workplace-signs

Workplace Signs - minimum requirements & signs on containers and pipes

EU. Workplace Signage: Annexes I and III, Directive 92/58/EEC, last amended by Directive 2014/27/EU, 5 March 2014

This list contains hazardous substances based on Table 3 of Annex VI to the CLP Regulation 1272/2008/EC. According to the annexes to Directive 92/58/EEC, storage areas and containers containing chemical substances or mixtures that are classified as hazardous according to the CLP Regulation must be duly marked and/or labeled. Directive 92/58/EEC requires employers to ensure proper signage is posted in areas where hazards cannot be avoided or reduced.

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Last updated 23 April 2024. Database contains 4307 unique substances/entries.
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Substance Name
EC No.
CAS No.
Index
Danger Symbols
 
hydrogen
215-605-7
1333-74-0
001-001-00-9
Flame
Gas cylinder
 Details
aluminium lithium hydride
240-877-9
16853-85-3
001-002-00-4
Flame
Corrosion
 Details
sodium hydride
231-587-3
7646-69-7
001-003-00-X
Flame
 Details
calcium hydride
232-189-2
7789-78-8
001-004-00-5
Flame
 Details
lithium
231-102-5
7439-93-2
003-001-00-4
Flame
Corrosion
 Details
n-hexyllithium
N-HEXYLLITHIUM
404-950-0
21369-64-2
003-002-00-X
Flame
Corrosion
 Details
(2-methylpropyl)lithium; isobutyllithium
440-620-2
920-36-5
003-003-00-5
Flame
Corrosion
Exclamation mark
 Details
beryllium
231-150-7
7440-41-7
004-001-00-7
Skull and crossbones
Health hazard
 Details
beryllium compounds with the exception of aluminium beryllium silicates, and with those specified elsewhere in this Annex
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Disodium tetrafluoroberyllate EC / List no: 237-630-2 | CAS no: 13871-27-7
Phosphoric acid, beryllium salt EC / List no: 252-356-3 | CAS no: 35089-00-0
Beryllium acetylide EC / List no: 208-050-7 | CAS no: 506-66-1
Beryllium hydroxide EC / List no: 236-368-6 | CAS no: 13327-32-7
Steel manufacture, chemicals
This category includes the chemical substances which are manufactured as part of steel and alloy steels. The following list identifies those elements which may exist in steel or which may comprise compounds present in steel or alloy steels. Aluminum, beryllium, boron, calcium, carbon, cerium, chromium, cobalt, copper, hafnium, iron, lanthanum, lead, magnesium, manganese, molybdenum, nickel, niobium, nitrogen, oxygen, phosphorus, selenium, silicon, sulfur, tantalum, tin, titanium, tungsten, vanadium, yttrium, zinc, zirconium.
EC / List no: 266-048-1 | CAS no: 65997-19-5
Beryllium chloride EC / List no: 232-116-4 | CAS no: 7787-47-5
Beryllium diboride EC / List no: 235-443-0 | CAS no: 12228-40-9
Octadecanoic acid, beryllium salt EC / List no: - | CAS no: 16687-38-0
Diethylberyllium EC / List no: 208-823-9 | CAS no: 542-63-2
Aluminium alloy, Al,Be EC / List no: 603-236-8 | CAS no: 12770-50-2
Beryllium orthosilicate EC / List no: 239-251-8 | CAS no: 15191-85-2
Bertrandite (Be4(OH)2O(SiO3)2) EC / List no: 235-299-9 | CAS no: 12161-82-9
Beryllium oxyfluoride EC / List no: - | CAS no: 63990-88-5
Beryllium carbonate EC / List no: 236-030-8 | CAS no: 13106-47-3
Beryllium EC / List no: 231-150-7 | CAS no: 7440-41-7
Beryllium telluride EC / List no: 235-451-4 | CAS no: 12232-27-8
Beryllium hydrogen phosphate (1:1) EC / List no: - | CAS no: 13598-15-7
Zinc beryllium silicate EC / List no: - | CAS no: 39413-47-3
Beryllium sulphide EC / List no: 237-064-6 | CAS no: 13598-22-6
Beryllium selenide EC / List no: 235-450-9 | CAS no: 12232-25-6
Beryllium sulfate tetrahydrate EC / List no: 629-461-1 | CAS no: 7787-56-6
Beryllium nitrate EC / List no: 237-062-5 | CAS no: 13597-99-4
Copper alloy, Cu 96, Be 2.2-2.8, Ni 1.1 (CDA 827) EC / List no: - | CAS no: 11108-64-8
Beryllium diboride EC / List no: 235-694-6 | CAS no: 12536-51-5
Beryllium diammonium tetrafluoride EC / List no: 238-948-4 | CAS no: 14874-86-3
Beryllium fluoride EC / List no: 232-118-5 | CAS no: 7787-49-7
Phosphoric acid, beryllium salt (2:3) EC / List no: - | CAS no: 13598-26-0
Bis(pentane-2,4-dionato-O,O')beryllium EC / List no: 233-513-5 | CAS no: 10210-64-7
Beryllium sulphate EC / List no: 236-842-2 | CAS no: 13510-49-1
Beryllium, bis(carbonato(2-))dihydroxytri- EC / List no: - | CAS no: 66104-24-3
Beryllium hexaboride EC / List no: 235-657-4 | CAS no: 12429-94-6
Beryllium phosphide EC / List no: 261-137-1 | CAS no: 58127-61-0
Beryllium dibromide EC / List no: 232-115-9 | CAS no: 7787-46-4
Beryllium di(acetate) EC / List no: 208-850-6 | CAS no: 543-81-7
Beryllium zinc silicate EC / List no: 247-151-0 | CAS no: 25638-88-4
Silicic acid, beryllium salt EC / List no: 261-293-0 | CAS no: 58500-38-2
Triberyllium nitride EC / List no: 215-132-6 | CAS no: 1304-54-7
Nitric acid, beryllium salt, tetrahydrate EC / List no: 690-699-4 | CAS no: 13510-48-0
Beryllium phosphide (BeP2) EC / List no: - | CAS no: 1268721-56-7
Beryllium diiodide EC / List no: 232-119-0 | CAS no: 7787-53-3
Beryllium nitrate trihydrate EC / List no: - | CAS no: 7787-55-5
Tetraberyllium boride EC / List no: 235-695-1 | CAS no: 12536-52-6
Hexakis[μ-(acetato-O:O')]-μ4-oxotetraberyllium EC / List no: 242-785-4 | CAS no: 19049-40-2
-
-
004-002-00-2
Skull and crossbones
Health hazard
 Details
beryllium oxide
215-133-1
1304-56-9
004-003-00-8
Skull and crossbones
Health hazard
 Details
boron trifluoride
231-569-5
7637-07-2
005-001-00-X
Gas cylinder
Skull and crossbones
Corrosion
 Details
boron trichloride
233-658-4
10294-34-5
005-002-00-5
Gas cylinder
Skull and crossbones
Corrosion
 Details
boron tribromide
233-657-9
10294-33-4
005-003-00-0
Skull and crossbones
Corrosion
 Details
trialkylboranes, solid
-
-
005-004-00-6
Flame
Corrosion
 Details
trialkylboranes, liquid
-
-
005-004-01-3
Flame
Corrosion
 Details
trimethyl borate
204-468-9
121-43-7
005-005-00-1
Flame
Exclamation mark
 Details
dibutyltin hydrogen borate
DBB
401-040-5
75113-37-0
005-006-00-7
Corrosion
Health hazard
Exclamation mark
 Details
boric acid
234-343-4
11113-50-1
005-007-00-2
Health hazard
 Details
boric acid
233-139-2
10043-35-3
005-007-00-2
Health hazard
 Details
diboron trioxide
215-125-8
1303-86-2
005-008-00-8
Health hazard
 Details
tetrabutylammonium butyltriphenylborate
P3B
418-080-4
120307-06-4
005-009-00-3
Exclamation mark
 Details
N, N-dimethylanilinium tetrakis(pentafluorophenyl)borate
B1; N,N-DIMETHYLANILINUM TETRAKIS(PENTAFLUOROPHENYL)BORATE; TÉTRAKIS(PENTAFLUOROPHÉNYL)BORATE DE N,N-DIMÉTHYLANILINIUM
422-050-6
118612-00-3
005-010-00-9
Health hazard
Corrosion
Exclamation mark
 Details
disodium tetraborate decahydrate
215-540-4
1303-96-4
005-011-00-4
Health hazard
 Details
disodium tetraborate pentahydrate
601-808-1
12179-04-3
005-011-00-4
Health hazard
 Details
disodium tetraborate, anhydrous
215-540-4
1330-43-4
005-011-00-4
Health hazard
 Details
orthoboric acid, sodium salt
237-560-2
13840-56-7
005-011-00-4
Health hazard
 Details
tetraboron disodium heptaoxide, hydrate
235-541-3
12267-73-1
005-011-00-4
Health hazard
 Details
diethyl{4-[1,5,5-tris(4-diethylaminophenyl)penta-2,4-dienylidene]cyclohexa-2,5-dienylidene}ammonium butyltriphenylborate
IRB
418-070-1
141714-54-7
005-012-00-X
Exclamation mark
 Details
diethylmethoxyborane
425-380-9
7397-46-8
005-013-00-5
Flame
Corrosion
Health hazard
Exclamation mark
 Details
4-formylphenylboronic acid
438-670-5
87199-17-5
005-014-00-0
Exclamation mark
 Details
1-chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate)
414-380-4
140681-55-6
005-015-00-6
Corrosion
Exclamation mark
 Details
sodium perborate [containing < 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm];sodium perborate [containing ≥ 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm]
239-172-9
15120-21-5
005-017-00-7
Flame over circle
Corrosion
Health hazard
Exclamation mark
 Details
sodium peroxoborate [containing < 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm];sodium peroxoborate [containing ≥ 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm]
-
-
005-017-00-7
Flame over circle
Corrosion
Health hazard
Exclamation mark
 Details
sodium peroxometaborate [containing < 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm];sodium peroxometaborate [containing ≥ 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm]
231-556-4
7632-04-4
005-017-00-7
Flame over circle
Corrosion
Health hazard
Exclamation mark
 Details
sodium perborate [containing < 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm];sodium perborate [containing ≥ 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm]
239-172-9
15120-21-5
005-017-01-4
Flame over circle
Skull and crossbones
Corrosion
Health hazard
 Details
sodium peroxoborate [containing ≥ 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm]
-
-
005-017-01-4
Flame over circle
Skull and crossbones
Corrosion
Health hazard
 Details
sodium peroxometaborate [containing < 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm];sodium peroxometaborate [containing ≥ 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm]
231-556-4
7632-04-4
005-017-01-4
Flame over circle
Skull and crossbones
Corrosion
Health hazard
 Details
perboric acid (H3BO2(O2)), monosodium salt trihydrate [containing < 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm];perboric acid (H3BO2(O2)), monosodium salt, trihydrate [containing ≥ 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm]
239-172-9
13517-20-9
005-018-00-2
Corrosion
Health hazard
Exclamation mark
 Details
perboric acid (HBO(O2)), sodium salt, tetrahydrate [containing < 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm];perboric acid (HBO(O2)), sodium salt, tetrahydrate [containing ≥ 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm]
231-556-4
10486-00-7
005-018-00-2
Corrosion
Health hazard
Exclamation mark
 Details
perboric acid, sodium salt, monohydrate; sodium peroxoborate [containing < 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm];perboric acid, sodium salt, monohydrate; sodium peroxoborate [containing ≥ 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm];perboric acid, sodium salt, tetrahydrate [containing < 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm];perboric acid, sodium salt, tetrahydrate [containing ≥ 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm];perboric acid, sodium salt; sodium peroxoborate [containing < 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm];perboric acid, sodium salt; sodium peroxoborate [containing ≥ 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm]
234-390-0
11138-47-9
005-018-00-2
Corrosion
Health hazard
Exclamation mark
 Details
sodium peroxoborate hexahydrate [containing < 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm];sodium peroxoborate hexahydrate [containing ≥ 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm]
-
-
005-018-00-2
Corrosion
Health hazard
Exclamation mark
 Details
perboric acid (H3BO2(O2)), monosodium salt trihydrate [containing < 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm];perboric acid (H3BO2(O2)), monosodium salt, trihydrate [containing ≥ 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm]
239-172-9
13517-20-9
005-018-01-X
Corrosion
Health hazard
Exclamation mark
 Details
perboric acid (HBO(O2)), sodium salt, tetrahydrate [containing < 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm];perboric acid (HBO(O2)), sodium salt, tetrahydrate [containing ≥ 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm]
231-556-4
10486-00-7
005-018-01-X
Corrosion
Health hazard
Exclamation mark
 Details
perboric acid, sodium salt, monohydrate; sodium peroxoborate [containing < 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm];perboric acid, sodium salt, monohydrate; sodium peroxoborate [containing ≥ 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm];perboric acid, sodium salt, tetrahydrate [containing < 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm];perboric acid, sodium salt, tetrahydrate [containing ≥ 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm];perboric acid, sodium salt; sodium peroxoborate [containing < 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm];perboric acid, sodium salt; sodium peroxoborate [containing ≥ 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm]
234-390-0
11138-47-9
005-018-01-X
Corrosion
Health hazard
Exclamation mark
 Details
sodium peroxoborate hexahydrate [containing < 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm];sodium peroxoborate hexahydrate [containing ≥ 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm]
-
-
005-018-01-X
Corrosion
Health hazard
Exclamation mark
 Details
perboric acid (HBO(O2)), sodium salt, monohydrate; sodium peroxoborate [containing < 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm];perboric acid (HBO(O2)), sodium salt, monohydrate; sodium peroxoborate [containing ≥ 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm]
231-556-4
10332-33-9
005-019-00-8
Flame over circle
Corrosion
Health hazard
Exclamation mark
 Details
perboric acid, sodium salt, monohydrate; sodium peroxoborate [containing < 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm];perboric acid, sodium salt, monohydrate; sodium peroxoborate [containing ≥ 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm];perboric acid, sodium salt, tetrahydrate [containing < 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm];perboric acid, sodium salt, tetrahydrate [containing ≥ 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm];perboric acid, sodium salt; sodium peroxoborate [containing < 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm];perboric acid, sodium salt; sodium peroxoborate [containing ≥ 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm]
234-390-0
11138-47-9
005-019-00-8
Flame over circle
Corrosion
Health hazard
Exclamation mark
 Details
perboric acid, sodium salt, monohydrate; sodium peroxoborate [containing < 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm];perboric acid, sodium salt, monohydrate; sodium peroxoborate [containing ≥ 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm];perboric acid, sodium salt, tetrahydrate [containing < 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm];perboric acid, sodium salt, tetrahydrate [containing ≥ 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm];perboric acid, sodium salt; sodium peroxoborate [containing < 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm];perboric acid, sodium salt; sodium peroxoborate [containing ≥ 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm]
234-390-0
11138-47-9
005-019-00-8
Flame over circle
Corrosion
Health hazard
Exclamation mark
 Details
perboric acid (HBO(O2)), sodium salt, monohydrate; sodium peroxoborate [containing < 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm];perboric acid (HBO(O2)), sodium salt, monohydrate; sodium peroxoborate [containing ≥ 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm]
231-556-4
10332-33-9
005-019-01-5
Flame over circle
Skull and crossbones
Corrosion
Health hazard
 Details
perboric acid, sodium salt, monohydrate; sodium peroxoborate [containing < 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm];perboric acid, sodium salt, monohydrate; sodium peroxoborate [containing ≥ 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm];perboric acid, sodium salt, tetrahydrate [containing < 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm];perboric acid, sodium salt, tetrahydrate [containing ≥ 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm];perboric acid, sodium salt; sodium peroxoborate [containing < 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm];perboric acid, sodium salt; sodium peroxoborate [containing ≥ 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm]
234-390-0
11138-47-9
005-019-01-5
Flame over circle
Skull and crossbones
Corrosion
Health hazard
 Details
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