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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Explosiveness

Currently viewing:

Administrative data

Endpoint:
explosiveness
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
1 (reliable without restriction)

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2015
Report date:
2015

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
other: “Manual of Test Criteria" of “Recommendations of Dangerous Goods"; UN-Test 1 (c), 2 (c) und C.1 (Time-Pressure-Test)
Deviations:
no
GLP compliance:
no

Test material

Constituent 1
Reference substance name:
Ethylmagnesiumbromide
IUPAC Name:
Ethylmagnesiumbromide
Test material form:
other: Solution
Details on test material:
ethylmagnesium bromide 45% in 2-Methyltetrahydrofuran

Results and discussion

Small-scale preliminary testsopen allclose all
Parameter:
other: More sensitive to shock than m-dinitrobenzene
Remarks:
migrated information
Remarks on result:
negative (not further specified)
Parameter:
other: More sensitive to friction than m-dinitrobenzene
Remarks:
migrated information
Remarks on result:
not measured/tested
Parameter:
other: Explosive under influence of flame
Remarks:
migrated information
Remarks on result:
not measured/tested
Parameter:
other: Explosive (not specified)
Remarks:
migrated information
Remarks on result:
negative (not further specified)

Any other information on results incl. tables

   Test 1  Test 2  Test 3
Net weight [g]  5,1  5,2  5,1
Time to 690 kPag [s]  -  -  30
Time to 2070 kPag [s]  -  -  -
Pressure increase time [s]  -  -  -

None of the three tests could show an increase of pressure up to 2070 kPa. Thus, according UN-Test 1(c), 2(c) und C.1 the result is negative.

UN-Tests 1(c) and 2(c)_ "-"

UN Test C.1: "no"

Applicant's summary and conclusion

Executive summary:

According to UN-Test 1(b), 2(b) and E.1 the result is negative.

UN-Tests 1(b) and 2(b): "-"

UN-Test E.1: "no"