skull and crossbones
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439-540-0
-
612-248-00-2
Exclamation mark
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432-200-2
-
014-043-00-8
Corrosion
Exclamation mark
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412-780-3
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042-004-00-5
Exclamation mark
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421-290-9
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613-225-00-X
Health hazard
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435-180-3
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601-084-00-7
Health hazard
Exclamation mark
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411-130-6
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603-137-00-X
Corrosion
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415-870-0
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616-102-00-9
Exclamation mark
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402-850-1
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611-043-00-5
Corrosion
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414-620-8
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611-116-00-1
Corrosion
Exclamation mark
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444-050-5
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611-175-00-3
Corrosion
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428-400-4
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607-591-00-X
Corrosion
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423-200-3
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607-513-00-4
Corrosion
Exclamation mark
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428-260-4
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611-143-00-9
Corrosion
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406-870-1
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611-104-00-6
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export-type