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Diss Factsheets

Environmental fate & pathways

Monitoring data

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Administrative data

Endpoint:
monitoring data
Type of information:
experimental study
Adequacy of study:
key study
Study period:
10/2001 to 10/2002
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
other: study documented in sufficient details, however some inconsistences were found in respect to sampling periods (sediment/mussel) and spiking level (mussel) for recovery experiments

Data source

Reference
Reference Type:
publication
Title:
Natural and synthetic endocrine disrupting compounds (EDCs) in water, sediment and biota of a coastal lagoon
Author:
Pojana G, Gomiero A, Jonkers N, Marcomini A
Year:
2007
Bibliographic source:
Environment International 33: 929-936 (2007)

Materials and methods

Test guideline
Qualifier:
no guideline required
GLP compliance:
not specified
Type of measurement:
concentration at contaminated site
Media:
surface water

Test material

Constituent 1
Chemical structure
Reference substance name:
Benzophenone
EC Number:
204-337-6
EC Name:
Benzophenone
Cas Number:
119-61-9
Molecular formula:
C13H10O
IUPAC Name:
diphenylmethanone

Study design

Details on sampling:
Water samples were collected at 4 stations located in the central Venice lagoon. The sampling sites were selected according to known major potential sources of endocrine disrupting compounds.
Station 1 (Isola delle Tresse) is affected by the treated industrial effluents from the nearby industrial district of Porto Marghera and by the effluent of a municipal mechanical-biological stp
Station 2 ((S. Nicolo) and Station 3 (Celestia) receive municipal untreated sewage from Lido island and the historical centre of Venice, respectively
Station 4 (S. Erasmo) located near the sea inlet, was assumed to be little affected by direct discharges and thus chosen as environmental background site.
Grab water samples were collected during 10 subsequent sampling sessions from October 2001 to October 2002
1000 mL water samples were extracted by SPE on a C-18 column and analyzed by HPLC/ESI-MS.

Results and discussion

Concentration
Country:
Italy
Location:
Venice lagoon
Substance or metabolite:
substance
Remarks on result:
other: benzophenone concentrations: <2.6 to 136 ng/L

Any other information on results incl. tables

Concentration of benzophenone in Venice lagoon water samples collected between October, 2001 and October 2002

 

Sampling period

Benzophenone concentration (ng/L) at sampling station

1

2

3

4

Oct, 2001

<2.6

15

16

-*

Nov, 2001

12

20

-*

<2.6

Feb, 2002

36

37

16

<2.6

May, 2002

6.5

<2.6

<2.6

<2.6

July, 2002

<2.6

<2.6

5.0

5.5

Oct, 2002

113

128

136

87

-* sample not collected

Applicant's summary and conclusion

Conclusions:
In Venice lagoon water samples collected between October, 2001 and October 2002 benzophenone concentrations ranging from <2.6 to 136 ng/L were detected.
Executive summary:

Between October, 2001 and October 2002 water samples were collected at 4 locations in the Venice lagoon and investigated on the occurrence of benzophenone. Benzophenone concentrations ranging from <2.6 to 136 ng/L were detected.