workplace-signs

Workplace Signs - minimum requirements & signs on containers and pipes

EU. Workplace Signage: Annexes I and III, Directive 92/58/EEC, last amended by Directive 2014/27/EU, 5 March 2014

This list contains hazardous substances based on Table 3 of Annex VI to the CLP Regulation 1272/2008/EC. According to the annexes to Directive 92/58/EEC, storage areas and containers containing chemical substances or mixtures that are classified as hazardous according to the CLP Regulation must be duly marked and/or labeled. Directive 92/58/EEC requires employers to ensure proper signage is posted in areas where hazards cannot be avoided or reduced.

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Last updated 26 April 2024. Database contains 4307 unique substances/entries.
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Substance Name
EC No.
CAS No.
Index
Danger Symbols
 
isobutylisopropyldimethoxysilane
ALKYLSILANE TZ 01748; DYNASYLAN 9405; EURENOR(R) 5020; PSX 5305
402-580-4
111439-76-0
014-009-00-2
Flame
Exclamation mark
 Details
haloxyfop-etotyl (ISO); 2-ethoxyethyl 2-(4-(3-chloro-5-trifluoromethyl-2-pyridyloxy)phenoxy)propionate; haloxyfop-(2-ethoxyethyl)
HALOXYFOP ETHOXYETHYL EST
402-560-5
87237-48-7
607-207-00-0
Exclamation mark
 Details
3-(bis(2-ethylhexyl)amino methyl)benzothiazole-2(3H)- thione
CM 22-447
402-540-6
105254-85-1
613-080-00-2
Corrosion
Exclamation mark
 Details
4-(1(or 4 or 5 or 6)-methyl-8,9,10-trinorborn-5-en-2- yl)pyridine, reaction mass of isomers
ORRINIFF
402-520-7
125352-06-9
613-079-00-7
Exclamation mark
 Details
trisodium (6-anilino-2-(5-nitro-2-oxidophenylazo)-3-sulphonato-1-naphtholato)(4-sulphonato-1,1'-azodi-2,2'naphtholato)chromate(1-)
SÄUREBLAU 82 226
402-500-8
104105-46-6
024-013-00-6
Corrosion
 Details
2-(4-(3-(4-chlorophenyl)-4,5- dihydropyrazolyl)phenylsulphonyl) ethyldimethylammonium hydrogen phosphonate
AZURANT PYRAZOLINE MR 5401; PYRAZOLINE BRIGHTENER MR 5401; UVITEX 4457
402-490-5
106359-93-7
613-084-00-4
Exclamation mark
 Details
exo-1-methyl-4-(1-methylethyl)-7-oxabicyclo[2.2.1]heptan-2-ol
CINEOLE ALCOHOL
402-470-6
87172-89-2
603-091-00-0
Corrosion
Exclamation mark
 Details
(C16 or C18-n-alkyl)(C16 or C18-n-alkyl)ammonium 2-((C16 or C18-n-alkyl)(C16 or C18-n-alkyl)carbamoyl)benzenesulphonate
OA 8523
402-460-1
-
016-053-00-8
Exclamation mark
 Details
2-(3-(prop-1-en-2-yl)phenyl)prop-2-yl isocyanate
M-TMI
402-440-2
2094-99-7
006-074-00-0
Skull and crossbones
Health hazard
Corrosion
 Details
cinmethylin (ISO); exo-(±)-1-methyl-2-(2-methylbenzyloxy)-4-isopropyl-7-oxabicyclo(2.2.1)heptane
ARGOLD; CINMETHYLIN; WL 95481
402-410-9
87818-31-3
603-093-00-1
Exclamation mark
 Details
(ethyl-3-oxobutanoato-O'1,O'3)(2-dimethylaminoethanolato)(1-methoxypropan-2-olato)aluminium(III), dimerised
AOC 1020X
402-370-2
149057-70-5
013-006-00-3
Flame
Corrosion
 Details
disodium N-carboxymethyl-N-(2-(2-hydroxyethoxy)ethyl)glycinate
DIDA
402-360-8
92511-22-3
607-192-00-0
Corrosion
 Details
S-(3-trimethoxysilyl)propyl 19-isocyanato-11-(6-isocyanatohexyl)-10,12-dioxo-2,9,11,13-tetraazanonadecanethioate
ALKYL ISOCYANATE SILANE SCD 617
402-290-8
85702-90-5
607-184-00-7
Flame
Health hazard
 Details
zinc 2-hydroxy-5-C13-18 alkylbenzoate
Z-6
402-280-3
149144-82-1
607-183-00-1
Exclamation mark
 Details
benzyltributylammonium 4-hydroxynaphthalene-1-sulphonate
BONTRON P-51
402-240-5
102561-46-6
016-052-00-2
Exclamation mark
 Details
4-amino-3-fluorophenol
FAP
402-230-0
399-95-1
604-028-00-X
Health hazard
Exclamation mark
 Details
bromobenzylbromotoluene, reaction mass of isomers
DBBT
402-210-1
99688-47-8
602-071-00-9
Health hazard
Exclamation mark
 Details
4-(2-chloro-4-trifluoromethyl)phenoxy-2-fluoroaniline hydrochloride
WL 125892
402-190-4
113674-95-6
612-094-00-6
Corrosion
Health hazard
Exclamation mark
 Details
trisodium 7-(4-(6-fluoro-4-(2-(2-vinylsulphonylethoxy)ethylamino)-1,3,5-triazin-2-ylamino)-2-ureidophenylazo)naphthalene-1,3,6-trisulphonate
C.I. REACTIVE YELLOW 174; GIALLO REATTIVO 174; JAUNE REACTIF 174; REAKTIV GELB 174
402-170-5
106359-91-5
016-051-00-7
Exclamation mark
 Details
potassium sodium 5-(4-chloro-6-(N-(4-(4-chloro-6-(5-hydroxy-2,7-disulphonato-6-(2-sulphonatophenylazo)-4-naphthylamino)-1,3,5-triazin-2-ylamino) phenyl-N-methyl)amino)-1,3,5-triazin-2-ylamino)-4-hydroxy-3-(2-sulphonatophenylazo)naphthalene-2,7-disulphonat
C.I. REACTIVE RED 231
402-150-6
-
016-050-00-1
Exclamation mark
 Details
cyclohexyldimethoxymethylsilane
CHMMS; CHMS; DYNASYLAN 9407; Z-6187
402-140-1
17865-32-6
014-011-00-3
Exclamation mark
 Details
2-(4-(3-(4-chlorophenyl)-2-pyra zolin-1-yl)phenylsulfonyl)ethyldimethylammonium formate
HOSTALUX VP 3481-1 HOSTALUX N2R
402-120-2
133514-97-3
613-083-00-9
Health hazard
Corrosion
Exclamation mark
 Details
reaction mass of pentyl methylphosphinate and 2-methylbutyl methylphosphinate
MPA
402-090-0
87025-52-3
015-144-00-X
Corrosion
 Details
(6-(4-hydroxy-3-(2-methoxyphenylazo)-2-sulfonato-7-naphthylamino)-1,3,5-triazin-2,4-diyl)bis[(amino-1-methylethyl)ammonium] formate
2691; CARTASOL BRILLANT SCHARLACH K-2GL KONZ.; CARTASOL BRILLANTSCHARLACH K-2GL FLÜSSIG (ZUBEREITUNG); CARTASOL BRILLANTSCHARLACH K-2GL GRANULAT (ZUBEREITUNG); CARTASOL BRILLIANT SCARLET K-2GL; CARTASOL BRILLIANT SCARLET K-2GL CONC.
402-060-7
108225-03-2
611-058-00-7
Health hazard
Corrosion
 Details
methyl 3-sulphamoyl-2-thenoate
A5546
402-050-2
59337-93-8
607-182-00-6
Exclamation mark
 Details
calcium octadecylxylenesulphonate
Z 7
402-040-8
148262-93-5
016-049-00-6
Corrosion
 Details
O-ethylhydroxylamine
ETA; ETA 50 (50 %IGE ZUBEREITUNG); O-ETHYLHYDROXYLAMINE
402-030-3
624-86-2
007-015-00-1
Flame
Skull and crossbones
Health hazard
 Details
2-(2-bromoethoxy)anisole
GUAIACOL-O-ETHYLBROMIDE
402-010-4
4463-59-6
603-090-00-5
Exclamation mark
 Details
N,N,N,N-tetrakis(4,6-bis(butyl- (N-methyl-2,2,6,6-tetramethyl piperidin-4-yl)amino)triazin-2- yl)-4,7-diazadecane-1,10- diamine
CHIMASSORB 119; LOWILITE 19
401-990-0
106990-43-6
613-078-00-1
Exclamation mark
 Details
N-hexadecyl(or octadecyl)-N-hexadecyl (or octadecyl)benzamide
DTBA
401-980-6
-
616-023-00-X
Exclamation mark
 Details
reaction mass of 1,1'-(methylenebis(4,1-phenylene))dipyrrole-2,5-dione and N-(4-(4-(2,5-dioxopyrrol-1-yl)benzyl)phenyl)acetamide and 1-(4-(4-(5- oxo-2H-2-furylide namino)benzyl)phenyl)pyrrole-2,5-dione
DESBIMID
401-970-1
-
613-085-00-X
Exclamation mark
 Details
3-(dimethylamino)propylurea
3-(DIMETHYLAMINO)PROPYL UREA; HST 2844
401-950-2
31506-43-1
006-073-00-5
Corrosion
 Details
reaction mass of 5-heptyl-1,2,4- triazol-3-ylamine and 5-nonyl-1,2,4-triazol-3-ylamine
PK 323
401-940-8
-
613-077-00-6
Exclamation mark
 Details
3-chloro-4,5,α, α, α-pentafluorotoluene
3-CHLORO-4,5-DIFLUOROBENZOTRIFLUORIDE
401-930-3
77227-99-7
602-070-00-3
Flame
Exclamation mark
 Details
isobutyl 3,4-epoxybutyrate
IVAX
401-920-9
100181-71-3
607-191-00-5
Exclamation mark
 Details
methyl acrylamidomethoxyacetate (containing ≥ 0,1 % acrylamid)
MAGME 100 MONOMEER
401-890-7
77402-03-0
607-190-00-X
Health hazard
Exclamation mark
 Details
sodium 3,5-dichloro-2-(5-cyano-2,6-bis(3-hydroxypropylamino)-4-methylpyridin-3-ylazo)benzenesulphonate
H: SÄUREGELB 2829
401-870-8
115035-41-1
016-048-00-0
Corrosion
 Details
(N-benzyl-N-ethyl)amino-3-hydroxyacetophenone hydrochloride
ETILEFRONE. HCL
401-840-4
55845-90-4
606-040-00-0
Corrosion
 Details
3,5-dichloro-2,4-difluorobenzoyl fluoride
3,5-DICHLORO-2,4-DIFLUOROBENZOYLFLUORIDE
401-800-6
101513-70-6
607-181-00-0
Skull and crossbones
Corrosion
 Details
3,5-dichloro-4-(1,1,2,2-tetrafluoroethoxy)aniline
DCATFOB; XRD 473 ANILINE
401-790-3
104147-32-2
612-093-00-0
Exclamation mark
 Details
diethyl 2,4-dihydroxycyclodisiloxane-2,4-diylbis(trimethylene)diphosphonate, tetrasodium salt, reaction products with disodium metasilicate
SIFOSIL; SIFOSIL KONZENTRAT G 96-00 FEST
401-770-4
148324-78-1
650-014-00-1
Corrosion
Exclamation mark
 Details
lead(II) methanesulphonate
BLEIMETHANSULFONAT; LEAD (II) METHANESULFONATE; LEAD METHANE SULPHONATE; LEAD SALT FP
401-750-5
17570-76-2
082-008-00-4
Health hazard
Corrosion
Exclamation mark
 Details
reaction mass of 2-chloroethyl chloropropyl 2-chloroethylphosphonate, reaction mass of isomers and 2-chloroethyl chloropropyl 2-chloropropylphosphonate, reaction mass of isomers
ADINE CP 31
401-740-0
-
015-143-00-4
Exclamation mark
 Details
prosulfocarb (ISO); S-benzyl N, N-dipropylthiocarbamate
PROSULFOCARB
401-730-6
52888-80-9
006-072-00-X
Exclamation mark
 Details
4,4-isobutylethylidenediphenol
AP-5
401-720-1
6807-17-6
604-024-00-8
Health hazard
Exclamation mark
 Details
3-chloro-5-trifluoromethyl-2- pyridylamine
ACTF; P-007
401-670-0
79456-26-1
613-076-00-0
Exclamation mark
 Details
N, N'-(2,2-dimethylpropylidene)hexamethylenediamine
LUPRAGEN VP 9159
401-660-6
1000-78-8
612-092-00-5
Exclamation mark
 Details
hexasodium 7-(4-(4-(4-(2,5-disulphonatoanilino)-6-fluoro-1,3,5-triazin-2-ylamino)-2-methylphenylazo)-7-sulphonatonaphthylazo)naphthalene-1,3,5-trisulphonate
BRUN REACTIF 45; BRUNO REATTIVO 45; C.I. REACTIVE BROWN 45; CIBACROM BROWN 1347; CIBACRON BROWN 1347; REACTIVE BRAUN 45
401-650-1
85665-96-9
016-047-00-5
Exclamation mark
 Details
tin(II) methanesulphonate
STANNOUS METHANE SULPHONAT; STANNOUS METHANE SULPHONATE; TIN (II) METHANE SULPHONATE; TIN METHANE SULPHONATE; TIN METHANESULFONATE; TIN SALT FS; ZINN(II) METHANESULFONATE; ZINN(II)-METHANSULFONAT
401-640-7
53408-94-9
050-018-00-8
Corrosion
Exclamation mark
 Details
potassium 2-hydroxycarbazole-1-carboxylate
AZYLACID-POTASSIUMSALT
401-630-2
96566-70-0
607-180-00-5
Exclamation mark
 Details
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