Residues (petroleum), atmospheric

Guidance on Safe Use

First-aid measures

1.Preamble1.1. Indications on Safety Data Sheets (SDS) for the professional user about guidance on safe use of petroleum products, in all its aspects, should take into account that applicable legislation and general accepted practices for the management of industrial routine activities or emergencies, as well as company operating procedures, already compose a background which indicates which general actions are necessary/mandatory, advisable or unadvisable in such cases. An extensive recapitulation of all this background information will not necessarily add information value to a SDS, and may actually decrease the readability of the document, especially in an emergency. Therefore the indications meant for actual inclusion in SDSs can be focused (although not necessarily limited) to:-  Product specific issues (i.e. special hazards or characteristics)-  Key Actions (or group of actions) that are applicable in the specific case1.2. The actual level of detail of information and its phrasing in individual SDSs may reflect local or national conventions or requirements, or company policies, but without infringing on the consistency with the information submitted hereunder. Also, more stringent national or local legal requirements or conventions will take precedence over the guidance provided in this document.

2. Warning before intervention2.1. Hydrogen sulphide (H2S) can accumulate in the headspace of product storage tanks and reach potentially hazardous concentrations.

3. Inhalation 3.1. Symptoms: Nasal irritation. Respiratory tract irritation. Exposure to hot fumes may cause: eye irritation, nose irritation, throat irritation, respiratory tract irritation, headache, nausea, nervousness. 3.2. Move to well-ventilated area. 3.3 Check vital signs regularly and act accordingly. 3.4. If there is any suspicion of inhalation of H2S: - Rescuers must wear breathing apparatus, belt and safety rope, and follow rescue procedures.- Remove casualty to fresh air as quickly as possible.- Immediately begin artificial respiration if breathing has ceased.-Provision of oxygen may help.- Obtain medical advice for further treatment.

4. Skin Contact 4.1. Symptoms: May cause mild skin irritation. Exposure to hot product may cause thermal burns. 4.2.  Remove contaminated, saturated clothing immediately.  4.3 Wash area with soap and water for 10 to 15 minutes.

5. Eye Contact 5.1. Symptoms: May cause mild eye reversible irritation. Exposure to hot fumes may cause severe irritation of eyes and mucous membranes. 5.2. Remove contact lenses. 5.3 Irrigate exposed eyes with 0.9% normal saline if available or water for at least 15 minutes. 5.4 Irrigate before and after removing the lenses to prevent a carry-over of the substances to the shielded area of the lens.

6. Ingestion / Aspiration 6.1. Incidental oral exposure: aspiration hazard; may be fatal if it enters the airways after swallowing. 6.2 IF SWALLOWED: Immediately call a POISON CENTRE or doctor/ physician. Do NOT induce vomiting. If vomiting does occur, have victim lean forward to reduce risk of aspiration.

Fire-fighting measures

1. Product specific hazards and other issues1.1. This substance will float and can be reignited on surface water.2. Extinguishing Media - Foam (Specifically trained personnel only)- Water fog (Specifically trained personnel only)- Dry chemical powder- Carbon dioxide- Other inert gases (subject to regulations)- Sand or earth3. Unsuitable Extinguishing Media3.1. Do not use direct water jets on the burning product; they could cause splattering and spread the fire.3.2. Simultaneous use of foam and water on the same surface is to be avoided as water destroys the foam.4. Combustion Products4.1. Incomplete combustion is likely to give rise to a complex mixture of airborne solid and liquid particulates and gases, including carbon monoxide, H2S, SOx (sulfur oxides) or sulfuric acid and unidentified organic and inorganic compounds.5. Protective Equipment for Firefighters5.1. In case of a large fire or in confined or poorly ventilated spaces wear full fire resistant protective clothing and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Accidental release measures

1. General information1.1. Stop or contain leak at the source if safe to do so.  Avoid direct contact with released material.  Stay upwind. In case of large spillages, alert occupants in downwind areas.1.2. Keep non-involved personnel away from the area of spillage. Alert emergency personnel.Except in case of small spillages, the feasibility of any actions should always be assessed and advised, if possible, by a trained, competent person in charge of managing the emergency.1.3. It is recommended to eliminate all ignition sources if safe to do so (e.g. electricity, sparks, fires, flares). 1.4. When the presence of dangerous amounts of H2S around the spilled product is suspected or proved, additional or special actions may be warranted, including access restrictions, use of special protection equipment, procedures and personnel training.1.5. If required, notify relevant authorities according to all applicable regulations. 2. Personal protection equipment for emergency responders2.1. Small spillages: normal antistatic working clothes are usually adequate. Large spillages: full body suit of chemically resistant and antistatic material, if necessary heat resistant and insulated.2.2. Work gloves providing adequate chemical resistance, specifically to aromatic hydrocarbons. Note: gloves made of PVA are not water-resistant, and are not suitable for emergency use.If contact with hot product is possible or anticipated, gloves should be heat-resistant and thermally insulated.2.3. Work helmet. Antistatic non-skid safety shoes or boots, if necessary heat-resistant.2.4. Goggles or face shield, if splashes or contact with eyes is possible or anticipated.2.5. Respiratory protection: A half or full-face respirator with filter(s) for organic vapours/H2S or a Self Contained Breathing Apparatus (SCBA) can be used according to the extent of spill and predictable amount of exposure. If the situation cannot be completely assessed, or if an oxygen deficiency is possible, only SCBA’s should be used.3. Spillages onto land 3.1. Prevent product from entering sewers, rivers, waterways or other bodies of water.3.2. If necessary dike the product with dry earth, sand or similar non-combustible materials. 3.3.  Let hot product cool down naturally3.4. Large spillages may be cautiously covered with foam, if available, to limit fire risk. Do not use direct jets3.5. When inside buildings or confined spaces ensure adequate ventilation.3.6. Absorb spilled product with suitable non-combustible materials.3.7. Collect free product with suitable means. Collect recovered product and other contaminated materials in suitable containers for recycle, recovery or safe disposal.3.8. In case of soil contamination, remove contaminated soil for remediation or disposal, in accordance with local regulations.4. Spillages in water or at sea4.1.  Product less dense than water: In case of small spillages in closed waters (i.e. ports), contain product with floating barriers or other equipment.  Collect spilled product by absorbing with specific floating absorbents4.2. If possible, large spillages in open waters should be contained with floating barriers or other mechanical means.  If this is not possible, control the spreading of the spillage, and collect the product by skimming or other suitable mechanical means.4.3. The use of dispersants should be advised by an expert, and, if required, approved by local authorities.4.4. Collect recovered product and other contaminated materials in suitable tanks or containers for recycle, recovery or safe disposal.4.5.   Product which is denser than water will sink to the bottom, and usually no intervention will be feasible. If possible, collect the product and contaminated materials with mechanical means, and store/dispose of according to relevant regulations. In special situations (to be assessed on case-by case basis, according to expert judgement and local conditions), excavations of trenches on the bottom to collect the product, or burying the product with sand may be a feasible option.5. Additional information5.1. Note: recommended measures are based on the most likely spillage scenarios for this material; however, local conditions (wind, air temperature, wave/current direction and speed) may significantly influence the choice of appropriate actions.  For this reason, local experts should be consulted when necessary.  Local regulations may also prescribe or limit actions to be taken.5.2. Concentration of H2S in tank headspaces may reach hazardous values, especially in case of prolonged storage. This situation is especially relevant for those operations which involve direct exposure to the vapours in the tank.5.3. Spillages of limited amounts of products, especially in the open air when vapours will be usually quickly dispersed, are dynamic situations, which are unlikely to entail exposure to dangerous concentrations.  As H2S has a density greater than ambient air, a possible exception may regard the build-up of dangerous concentrations in specific spots, like trenches, depressions or confined spaces.  In all these circumstances, however, the correct actions should be assessed on a case-by-case basis.

Handling and storage

1. General Information1.1. Obtain special instructions before use 1.2. Ensure that all relevant regulations regarding handling and storage facilities of flammable products are followed.1.3. A specific assessment of inhalation risks from the presence of H2S in tank headspaces, confined spaces, product residue, tank waste and waste water, and unintentional releases must be made to help determine controls appropriate to local circumstances.1.4. It is recommended to keep away from sparks/open flames/hot surfaces. – No smoking.1.5. Use and store only outdoors or in a well-ventilated area.1.6. Avoid contact with the product.1.7. Avoid release to the environment.2. Handling2.1. Take precautionary measures against static electricity.2.2. Ground/bond containers, tanks and transfer/receiving equipment.2.3. The vapour is heavier than air. Beware of accumulation in pits and confined spaces.2.4. Do not breathe fume/ mist/ vapours2.5. Avoid contact with skin. Precautions should be taken to avoid skin burns when handling hot product.2.6. Use adequate personal protective equipment as required.2.7. For more information regarding protective equipment and operational conditions see Exposure scenarios. 3. Storage3.1. Storage area layout, tank design, equipment and operating procedures must comply with the relevant European, national or local legislation.3.2. Storage installations should be designed with adequate bunds so as to prevent ground and water pollution in case of leaks or spills. 3.3. Cleaning, inspection and maintenance of internal structure of storage tanks must be done only by properly equipped and qualified personnel as defined by national, local or company regulations. 3.4. Before entering storage tanks and commencing any operation in a confined area, check the atmosphere for oxygen content, hydrogen sulphide (H2S) and flammability. 3.5. Store separately from oxidising agents.4. Recommended and Unsuitable Materials for Storage4.1. Recommended materials: For containers, or container linings use mild steel, stainless steel.4.2. Unsuitable materials: some synthetic materials may be unsuitable for containers or container linings depending on the material specification and intended use. Compatibility should be checked with the manufacturer 5. Container AdviceIf the product is supplied in containers:5.1. Keep only in the original container or in a suitable container for this kind of product.5.2. Store in a well-ventilated place. 5.3. Keep containers tightly closed and properly labelled.5.4. Empty containers may contain combustible product residues. Do not weld, solder, drill, cut or incinerate empty containers, unless they have been properly cleaned.6. Hygiene measures6.1. Ensure that proper housekeeping measures are in place.6.2. Contaminated materials should not be allowed to accumulate in the workplaces and should never be kept inside the pockets.6.3. Keep away from food and beverages.6.4. Do not eat, drink or smoke while using this product.6.5. Wash the hands thoroughly after handling.6.6. Change contaminated clothes at the end of working shift.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:

a) UN 1202
b) UN 1993
c) UN 3082
d) UN 3256
Choose a propper UN No. acc. to classification rules in ADR Part 2 - Classification

Shipping information

Proper shipping name and description:

a) GAS OIL or DIESEL FUEL or HEATING OIL, LIGHT
(Choose only one of the three proper shipping names acc. to physical data and classification rules in Part 2, ADR)
b) FLAMMABLE LIQUID, N.O.S.
(Followed by the technical name, for details look into the dangerous goods regulation)
c) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Followed by the technical name, for details look into the dangerous goods regulation)
d) ELEVATED TEMPERATURE LIQUID, FLAMMABLE, N.O.S.
(Followed by the technical name, for details look into the dangerous goods regulation)

Chemical name:

a) See EC/CAS name listed in CONCAWE for this category
b) See EC/CAS name listed in CONCAWE for this category
c) See EC/CAS name listed in CONCAWE for this category
d) See EC/CAS name listed in CONCAWE for this category

Language:

English

Labels:

a) 3
b) 3
c) 9
d) 3
Marks
a) environmentally hazardous substance mark
b) environmentally hazardous substance mark
c) environmentally hazardous substance mark
d) environmentally hazardous substance mark

Special provisions / remarks

Special provisions:

a) 1 - 640K, ADR 664
2 - 640L, ADR 664
3 - 640M, ADR 664
b) 274, 601, 640C or 640D
c) 274, 335, 375 and 601
d) 274, 560

Remarks:

See ADR chapter 3.3 for details.
Also see Section 7 of the SDS, Handling and Storage

Inland waterway transport (UN RTDG/ADN(R))

UN number:

a) UN 1202
b) UN 1993
c) UN 3082
d) UN 3256
Choose a propper UN No. acc. to classification rules in ADN Part 2 - Classification

Shipping information

Proper shipping name and description:

a) 1 - GAS OIL or DIESEL FUEL or HEATING OIL, LIGHT (flash-point not more than 60 °C)
2 - DIESEL FUEL complying with standard EN 590:2013 + A1:2017 or GAS OIL or HEATING OIL, LIGHT with a flash-point as specified in EN 590:2013 + A1:2017
3 - GAS OIL or DIESEL FUEL or HEATING OIL, LIGHT (flash-point more than 60 °C and not more than 100 °C)
(Choose only one of the three proper shipping names acc. to physical data and classification rules in Part 2, ADN)
b) FLAMMABLE LIQUID, N.O.S. (Followed by the technical name, for details look into the dangerous goods regulation)
c) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Followed by the technical name, for details look into the dangerous goods regulation)
d) ELEVATED TEMPERATURE LIQUID, FLAMMABLE, N.O.S. (Followed by the technical name, for details look into the dangerous goods regulation)

Chemical name:

a) See EC/CAS name listed in CONCAWE for this category
b) See EC/CAS name listed in CONCAWE for this category
c) See EC/CAS name listed in CONCAWE for this category
d) See EC/CAS name listed in CONCAWE for this category

Language:

English

Labels:

a) 3
b) 3
c) 9
d) 3
Marks
a) environmentally hazardous substance mark
b) environmentally hazardous substance mark
c) environmentally hazardous substance mark
d) environmentally hazardous substance mark

Special provisions / remarks

Remarks:

Special provisions:
a) 640K, 640L or 640M see chapter 3.3 ADN for details
b) 274, 601, 640C or 640D see chapter 3.3 ADN for details
c) 274, 335, 375 and 601
d) 274, 560

Marine transport (UN RTDG/IMDG)

UN number:

a) UN 1202
b) UN 1993
c) UN 3082
d) UN 3256
Choose a propper UN No. acc. to classification rules in IMDG Part 2 - Classification

Shipping information

Proper shipping name and description:

a) 1 - GAS OIL or DIESEL FUEL or HEATING OIL, LIGHT (flash-point not more than 60 °C)
2 - DIESEL FUEL complying with standard EN 590:2013 + A1:2017 or GAS OIL or HEATING OIL, LIGHT with a flash-point as specified in EN 590:2013 + A1:2017
3 - GAS OIL or DIESEL FUEL or HEATING OIL, LIGHT (flash-point more than 60 °C and not more than 100 °C)
(Choose only one of the three proper shipping names acc. to physical data and classification rules in Part 2, IMDG)
b) FLAMMABLE LIQUID, N.O.S. (Followed by the technical name, for details look into the dangerous goods regulation)
c) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Followed by the technical name, for details look into the dangerous goods regulation)
d) ELEVATED TEMPERATURE LIQUID, FLAMMABLE, N.O.S. (Followed by the technical name, for details look into the dangerous goods regulation)

Chemical name:

a) See EC/CAS name listed in CONCAWE for this category
b) See EC/CAS name listed in CONCAWE for this category
c) See EC/CAS name listed in CONCAWE for this category
d) See EC/CAS name listed in CONCAWE for this category

Labels:

a) 3
b) 3
c) 9
d) 3
Marks
a) environmentally hazardous substance mark
b) environmentally hazardous substance mark
c) environmentally hazardous substance mark
d) environmentally hazardous substance mark

Marine pollutant

Special provisions / remarks

Remarks:

Also see Section 7 of the SDS, Handling and Storage

Air transport (UN RTDG/ICAO/IATA)

UN number:

a) UN 1202
b) UN 1993
c) UN 3082
d) UN 3256
Choose a propper UN No. acc. to classification rules in IATA Part 2 - Classification

Shipping information

Proper shipping name and description:

a) 1 - GAS OIL or DIESEL FUEL or HEATING OIL, LIGHT (flash-point not more than 60 °C)
2 - DIESEL FUEL complying with standard EN 590:2013 + A1:2017 or GAS OIL or HEATING OIL, LIGHT with a flash-point as specified in EN 590:2013 + A1:2017
3 - GAS OIL or DIESEL FUEL or HEATING OIL, LIGHT (flash-point more than 60 °C and not more than 100 °C)
(Choose only one of the three proper shipping names acc. to physical data and classification rules in Part 2, IATA)
b) FLAMMABLE LIQUID, N.O.S. (Followed by the technical name, for details look into the dangerous goods regulation)
c) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Followed by the technical name, for details look into the dangerous goods regulation)
d) ELEVATED TEMPERATURE LIQUID, FLAMMABLE, N.O.S. (Followed by the technical name, for details look into the dangerous goods regulation)

Chemical name:

a) See EC/CAS name listed in CONCAWE for this category
b) See EC/CAS name listed in CONCAWE for this category
c) See EC/CAS name listed in CONCAWE for this category
d) See EC/CAS name listed in CONCAWE for this category

Labels:

a) 3
b) 3
c) 9
d) 3
Marks
a) environmentally hazardous substance mark
b) environmentally hazardous substance mark
c) environmentally hazardous substance mark
d) environmentally hazardous substance mark

Special provisions / remarks

Remarks:

Data on IATA needs to be verified

Additional transport information

Additional information

Special provisions / remarks / other:

To fulfill the requirements of dangerous goods transport, it is strongly advised to ask your local d angerous goods advisor. There might be regional or national regulations, which are not considered in this dossier.

Exposure controls / personal protection

Note: In this case the information in heading 8 is not required, according to Art. 14 (1) and (2), and Annex VI, Sect. 5.6 of the Regulation.(If applicable, substance registered as an isolated or transported intermediate). Please refer to the assessment report on Risk Management Measures in Section 13 which provides the required information on Strictly Controlled Conditions for the registration of this isolated/transported intermediate.