Registration Dossier

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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Hazard for aquatic organisms

Hazard for air

Hazard for terrestrial organisms

Hazard for predators

Additional information

Two studies of acute aquatic toxicity performed with the degradation product hydrochloric acid are available. Infact, Phosphorus pentachloride degrades rapidly in water to form hydrochloric acid and phosphoric acid. The degradation products of phosphorus pentachloride will dissociate in aqueous conditions with the formation of the environmentally ubiquitous ionic species H+, Cl- and phosphate, therefore in can be predicted that the effects of the substance will be indirect and due to pH (acidification) rather than direct. The hazard of hydrochloric acid for the environment is caused by the proton (pH effect). For this reason the effect of hydrochloric acid on the organisms depends on the buffer capacity of the aquatic ecosystem. Latest dossier for registration of HCl on ECHA website reports lower values for acute aquatic toxicity (Invertebrates and algae).

Conclusion on classification

Phosphorus pentachloride immediately dissociates in water. The assessment of environment toxicity is based on toxicity of hydrochloric acid, which is the most dangerous degradation product. The effect of hydrochloric acid depends on pH effect caused by the proton. For this reason no classification is required.