Registration Dossier
Registration Dossier
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EC number: 427-770-4 | CAS number: 1075-89-4
Guidance on Safe Use
Guidance on Safe Use
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Administrative data
First-aid measures
General information
Personal protection for the First Aider.
Instantly remove any clothing soiled by the product.
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least
48 hours after the accident.
After inhalation
Take affected persons into the open air and position comfortably
Supply fresh air. If required, provide artificial respiration. Keep patient warm.
Call for medical help.
In case of unconsciousness bring patient into stable side position for transport.
After skin contact
Instantly remove contaminated clothing.
Instantly wash with water and rinse thoroughly.
Or better;
Instantly wash with water and soap and rinse thoroughly.
If skin irritation continues, consult a doctor.
After wide skin contact call for medical help.
After eye contact
Rinse opened eye for several minutes under running water.
Seek medical treatment.
After swallowing
Rinse out mouth and then drink plenty of water.
Do not induce vomiting.
Call a doctor immediately.
A vomiting person on the side, lying on the back, turn.
If vomiting, hold the head of the vomiting person low with the body in a prone position.
Information for doctor The toxicological properties of this material have not bean fully investigated.
The following symptoms may occur: A description of symptoms is not present at the moment.
Danger
Mortal danger after exposition (swallowing).
There are at present no indications to further acute dangers for the health.
Further health dangers cannot be excluded however.
Treatment
Elemental assistance.
Decontamination.
Treat symptomatically and supportively.
Personal protection for the First Aider.
Instantly remove any clothing soiled by the product.
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least
48 hours after the accident.
After inhalation
Take affected persons into the open air and position comfortably
Supply fresh air. If required, provide artificial respiration. Keep patient warm.
Call for medical help.
In case of unconsciousness bring patient into stable side position for transport.
After skin contact
Instantly remove contaminated clothing.
Instantly wash with water and rinse thoroughly.
Or better;
Instantly wash with water and soap and rinse thoroughly.
If skin irritation continues, consult a doctor.
After wide skin contact call for medical help.
After eye contact
Rinse opened eye for several minutes under running water.
Seek medical treatment.
After swallowing
Rinse out mouth and then drink plenty of water.
Do not induce vomiting.
Call a doctor immediately.
A vomiting person on the side, lying on the back, turn.
If vomiting, hold the head of the vomiting person low with the body in a prone position.
Information for doctor The toxicological properties of this material have not bean fully investigated.
The following symptoms may occur: A description of symptoms is not present at the moment.
Danger
Mortal danger after exposition (swallowing).
There are at present no indications to further acute dangers for the health.
Further health dangers cannot be excluded however.
Treatment
Elemental assistance.
Decontamination.
Treat symptomatically and supportively.
Fire-fighting measures
· Suitable extinguishing agents
CO2, extinguishing powder or water fog. Fight larger fires with water fog or alcohol-resistant foam.
· For safety reasons unsuitable extinguishing agents Water with a full water jet.
· Special hazards caused by the material, its products of combustion or flue gases:
Formation of toxic and corrosive gases during heating or in case of fire.
Can be released in case of fire:
Carbon monoxide and carbon dioxide.
Nitrogen oxides (NOx)
Dust explosion hazard!
· Protective equipment:
Wear self-contained breathing apparatus.
Wear full protective suit.
· Additional information
Collect contaminated fire fighting water separately. It must not enter drains.
Damp down gases/fumes/haze with water spray jet.
CO2, extinguishing powder or water fog. Fight larger fires with water fog or alcohol-resistant foam.
· For safety reasons unsuitable extinguishing agents Water with a full water jet.
· Special hazards caused by the material, its products of combustion or flue gases:
Formation of toxic and corrosive gases during heating or in case of fire.
Can be released in case of fire:
Carbon monoxide and carbon dioxide.
Nitrogen oxides (NOx)
Dust explosion hazard!
· Protective equipment:
Wear self-contained breathing apparatus.
Wear full protective suit.
· Additional information
Collect contaminated fire fighting water separately. It must not enter drains.
Damp down gases/fumes/haze with water spray jet.
Accidental release measures
· Person-related safety precautions:
Put on breathing apparatus.
Wear protective equipment. Keep unprotected persons away.
Keep away from ignition sources
Avoid causing dust.
Ensure adequate ventilation
Bring persons out of danger.
· Measures for environmental protection:
Do not allow to enter sewing systems, water bodies, groundwater or soil.
Inform respective authorities in case product reaches water, sewage system or soil.
Keep dirty washing water for appropriate disposal.
· Measures for cleaning/collecting:
Avoid causing dust.
Ensure adequate ventilation.
Collect mechanically.
Clean up affected area.
May be recycled or disposed of in appropiate containers
Dispose of contaminated material as waste according to item 13.
Put on breathing apparatus.
Wear protective equipment. Keep unprotected persons away.
Keep away from ignition sources
Avoid causing dust.
Ensure adequate ventilation
Bring persons out of danger.
· Measures for environmental protection:
Do not allow to enter sewing systems, water bodies, groundwater or soil.
Inform respective authorities in case product reaches water, sewage system or soil.
Keep dirty washing water for appropriate disposal.
· Measures for cleaning/collecting:
Avoid causing dust.
Ensure adequate ventilation.
Collect mechanically.
Clean up affected area.
May be recycled or disposed of in appropiate containers
Dispose of contaminated material as waste according to item 13.
Handling and storage
HANDLING
· Information for safe handling:
!!! A T T E N T I O N !!! This product should be handled only under strictly controlled conditions according to REACH, Article 18 (4)!
Keep containers tightly sealed.
Only handle and refill product in closed systems.
Work areas should be physically separate (e.g.: by using encapsulation in safety booths).
Prevent formation of dust.
Enclosure or extractor facilities are required.
Take note of emission threshold.
Use enclosed means of conveyance.
Information about protection against explosions and fires:
Substance/product is flammable.
Dust can combine with air to form an explosive mixture.
Fire fighting equipment must be available.
Keep breathing equipment ready.
Avoid deposition of dust.
Protect from heat.
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
STORAGE
· Requirements to be met by storerooms and containers:
Store in cool location.
Store only in unopened original containers.
· Information about storage in one common storage facility:
Keep away from foodstuffs.
Do not store together with materials/products which can form dangerous chemical reactions.
· Further information about storage conditions:
Keep container tightly sealed.
Protect from heat and direct sunlight.
Store in a locked cabinet or with restricted to technical experts or their assistants.
Open container only under localised extractor facilities.
· Recommended storage temperature: < +30°C
· Information for safe handling:
!!! A T T E N T I O N !!! This product should be handled only under strictly controlled conditions according to REACH, Article 18 (4)!
Keep containers tightly sealed.
Only handle and refill product in closed systems.
Work areas should be physically separate (e.g.: by using encapsulation in safety booths).
Prevent formation of dust.
Enclosure or extractor facilities are required.
Take note of emission threshold.
Use enclosed means of conveyance.
Information about protection against explosions and fires:
Substance/product is flammable.
Dust can combine with air to form an explosive mixture.
Fire fighting equipment must be available.
Keep breathing equipment ready.
Avoid deposition of dust.
Protect from heat.
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
STORAGE
· Requirements to be met by storerooms and containers:
Store in cool location.
Store only in unopened original containers.
· Information about storage in one common storage facility:
Keep away from foodstuffs.
Do not store together with materials/products which can form dangerous chemical reactions.
· Further information about storage conditions:
Keep container tightly sealed.
Protect from heat and direct sunlight.
Store in a locked cabinet or with restricted to technical experts or their assistants.
Open container only under localised extractor facilities.
· Recommended storage temperature: < +30°C
Transport information
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
Components with critical values that require monitoring at the workplace: Not required.
· Personal protective equipment
General protective and hygienic measures
Keep away from foodstuffs, beverages and food.
Clean soiled garments by vacuum cleaning. Do not blow off or brush off.
Store protective clothing separately.
Wash hands during breaks and at the end of the work.
Do not inhale dust / smoke / mist.
Avoid contact with the eyes and skin.
Do not eat, drink or smoke while working.
Breathing equipment:
If used in closed systems or suitable extractor facilities are available breathing protection is not necessary.
In an emergency (e.g.: unintentional release of the substance) respiratory protection must be worn.
In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive
or longer exposure use breathing apparatus that is independent of circulating air.
Filter P3.
Protection of hands:
Chemical-protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Check protective gloves prior to each use for their proper condition.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Preventive skin protection by use of skin-protecting agents is recommended.
Material of gloves
No material can be recommended.
Experience says that polychloroprene, nitrile rubber, butylrubber, fluoro-caoutchouc, and polyvinyl chloride are suitable as glove materials for protection against undissolved solids. The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. ASK THE MANUFACTURER FOR SUITABLE MATERIAL.
Penetration time of glove material
At the permeation time no data are present.
The penetration of the glove material is impossible with dry and not gassing solids.
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed.
Not suitable are gloves made of the following materials:
Strong gloves
Leather gloves
Eye protection:
Chemical safety goggles.
Body protection:
Wear dust tight protective clothing.
Antistatic protective clothing.
Apron
Suitable chemical protection suit.
Protective clothing should be selected specifically for the working place, depending on concentration and quantity of the hazardous substances handled. The resistance of the protective clothing to chemicals should be ascertained with the respective supplier.
· Personal protective equipment
General protective and hygienic measures
Keep away from foodstuffs, beverages and food.
Clean soiled garments by vacuum cleaning. Do not blow off or brush off.
Store protective clothing separately.
Wash hands during breaks and at the end of the work.
Do not inhale dust / smoke / mist.
Avoid contact with the eyes and skin.
Do not eat, drink or smoke while working.
Breathing equipment:
If used in closed systems or suitable extractor facilities are available breathing protection is not necessary.
In an emergency (e.g.: unintentional release of the substance) respiratory protection must be worn.
In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive
or longer exposure use breathing apparatus that is independent of circulating air.
Filter P3.
Protection of hands:
Chemical-protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Check protective gloves prior to each use for their proper condition.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Preventive skin protection by use of skin-protecting agents is recommended.
Material of gloves
No material can be recommended.
Experience says that polychloroprene, nitrile rubber, butylrubber, fluoro-caoutchouc, and polyvinyl chloride are suitable as glove materials for protection against undissolved solids. The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. ASK THE MANUFACTURER FOR SUITABLE MATERIAL.
Penetration time of glove material
At the permeation time no data are present.
The penetration of the glove material is impossible with dry and not gassing solids.
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed.
Not suitable are gloves made of the following materials:
Strong gloves
Leather gloves
Eye protection:
Chemical safety goggles.
Body protection:
Wear dust tight protective clothing.
Antistatic protective clothing.
Apron
Suitable chemical protection suit.
Protective clothing should be selected specifically for the working place, depending on concentration and quantity of the hazardous substances handled. The resistance of the protective clothing to chemicals should be ascertained with the respective supplier.
Stability and reactivity
Conditions to be avoided:
No decomposition if used and stored according to specifications.
To avoid thermal decomposition do not overheat.
Flames, sparks, electrostatic charges
Materials to be avoided:
Bases
Oxidizing agents
Dangerous reactions
The product is not capable of dust explosion in the form supplied; enrichment with fine dust causes risk of dust explosion.
Reacts with strong bases.
Reacts with strong oxidizing agents.
Dangerous products of composition:
Danger of toxic pyrolysis products
Can be released in case of fire:
Carbon monoxide (CO) and carbon dioxide (CO₂)
Nitrogen oxides (NOx)
No decomposition if used and stored according to specifications.
To avoid thermal decomposition do not overheat.
Flames, sparks, electrostatic charges
Materials to be avoided:
Bases
Oxidizing agents
Dangerous reactions
The product is not capable of dust explosion in the form supplied; enrichment with fine dust causes risk of dust explosion.
Reacts with strong bases.
Reacts with strong oxidizing agents.
Dangerous products of composition:
Danger of toxic pyrolysis products
Can be released in case of fire:
Carbon monoxide (CO) and carbon dioxide (CO₂)
Nitrogen oxides (NOx)
Disposal considerations
Recommendation
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Must be specially treated under adherence to official regulations.
European waste catalogue
A waste code in accordance with the European Waste Catalogue (EWC) may not be assigned to this
product since it admits of a classification only when the consumer uses it for some purpose. In
agreement with the waste code must be determined regional waste disposal authority or company.
Uncleaned packagings:
Recommendation: Disposal must be made according to official regulations.
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Must be specially treated under adherence to official regulations.
European waste catalogue
A waste code in accordance with the European Waste Catalogue (EWC) may not be assigned to this
product since it admits of a classification only when the consumer uses it for some purpose. In
agreement with the waste code must be determined regional waste disposal authority or company.
Uncleaned packagings:
Recommendation: Disposal must be made according to official regulations.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
