Registration Dossier
Registration Dossier
Data platform availability banner - registered substances factsheets
Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.
The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.
Diss Factsheets
Use of this information is subject to copyright laws and may require the permission of the owner of the information, as described in the ECHA Legal Notice.
EC number: 284-366-9 | CAS number: 84852-53-9
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Additional information on environmental fate and behaviour
Administrative data
- Endpoint:
- additional information on environmental fate and behaviour
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Study period:
- July 14, 1992 - June 25, 1993
- Reliability:
- 1 (reliable without restriction)
- Rationale for reliability incl. deficiencies:
- other: Study performed according to GLPs via a protocol approved by the U.S. EPA. PBDD/F analytes and LOQ's established by U.S. EPA.
Data source
Referenceopen allclose all
- Reference Type:
- study report
- Title:
- Unnamed
- Year:
- 1 993
- Reference Type:
- publication
- Title:
- Defintive study of the determination of polybrominated dibenzo-p-dioxins and polybrominated dibenzofurans in decabromodiphenyloxide and tetrabromobisphenol-A
- Author:
- Ranken et al.
- Year:
- 1 994
- Bibliographic source:
- Bull. Soc. Chim. Belg. 103(5-6): 218-233
Materials and methods
Test guideline
- Qualifier:
- no guideline available
- Principles of method if other than guideline:
- Extruded pellets of DBDPEthane in high impact polystyrene (HIPS) containing antimony trioxide (Sb2O3) was incinerated by Southwest Research Insitute using a laboratory simulation of municipal waste incineration. The simulation method was developed by Southwest Research Insitute. The combustion products were analyzed for PBDD/PBDF content using HRGC/LRMS and 13C-labelled standards. The methodologies used were approved by the U.S. EPA.
- GLP compliance:
- yes
- Type of study / information:
- Analysis of combustion products of the laboratory simulation of incineration of municipal waste containing DBDPEthane flame retarded HIPS for PBDD/PBDF content.
Test material
- Reference substance name:
- 1,1'-(ethane-1,2-diyl)bis[pentabromobenzene]
- EC Number:
- 284-366-9
- EC Name:
- 1,1'-(ethane-1,2-diyl)bis[pentabromobenzene]
- Cas Number:
- 84852-53-9
- Molecular formula:
- C14H4Br10
- IUPAC Name:
- 1,2,3,4,5-pentabromo-6-[2-(2,3,4,5,6-pentabromophenyl)ethyl]benzene
- Test material form:
- solid: pellets
- Details on test material:
- A representative sample of DBDPEthane produced at the Ethyl Process Development Center, Baton Rouge, LA, in a semi-works production unit. The test substance was combined with HIPS and Sb2/O3, extruded, and cut into pellets. The pellets were shipped to Southwest Research Institute, San Antonio, TX.
Constituent 1
Results and discussion
Any other information on results incl. tables
The combustion samples were analyzed using a VG Trio-1 GC/MS/DS. Combustion samples were spiked with labeled internal standards at or below the LOQ for each. Data collected for the labeled PBDD/PBDF internal standards, which were spiked below target LOQ levels, demonstrated greater than 10:1 S/N ratios and thus met the Guidelines sensitivity objective. The Guidelines target that the labeled internal standards be recovered at 100 +/- 50% was met for 29 of the 32 standards in the test and quality control samples. Recovery of 13C-2,3,7,8 -TBDF and 13C-2,3,7,8 -TBDD from Laboratory Method Blank 1 was 44 and 47%, respectively. Recovery of 13C-2,3,7,8 -PeBDF from test burn PMN-2 was 48%.
The reproducibility of the recoveries of the labeled internal standards from the three incineration experiments showed a percent relative standard deviation of less than 20%, thus meeting data quality objectives. Method accuracy was demonstrated by analyzing two laboratory method blanks that had been fortified with unlabeled analytes at concentrations at or below the target LOQ. Recoveries of the spiked analytes from Fortified Laboratory Method Blank 2 ranged from 99 to 140%, which was within the Guidelines targets. Recoveries of the spiked analytes from fortified Laboratory Method Blank 1 ranged from 100 to 176%. The 176% recovery of 1,2,3,4,7,8 -HxBDF was the only value outside the Guidelines targest. The recovery of octabromodibenzodioxin spiked into the Fortified Laboratory Method Blanks could not be measured.
Analysis of two laboratory method blanks showed that the equipment and procedures did not contribute interferences or analytes. Analysis of the background sample showed that some PBDD/PBDFs were produced by the incinerator itself or were introduced as contaminants during the analysis. In particular, HpBDF and HxBDF could be detected, although their concentration appeared to be considerably below the target LOQ. The quantity of HpBDF and HxBDF did not affect the test burn results.
The results indicated the combustion products of DBDPEthane/HIPS/Sb2O3 samples contained no 2,3,7,8 -substituted PBDD/PBDFs at or above the limits of quantitation. One exception is noted. An adequate detector response could not be established for octabromodibenzo-p-dioxin at the limit of quantitation (S/N 10:1). But in all cases the octabromodibenzo-p-dioxin concentration was below the limit of detection (S/N 3:1).
Applicant's summary and conclusion
- Conclusions:
- A typical HIPS/DBDPEthane/Antimony trioxide resin did not produce PBDD/PBDF at or above the limits of quantitation established for this test by the U.S. EPA.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.