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Environmental fate & pathways

Hydrolysis

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Description of key information

Assessment of hydrolytic stability using the regulatory method presented in Method C7 Abiotic Degradation, Hydrolysis as a Function of pH of Commission Regulation (EC) No 440/2008 of 30 May 2008 and Method 111 of the OECD Guidelines for Testing of Chemicals, 13 April 2004, was not considered feasible for this test item.

Key value for chemical safety assessment

Additional information

The hydrolytic half-life was determined for tetrapotassium pyrophosphate (EC No: 230 -785 -7). The ionic substance was assumed to undergo dissociation in aqueous solutions (resulting in potassium cations and pyrophosphate anions) therefore the cation was assumed to have a negligible influence on the rate of hydrolysis of the anion. This is expected to be replicated at environmentally relevant concentrations and on dissolution into complex environmental matrices. Although cation of the final matrix may retain some minor influence on the hydrolytic rate, such a relationship is considered beyond the scope of a standard test method and would not have been addressed or identified when testing in accordance with OECD method 111.