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Guidance on Safe Use

First-aid measures

INHALATION:

Get medical attention immediately. Move exposed person to fresh

air. If it is suspected that fumes are still present, the rescuer should

wear an appropriate mask or self-contained breathing apparatus.

Keep person warm and at rest. If not breathing, if breathing is

irregular or if respiratory arrest occurs, provide artificial respiration

or oxygen by trained personnel. It may be dangerous to the person

providing aid to give mouth-to-mouth resuscitation. If unconscious,

place in recovery position and get medical attention immediately.

Maintain an open airway. Loosen tight clothing such as a collar, tie,

belt or waistband. In case of inhalation of decomposition products

in a fire, symptoms may be delayed. The exposed person may

need to be kept under medical surveillance for 48 hours.

INGESTION:

Get medical attention immediately. Wash out mouth with water.

Move exposed person to fresh air. Keep person warm and at rest.

If material has been swallowed and the exposed person is

conscious, give small quantities of water to drink. Stop if the

exposed person feels sick as vomiting may be dangerous. Do not

induce vomiting unless directed to do so by medical personnel. If

vomiting occurs, the head should be kept low so that vomit does

not enter the lungs. Never give anything by mouth to an

unconscious person. If unconscious, place in recovery position and

get medical attention immediately. Maintain an open airway.

Loosen tight clothing such as a collar, tie, belt or waistband.

SKIN CONTACT:

Flush contaminated skin with plenty of water. Remove

contaminated clothing and shoes. Continue to rinse for at least 10

minutes. Get medical attention. In the event of any complaints or

symptoms, avoid further exposure. Wash clothing before reuse.

Clean shoes thoroughly before reuse. Carefully clean hair, under

the nails, and other hidden areas. In case of blueness of lips, skin

or nails (cyanosis) let the person breathe oxygen. No physical

exertion.

INFORMATION FOR THE PHYSICIAN: Elementary aid,

decontamination, symptomatic treatment and depending on the

formation of methaemoglobin: intravenous administration of

toluidine blue or other redox dyes according to dosage

specifications plus ascorbic acid.

CONTACT WITH THE HOT MELT: Cooling immediately with

plenty of water. Do not remove product crusts which may have

formed neither forcibly nor by applying any solvents to the skin

involved. In order to obtain medical care for possible burns and for

a smooth cleansing of the skin, seek medical advice immediately.

EYE CONTACT:

Immediately flush eyes with plenty of water, occasionally lifting the

upper and lower eyelids. Check for and remove any contact lenses.

Continue to rinse for at least 10 minutes. Get medical attention.

NOTES TO THE PHYSICIAN:

Elementary aid, decontamination, symptomatic treatment and depending on the formation of methaemoglobin: intravenous administration of toluidine blue or other redox dyes according to dosage specifications plus ascorbic acid

Fire-fighting measures

EXTINGUISHING MEDIA

Suitable: In case of fire, use water spray (fog), foam, dry chemical or CO2.

Not suitable: Never use water jet.

Hazards from the substance or mixture:

In a fire or if heated, a pressure increase will occur and the container may burst.

Hazardous combustion products:

Decomposition products may include the following materials:

carbon oxides, nitrogen oxides, halogenated compounds

Special precautions for fire-fighters:

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. This material is toxic to aquatic organisms. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain.

Special protective equipment for fire-fighters:

Fire-fighters should wear appropriate protective equipment and selfcontained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Accidental release measures

PERSONAL PRECAUTIONS:

Avoid exposure - obtain special instructions before use. No action shall be taken involving any personal risk or without suitable training. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist. Provide adequate ventilation. Put on appropriate personal protective equipment (see Section 8 SDS).

ENVIRONMENTAL PRECAUTIONS:

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

LARGE SPILL:

Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13 SDS). Dispose of via a licensed waste disposal contractor.

Note: see Section 1 for emergency contact information and Section 13 SDS for waste disposal. Contaminated absorbent material may pose

the same hazard as the spilled product.

SMALL SPILL:

Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble or absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Handling and storage

Precautions for safe handling:

Avoid exposure - obtain special instructions before use. Put on appropriate personal protective equipment (see Section 8 SDS). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Avoid release to the environment. If during normal use the material

presents a respiratory hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous.

The product is registered with strictly controlled conditions as defined in Article 17(3) or 18(4) of regulation (EC) no. 1907/2006 (REACH Regulation) and must therefore be handled as such. Refer to the industry guidance prepared by Concawe/Cefic/EFCG for advice on the confirmation of strictly controlled conditions.

Conditions for safe storage, including any incompatibilities:

Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and wellventilated area, away from incompatible materials (see Section 10 SDS) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid

environmental contamination.

Transport information

Shipping

SpecialProvisions

Shipping

Remarks

Marine transport (UN RTDG/IMDG)

Shipping

Remarks

Shipping

Remarks

SpecialProvisions

Exposure controls / personal protection

This substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 17(3) for on-site isolated intermediates and, in case the substance is transported to other sites for further processing, the substance should be handled at these sites under the Strictly Controlled Conditions as specified in REACH regulation Article 18(4). Site  documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at each Manufacturing site.

Written confirmation of application of Strictly Controlled Conditions has been received from every affected Distributor and Downstream Manufacturer/User of the Registrants intermediate.

RECOMMENDED MONITORING PROCEDURES:

If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to monitoring standards, such as the following: European Standard EN 689 (Workplace atmospheres - Guidance for the assessment of exposure by

inhalation to chemical agents for comparison with limit values and measurement strategy) European Standard EN 14042 (Workplace atmospheres - Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents) European Standard EN 482 (Workplace atmospheres - General requirements for the performance of procedures for the measurement of chemical agents) Reference to national guidance documents for methods for the determination of hazardous substances will also be required.

RISK MANAGEMENT MEASURES- OCCUPATIONAL EXPOSURE CONTROL

TECHNICAL MEASURES:

The substance shall be rigorously contained by technical means during its whole lifecycle including manufacture, purification, cleaning and maintenance of equipment, sampling, analysis, loading and unloading of equipment or vessels, waste disposal or purification and storage. Procedural and control technologies shall be used that minimise emission and any resulting exposure. In cases of accident and where waste is generated, procedural and/ or control technologies shall be used to minimise emissions and the resulting exposure during purification or cleaning and maintenance procedures.

ORGANISATIONAL MEASURES:

Only properly trained and authorised personnel shall handle the substance. In the case of cleaning and maintenance works, special

procedures such as purging and washing shall be applied before the system is opened and entered.

Respiratory protection :

If exposure cannot be ruled out, e.g. during product transfer, sampling or maintenance, a well-fitting respiratory mask conforming to standards or well-fitting respiratory device conforming to standards must be worn. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Recommended: Full mask with type ABEK filter.

Hand protection :

Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if product contact cannot be excluded. After contamination with product change the gloves immediately and dispose of them according to relevant national and local regulations. Recommended: (< 1 hour) Baypren , Viton® or PVC gloves.

Eye protection :

Safety eyewear complying with an approved standard should be used to avoid exposure to liquid splashes, mists, gases or dusts.

Recommended: safety glasses with side-shields

Skin protection:

Wear protective clothing. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Recommended: Wear protective clothing.

Hygiene measures:

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewashstations and safety showers are close to the workstation location.

Environmental exposure controls

Technical measures:

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, special waste water treatment, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

Stability and reactivity

Reactivity:

No specific test data related to reactivity available for this product or its ingredients.

STABILITY:

The product is stable.

POSSIBILITY OF HAZARDOUS REACTIONS:

Under normal conditions of storage and use, hazardous reactions will not occur.

CONDITIONS OT AVOID:

In the case of dusty organic products the possibility of a dust explosion should always be considered. No hazardous reactions when used as directed. Avoid release to the environment. In the presence of concentrated alkali chloronitrophenolate is formed which is explodable in the dry state, by e.g. friction.

HAZARDOUS COMBUSTION PRODUCTS:

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

Disposal considerations

METHODS OF DISPOSAL:

Examine possibilities for re-utilisation. Product residues and uncleaned empty containers should be packaged, sealed, labelled, and disposed of or recycled according to relevant national and local regulations. Where large quantities are concerned, consult the supplier. When uncleaned empty containers are passed on, the recipient must be warned of any possible hazard that may be caused by residues. For disposal within the EC, the appropriate code according to the European Waste List (EWL) should be used. It is among the tasks of the polluter to assign the waste to waste codes specific to industrial sectors and processes according to the European Waste List (EWL)

HAZARDOUS WASTE:

The classification of the product may meet the criteria for a hazardous waste.